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Reactions with Manganese (III) Acetate

  • Chapter
Organic Syntheses by Oxidation with Metal Compounds

Abstract

Oxidations with manganese (III) acetate can be broadly divided into two classes:

  1. 1.

    Direct inner- or outer-sphere one-electron oxidation of the substrate after formation of an inner- or outer-sphere substrate-Mn(III) complex. Often subsequent oxidation of an intermediate radical is product determining. Numerous examples can be found in oxidations of alcohols, amino- and thio-compounds, carboxylic acids, and certain aromatics.

  2. 2.

    Indirect oxidation of the substrate after formation of an intermediate adduct free radical from interaction of manganese (III) acetate and an enolizable compound and subsequent addition or substitution of this radical to the substrate. Most examples here refer to aromatic substitution and oxidative addition of enolizable compounds to unsaturated systems.

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de Klein, W.J. (1986). Reactions with Manganese (III) Acetate. In: Mijs, W.J., de Jonge, C.R.H.I. (eds) Organic Syntheses by Oxidation with Metal Compounds. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2109-5_4

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