Skip to main content
Log in

Comparison and characterization of biocompatible polymer coatings on AISI 316L stainless steel

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

Polyethylene glycol (PEG)- and polydimethylsiloxane (PDMS)-based corrosion protection coatings of the AISI 316L stainless steel surface were investigated. X-ray photoelectron spectroscopy (XPS) was used to confirm successful deposition of the coatings on the substrate as well as to estimate the thickness for both coating types. Contact angle measurements were used to evaluate wetting properties of noncoated, PEG-coated, and PDMS-coated substrates. Hydrophobicity was achieved by applying PDMS coating on the substrate. Potentiodynamic measurements established enhanced corrosion stability of PEG- and PDMS-coated stainless steels. Electrochemical impedance spectroscopy was also performed. It showed superior corrosion protection vs immersion time dependence for PDMS coating in NaCl solution compared to PEG coating.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Hryniewicz, T, Rokicki, R, Rokosz, K, “Corrosion Characteristics of Medical-Grade AISI Type 316L Stainless Steel Surface After Electropolishing in a Magnetic Field.” Corrosion, 64 660 (2008)

    Article  Google Scholar 

  2. Wei, J, Ravn, DB, Gram, L, Kingshott, P, “Stainless Steel Modified with Poly(ethylene glycol) Can Prevent Protein Adsorption but not Bacterial Adhesion.” Colloids and Surfaces B, 32 275–291 (2003)

    Article  Google Scholar 

  3. Samal, SS, Vishwakarma, V, Ramachandran, D, “Study of Antibacterial Activities of Carbon Nanotube Based Epoxy Composites to Prevent Biofouling in Marine Environment: A Lab Scale Approach.” Marine Eng. Front. (MEF), 1 (3) 49–52 (2013)

    Google Scholar 

  4. Videla, HA, Herrera, LK, “Microbiologically Influenced Corrosion: Looking to the Future.” Int. Microbiol., 8 169–180 (2005)

    Google Scholar 

  5. Marabotti, I, Morelli, A, Orsini, LM, Martinelli, E, Galli, G, Chiellini, E, Lien, EM, Pettitt, ME, Callow, ME, Callow, JA, Conlan, SL, Mutton, RJ, Clare, AS, Kocijan, A, Donik, C, Jenko, M, “Fluorinated/Siloxane Copolymer Blends for Fouling Release: Chemical Characterisation and Biological Evaluation with Algae and Barnacles.” Biofouling, 25 481–493 (2009)

    Article  Google Scholar 

  6. Kang, C-K, Lee, Y-S, “The Surface Modification of Stainless Steel and the Correlation Between the Surface Properties and Protein Adsorption.” J. Mater. Sci., 18 1389–1398 (2007)

    Google Scholar 

  7. Akesso, L, Navabpour, P, Teer, D, Pettitt, ME, Callow, ME, Liu, C, Wang, S, Zhao, Q, Donik, C, Kocijan, A, Jenko, M, Callow, JA, “Deposition Parameters to Improve the Fouling-Release Properties of Thin Siloxane Coatings Prepared by PACVD.” Appl. Surf. Sci., 255 6508–6514 (2009)

    Article  Google Scholar 

  8. Beigbeder, A, Jeusette, M, Mincheva, R, Degée, Ph, Claes, M, Brocorens, P, Lazzaroni, R, Dubois, Ph, “On the Effect of Carbon Nanotubes on the Wettability and Surface Morphology of Hydrosilylation-Curing Silicone Coatings.” J. Nanostruct. Polym. Nanocomposites, 5 37–43 (2009)

    Google Scholar 

  9. Tasso, M, Pettitt, ME, Cordeiro, AL, Callow, ME, Callow, JA, Werner, C, “Antifouling Potential of Subtilisin A Immobilized Onto Maleic Anhydride Copolymer Thin Films.” Biofouling, 25 505–516 (2009)

    Article  Google Scholar 

  10. Schilp, S, Rosenhahn, A, Pettitt, ME, Bowen, J, Callow, ME, Callow, JA, Grunze, M, “Physicochemical Properties of (ethylene glycol)-Containing Self-assembled Monolayers Relevant for Protein and Algal Cell Resistance.” Langmuir, 25 (17) 10077–10082 (2009)

    Article  Google Scholar 

  11. Yuan, S, Wan, D, Liang, B, Pehkonen, SO, Ting, YP, Neoh, KG, Kang, ET, “Lysozyme-Coupled Poly(poly(ethylene glycol)methacrylate)-Stainless Steel Hybrids and Their Antifouling and Antibacterial Surfaces.” Langmuir, 27 2761–2774 (2011)

    Article  Google Scholar 

  12. Cabrala, AM, Duarte, RG, Montemor, MF, Ferreira, MGS, “A Comparative Study on the Corrosion Resistance of AA2024-T3 Substrates Pre-treated with Different Silane Solutions: Composition of the Films Formed.” Prog. Org. Coat., 54 (4) 322–331 (2005)

    Article  Google Scholar 

  13. Zhang, F, Kang, ET, Neoh, KG, Wang, P, Tan, KL, “Surface Modification of Stainless Steel by Grafting of Poly(ethylene glycol) for Reduction in Protein Adsorption.” Biomaterials, 22 1541–1548 (2001)

    Article  Google Scholar 

  14. Zhang, H, Chiao, M, “Antifouling Coatings of PDMS Devices for Biological/Biomedical Applications.” J. Med. Biol. Eng., (2014). doi:10.5405/jmbe.1758

    Google Scholar 

  15. Deyab, MA, Abd El-RehimInt, SS, “Influence of Polyethylene Glycols on the Corrosion Inhibition of Carbon Steel in Butyric Acid Solution: Weight Loss, EIS and Theoretical Studies.” J. Electrochem. Sci., 8 12613–12627 (2013)

    Google Scholar 

  16. John, S, Kuruvilla, M, Josep, A, “Surface Morphological and Impedance Spectroscopic Studies on the Interaction of Polyethylene Glycol (PEG) and Polyvinyl Pyrrolidone (PVP) with Mild Steel in Acid Solutions.” Res. Chem. Intermed., 39 1169–1182 (2013)

    Article  Google Scholar 

  17. Certhoux, E, Ansart, F, Turq, V, Bonino, JP, Sobrino, JM, Garcia, J, Reby, J, “New Sol–Gel Formulations to Increase the Barrier Effect of a Protective Coating Against the Corrosion of Steels.” Prog. Org. Coat., 76 165–172 (2013)

    Article  Google Scholar 

  18. Wu, KH, Chao, CM, Yeh, TF, “Thermal Stability and Corrosion Resistance of Polysiloxane Coatings on 2024-T3 and 6061-T6 Aluminum Alloy.” Surf. Coat. Technol., 201 5782–5788 (2007)

    Article  Google Scholar 

  19. Zhang, M, Desai, T, Ferrari, M, “Proteins and Cells on PEG Immobilized Silicon Surfaces.” Biomaterials, 19 953–960 (1998)

    Article  Google Scholar 

  20. Fairley, N, CasaXPS VAMAS Processing Software, http://www.casaxps.com/.

  21. Li, D, Neumann, AW, “A Reformulation of the Equation of State for Interfacial-Tensions.” J. Colloid Interface Sci., 137 304–307 (1990)

    Article  Google Scholar 

  22. Naumkin, AV, Kraut-Vass, A, Gaarenstroom, SW, Powell, C.J (eds.), NIST X-ray Photoelectron Spectroscopy Database, http://srdata.nist.gov/xps/.

  23. Chastain, J (ed.) Handbook of X-ray Photoelectron Spectroscopy. Physical Electronics Inc., Eden Prairie, 1995

    Google Scholar 

  24. Kwok, DY, Neumann, AW, “Contact Angle Measurement and Contact Angle Interpretation.” Adv. Colloid Interface Sci., 81 167–249 (1999)

    Article  Google Scholar 

  25. Yu, YY, Chen, CY, Chen, WC, “Synthesis and Characterization of Organic—Inorganic Hybrid Thin Films from Poly(acrylic) and Monodispersed Colloidal Silica.” Polymer, 44 593–601 (2003)

    Article  Google Scholar 

  26. Raistrick, ID, MacDonald, JR, Francschetti, DR, In: MacDonald, JR (ed.) Impedance spectroscopy Emphasizing Solid materials and Systems, Vol. 2, pp. 27–84. Wiley, New York, 1987

    Google Scholar 

Download references

Acknowledgment

This work was carried out within the framework of the Slovenian program P2-0132, “Fizika in kemija površin kovinskih materialov” of the Slovenian Research Agency, whose support is gratefully acknowledged by A. Kocijan, M. Conradi, and Dj. Mandrino.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Kocijan.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kocijan, A., Conradi, M., Mandrino, D. et al. Comparison and characterization of biocompatible polymer coatings on AISI 316L stainless steel. J Coat Technol Res 12, 1123–1131 (2015). https://doi.org/10.1007/s11998-015-9698-8

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-015-9698-8

Keywords

Navigation