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Doppelsalzbildung bei Amiden und vinylogen Amiden

Double salts from amides and vinylogous amides

  • Organische Chemie und Biochemie
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Abstract

The structures of the title compounds are examined by13C-NMR and ESCA spectroscopy. Every double salt shows O-protonation, the proton lying within the experimental error half-way between the carbonyl oxygen atoms of the two molecules of amides resp. vinylogous amides.

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Literatur

  1. S. Gabriel, Ber. dtsch. chem. Ges.22, 3339 (1889).

    Article  Google Scholar 

  2. H. Böhme, H. J. Bohn, E. Köhler undJ. Roehr, Ann. Chem.664, 139 (1963)

    Article  Google Scholar 

  3. Nach Fertigstellung unserer Arbeit erschien in den Nachrichten aus Chemie, Technik und Laboratorium25, 670 (1977) eine Notiz über das Ergebnis einer Röntgenstrukturanalyse vonH. U. Schenck, P. Simak undE. Haedicke an einem Komplex aus 2 MolenN-Methylpyrrolidon und HI3. Danach soll das Proton in der Mitte zwischen den beiden Carbonylsauerstoffatomen fixiert sein.

  4. R. B. Homer undC. D. Johnson, in: The Chemistry of Amides (J. Zabicky, Hrsg.). Interscience. 1970.

  5. J. Tafel undO. Wassmuth, Ber. dtsch. chem. Ges.400, 2831 (1907).

    Article  Google Scholar 

  6. O. Wallach, Ann. Chem.312, 179 (1900).

    Article  Google Scholar 

  7. G. F. D'Alelio undE. E. Reid, J. Amer. Chem. Soc.59, 109 (1937).

    Article  Google Scholar 

  8. F. F. Blicke undJ. H. Burckhalter, J. Amer. Chem. Soc.64, 451 (1942).

    Article  CAS  Google Scholar 

  9. Houben-Weyl-Müller, 4. Aufl., Band 11/2, S. 568.

  10. O. D. Bonner, K. W. Bunzl undG. B. Woolsey, Spectrochim. Acta22, 1125 (1966).

    Article  CAS  Google Scholar 

  11. H. G. Fitzky, D. Wendisch undR. Holm, Angew. Chem.84, 1037 (1972).

    Article  Google Scholar 

  12. S. Hünig undH. Hoch, Fortschr. Chem. Forsch.14, 253 (1970).

    Google Scholar 

  13. I. Jirkovsky, Canad. J. Chem.52, 55 (1974).

    Article  CAS  Google Scholar 

  14. H. E. A. Kramer, Ann. Chem.696, 15 (1966).

    Article  CAS  Google Scholar 

  15. G. H. Alt undA. J. Speziale, J. Org. Chem.30, 1407 (1965).

    Article  CAS  Google Scholar 

  16. N. J. Leonard undJ. A. Adamcik, J. Amer. Chem. Soc.81, 595 (1959).

    Article  CAS  Google Scholar 

  17. G. O. Dudek undR. H. Holm, J. Amer. Chem. Soc.84, 2691 (1962).

    Article  CAS  Google Scholar 

  18. H.-J. Nowak, Dissertation, FU Berlin, in Vorbereitung.

  19. J. Herbke, Dissertation, FU Berlin, 1978.

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Möhrle, H., Kampe, C., Herbke, J. et al. Doppelsalzbildung bei Amiden und vinylogen Amiden. Monatshefte für Chemie 109, 1295–1303 (1978). https://doi.org/10.1007/BF00906041

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  • DOI: https://doi.org/10.1007/BF00906041

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