Abstract
Currently, anticorrosive coatings find a large number of applications and can be effectively used for corrosion protection of many corrosion-prone metals like aluminum, iron, etc. Nanocontainers have the ability to encapsulate large amounts of guest molecules within their core, and releasing them in a controlled way can aid in providing self-healing abilities to the coating, thus providing active protection. In the present study, a novel approach of synthesis of nanocontainers using carbon nanotubes (CNTs) and corrosion inhibitor 2-mercaptobenzothiazole has been discussed with their applications in corrosion protection of mild steel (MS). It is a three-step procedure involving layer-by-layer deposition of the CNT, inhibitor, and polyelectrolytes, which thus provides enhanced corrosion protection when coated on MS plates. The thickness of the layer, surface charge, and functional groups present on each layer were identified using various analytic techniques such as particle size distribution, zeta potential, and FTIR analysis. X-ray diffractograms analyses of CNT and modified CNT were performed to evaluate their crystallographic properties. The morphological and particle size clearly indicate the development of a nanocontainer. The corrosion rate analysis of nanocontainer-epoxy coatings on MS panel has been performed by means of salt spray and DC polarization measurements. The corrosion resistance was measured after the immersion of the coated samples in alkali solution.
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References
Sørensen, PA, Kill, S, Dam-Johansen, K, Weinell, CE, “Anticorrosive Coatings: A Review.” J. Coat. Technol. Res., 6 (2) 135–176 (2009)
Fontana, MG, Corrosion Engineering. Tata McGraw-Hill Education Private Limited, New Delhi, 2005
Deshpande, P, Jadhav, N, Gelling, V, Sazou, D, “Conducting Polymers for Corrosion Protection: A Review.” J. Coat. Technol. Res., 11 (4) 473–494 (2014)
Yeole, KV, Mahajan, LH, Mhaske, ST, “Poly (o-Anisidine)-MWCNT Nanocomposite: Synthesis.” Polym. Compos., (2014). doi:10.1002/pc.23054, Characterization and Anticorrosion Properties
Zheludkevich, ML, Shchukin, DG, Yasakau, KA, Mohwald, H, Ferreira, MGS, “Anticorrosion Coatings with Self-healing Effect Based on Nanocontainers Impregnated with Corrosion Inhibitor.” Chem. Mater., 19 402–411 (2007)
Zaarei, D, Sarabi, AA, Sharif, F, Kassiriha, SM, “Structure, Properties and Corrosion Resistivity of Polymeric Nanocomposite Coatings Based on Layered Silicates.” J. Coat. Technol. Res., 5 (2) 241–249 (2008)
Jadhav, N, Vetter, CA, Gelling, VJ, “The Effect of Polymer Morphology on the Performance of a Corrosion Inhibiting Polypyrrole/Aluminum Flake Composite Pigment.” Electrochim. Acta, 102 28–43 (2013)
Armelin, E, Alemán, C, Iribarren, JI, “Anticorrosion Performances of Epoxy Coatings Modified with Polyaniline: A Comparison Between the Emeraldine Base and Salt Forms.” Prog. Org. Coat., 65 88–93 (2009)
Jadhav, N, Gelling, VJ, “Synthesis and Characterization of Micaceous Iron Oxide/Polypyrrole Composite Pigments and Their Application for Corrosion Protection of Cold Rolled Steel.” Corrosion, 70 464–474 (2013)
Sangaj, NS, Malshe, VC, “Permeability of Polymers in Protective Organic Coatings.” Prog. Org. Coat., 50 28–39 (2004)
Peng, S, Zhao, W, Li, H, Zeng, Z, Xue, Q, Wu, X, “The Enhancement of Benzotriazole on Epoxy Functionalized Silica Sol–Gel Coating for Copper Protection.” Appl. Surf. Sci., 276 284–290 (2013)
Tavandashti, NP, Sanjabi, S, Shahrabi, T, “Corrosion Protection Evaluation of Silica/Epoxy Hybrid Nanocomposite Coatings to AA2024.” Prog. Org. Coat., 65 (2) 182–186 (2009)
Balaskasa, AC, Kartsonakisa, IA, Tzivelekaa, LA, Kordasa, GC, “Improvement of Anti-corrosive Properties of Epoxy-Coated AA 2024-T3 with TiO2 Nanocontainers Loaded with 8-Hydroxyquinoline.” Prog. Org. Coat., 74 418–426 (2012)
Kartsonakisa, IA, Balaskasa, AC, Koumoulos, EP, Charitidis, CA, Kordasa, G, “ORMOSIL-Epoxy Coatings with Ceramic Containers for Corrosion Protection of Magnesium Alloys ZK10.” Prog. Org. Coat., 76 459–470 (2013)
Tedim, J, Poznyak, SK, Kuznetsova, A, Raps, D, Hack, T, Zheludkevich, ML, Ferreira, MGS, “Enhancement of Active Corrosion Protection via Combination of Inhibitor-Loaded Nanocontainers.” ACS Appl. Mater. Interfaces, 2 1528–1535 (2010)
Subramania, A, Kalyana Sundaram, NT, Sathiya Priya, R, Saminathan, K, Muralidharan, VS, Vasudevan, T, “Aldimines Effective Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution.” J. Appl. Electrochem., 34 693–696 (2004)
Borisov, D, Akcakayıran, D, Schenderlein, M, Möhwald, H, Shchukin, DG, “Nanocontainer-Based Anticorrosive Coatings: Effect of the Container Size on the Self-Healing Performance.” Adv. Funct. Mater., 23 (30) 3799–3812 (2013)
Shchukin, DG, Mohwald, H, “Self-repairing Coatings Containing Active Nanoreservoirs.” Small, 3 (6) 926–943 (2007)
Goesmann, H, Feldmann, C, “Nanoparticulate Functional Materials.” Angew. Chem. Int. Ed., 49 (8) 1362–1395 (2010)
Shchukin, DG, Zheludkevich, M, Yasakau, K, Lamaka, S, Ferreira, MGS, Möhwald, H, “Layer-by-Layer Assembled Nanocontainers for Self-healing Corrosion Protection.” Adv. Mater., 18 (13) 1672–1678 (2006)
Sonawane, SH, Bhanvase, BA, Jamalia, AA, Dubey, SK, Kale, SS, Pinjari, DV, Kulkarni, RD, Gogate, PR, Pandit, AB, “Improved Active Anticorrosion Coatings Using Layer-by-Layer Assembled ZnO Nanocontainers with Benzotriazole.” Chem. Eng. J., 189–190 464–472 (2012)
Zheludkevich, ML, Tedim, J, Ferreira, MGS, “Smart Coatings for Active Corrosion Protection Based on Multi-functional Micro and Nanocontainers.” Electrochim. Acta, 82 314–323 (2012)
Li, D, Wang, F, Yu, X, Wang, J, Liu, Q, Yang, P, He, Y, Wang, Y, Zhang, M, “Anticorrosion Organic Coating with Layered Double Hydroxide Loaded with Corrosion Inhibitor of Tungstate.” Prog. Org. Coat., 71 302–309 (2011)
Arunchandran, C, Ramya, S, George, RP, Kamachi, MU, “Corrosion Inhibitor Storage and Release Property of TiO2 Nanotube Powder Synthesized by Rapid Breakdown Anodization Method.” Mater. Res. Bull., 48 635–639 (2013)
Poznyak, SK, Tedim, J, Rodrigues, LM, Salak, AN, Zheludkevich, ML, Dick, LFP, Ferreira, MGS, “Novel Inorganic Host Layered Double Hydroxides Intercalated with Guest Organic Inhibitors for Anticorrosion Applications.” ACS Appl. Mater. Interfaces, 1 (10) 2353–2362 (2009)
Ionita, M, Pruna, A, “Polypyrrole/Carbon Nanotube Composites: Molecular Modeling and Experimental Investigation as Anti-corrosive Coating.” Prog. Org. Coat., 72 (4) 647–652 (2011)
Richard Prabakar, SJ, Pyo, M, “Corrosion Protection of Aluminum in LiPF6 by Poly(3,4-ethylenedioxythiophene) Nanosphere-Coated Multiwalled Carbon Nanotube.” Corros. Sci., 57 42–48 (2012)
Xie, S, Li, W, Pan, Z, Chang, B, Sun, L, “Mechanical and Physical Properties on Carbon Nanotube.” J. Phys. Chem. Solids, 61 1153–1158 (2000)
Yuen, SM, Ma, CCM, Chiang, CL, Teng, CC, Yu, YH, “Poly(vinyltriethoxysilane) Modified MWCNT/Polyimide Nanocomposites Preparation, Morphological, Mechanical, and Electrical Properties.” J. Polym. Sci. Part A, 46 (3) 803–816 (2008)
van der Merwe, EM, Mathebula, CL, Prinsloo, LC, “Characterization of the Surface and Physical Properties of South African Coal Fly Ash Modified by Sodium Lauryl Sulphate (SLS) for Applications in PVC Composites.” Powder Technol., 266 70–78 (2014)
Karim, MR, Lee, CJ, Park, YT, Lee, MS, “SWNTs Coated by Conducting Polyaniline: Synthesis and Modified Properties.” Synth. Met., 151 (2) 131–135 (2005)
Wang, Y, Zhang, D, “Synthesis, Characterization, and Controlled Release Anticorrosion Behavior of Benzoate Intercalated Zn-Al Layered Double Hydroxides.” Mater. Res. Bull., 46 (11) 1963–1968 (2011)
Omastová, M, Rychlý, J, Trchová, M, Kovová, J, “Properties and Thermal Decomposition of Polypyrrole Prepared in the Presence of Sodium Bis(2-ethylhexyl) Sulfosuccinate.” Des. Monomers Polym., 7 (6) 633–646 (2004)
Kartsonakis, I, Daniilidis, I, Kordas, G, “Encapsulation of the Corrosion Inhibitor 8-Hydroxyquinoline into Ceria Nanocontainers.” J. Sol-Gel Sci. Technol., 48 24–31 (2008)
Liu, Y, Yang, J, Zhao, Z, Lia, J, Zhang, R, Yao, F, “Formation and Characterization of Natural Polysaccharide Hollow Nanocapsules via Template Layer-by-Layer Self-assembly.” J. Colloid Interface Sci., 379 (1) 130–140 (2012)
Shchukin, DG, Möhwald, H, “Surface-Engineered Nanocontainers for Entrapment of Corrosion Inhibitors.” Adv. Funct. Mater., 17 1451–1458 (2007)
Shchukin, DG, Köhler, K, Möhwald, H, Sukhorukov, GB, “Gas-Filled Polyelectrolyte Capsules.” Angew. Chem. Int. Ed., 44 (21) 3310–3314 (2005)
Tamil Selvi, S, Raman, V, Rajendran, N, “Corrosion Inhibition of Mild Steel by Benzotriazole Derivatives in Acidic Medium.” J. Appl. Electrochem., 33 1175–1182 (2003)
Ramesh, S, Rajeswari, S, “Corrosion Inhibition of Mild Steel in Neutral Aqueous Solution by New Triazole Derivatives.” Electrochim. Acta, 49 (5) 811–820 (2004)
Yu, X, Wang, J, Zhang, M, Yang, L, Li, J, Yang, P, Cao, D, “Synthesis, Characterization and Anticorrosion Performance of Molybdate Pillared Hydrotalcite/In Situ Created ZnO Composite as Pigment for Mg–Li Alloy Protection.” Surf. Coat. Technol., 203 (3–4) 250–255 (2008)
Kartsonakis, IA, Balaskas, AC, Kordas, GC, “Influence of Cerium Molybdate Containers on the Corrosion Performance of Epoxy Coated Aluminium Alloys 2024-T3.” Corros. Sci., 53 (11) 3771–3779 (2011)
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Yeole, K.V., Agarwal, I.P. & Mhaske, S.T. The effect of carbon nanotubes loaded with 2-mercaptobenzothiazole in epoxy-based coatings. J Coat Technol Res 13, 31–40 (2016). https://doi.org/10.1007/s11998-015-9730-z
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DOI: https://doi.org/10.1007/s11998-015-9730-z