Abstract
Polyethylene glycol (PEG)- and polydimethylsiloxane (PDMS)-based corrosion protection coatings of the AISI 316L stainless steel surface were investigated. X-ray photoelectron spectroscopy (XPS) was used to confirm successful deposition of the coatings on the substrate as well as to estimate the thickness for both coating types. Contact angle measurements were used to evaluate wetting properties of noncoated, PEG-coated, and PDMS-coated substrates. Hydrophobicity was achieved by applying PDMS coating on the substrate. Potentiodynamic measurements established enhanced corrosion stability of PEG- and PDMS-coated stainless steels. Electrochemical impedance spectroscopy was also performed. It showed superior corrosion protection vs immersion time dependence for PDMS coating in NaCl solution compared to PEG coating.
Similar content being viewed by others
References
Hryniewicz, T, Rokicki, R, Rokosz, K, “Corrosion Characteristics of Medical-Grade AISI Type 316L Stainless Steel Surface After Electropolishing in a Magnetic Field.” Corrosion, 64 660 (2008)
Wei, J, Ravn, DB, Gram, L, Kingshott, P, “Stainless Steel Modified with Poly(ethylene glycol) Can Prevent Protein Adsorption but not Bacterial Adhesion.” Colloids and Surfaces B, 32 275–291 (2003)
Samal, SS, Vishwakarma, V, Ramachandran, D, “Study of Antibacterial Activities of Carbon Nanotube Based Epoxy Composites to Prevent Biofouling in Marine Environment: A Lab Scale Approach.” Marine Eng. Front. (MEF), 1 (3) 49–52 (2013)
Videla, HA, Herrera, LK, “Microbiologically Influenced Corrosion: Looking to the Future.” Int. Microbiol., 8 169–180 (2005)
Marabotti, I, Morelli, A, Orsini, LM, Martinelli, E, Galli, G, Chiellini, E, Lien, EM, Pettitt, ME, Callow, ME, Callow, JA, Conlan, SL, Mutton, RJ, Clare, AS, Kocijan, A, Donik, C, Jenko, M, “Fluorinated/Siloxane Copolymer Blends for Fouling Release: Chemical Characterisation and Biological Evaluation with Algae and Barnacles.” Biofouling, 25 481–493 (2009)
Kang, C-K, Lee, Y-S, “The Surface Modification of Stainless Steel and the Correlation Between the Surface Properties and Protein Adsorption.” J. Mater. Sci., 18 1389–1398 (2007)
Akesso, L, Navabpour, P, Teer, D, Pettitt, ME, Callow, ME, Liu, C, Wang, S, Zhao, Q, Donik, C, Kocijan, A, Jenko, M, Callow, JA, “Deposition Parameters to Improve the Fouling-Release Properties of Thin Siloxane Coatings Prepared by PACVD.” Appl. Surf. Sci., 255 6508–6514 (2009)
Beigbeder, A, Jeusette, M, Mincheva, R, Degée, Ph, Claes, M, Brocorens, P, Lazzaroni, R, Dubois, Ph, “On the Effect of Carbon Nanotubes on the Wettability and Surface Morphology of Hydrosilylation-Curing Silicone Coatings.” J. Nanostruct. Polym. Nanocomposites, 5 37–43 (2009)
Tasso, M, Pettitt, ME, Cordeiro, AL, Callow, ME, Callow, JA, Werner, C, “Antifouling Potential of Subtilisin A Immobilized Onto Maleic Anhydride Copolymer Thin Films.” Biofouling, 25 505–516 (2009)
Schilp, S, Rosenhahn, A, Pettitt, ME, Bowen, J, Callow, ME, Callow, JA, Grunze, M, “Physicochemical Properties of (ethylene glycol)-Containing Self-assembled Monolayers Relevant for Protein and Algal Cell Resistance.” Langmuir, 25 (17) 10077–10082 (2009)
Yuan, S, Wan, D, Liang, B, Pehkonen, SO, Ting, YP, Neoh, KG, Kang, ET, “Lysozyme-Coupled Poly(poly(ethylene glycol)methacrylate)-Stainless Steel Hybrids and Their Antifouling and Antibacterial Surfaces.” Langmuir, 27 2761–2774 (2011)
Cabrala, AM, Duarte, RG, Montemor, MF, Ferreira, MGS, “A Comparative Study on the Corrosion Resistance of AA2024-T3 Substrates Pre-treated with Different Silane Solutions: Composition of the Films Formed.” Prog. Org. Coat., 54 (4) 322–331 (2005)
Zhang, F, Kang, ET, Neoh, KG, Wang, P, Tan, KL, “Surface Modification of Stainless Steel by Grafting of Poly(ethylene glycol) for Reduction in Protein Adsorption.” Biomaterials, 22 1541–1548 (2001)
Zhang, H, Chiao, M, “Antifouling Coatings of PDMS Devices for Biological/Biomedical Applications.” J. Med. Biol. Eng., (2014). doi:10.5405/jmbe.1758
Deyab, MA, Abd El-RehimInt, SS, “Influence of Polyethylene Glycols on the Corrosion Inhibition of Carbon Steel in Butyric Acid Solution: Weight Loss, EIS and Theoretical Studies.” J. Electrochem. Sci., 8 12613–12627 (2013)
John, S, Kuruvilla, M, Josep, A, “Surface Morphological and Impedance Spectroscopic Studies on the Interaction of Polyethylene Glycol (PEG) and Polyvinyl Pyrrolidone (PVP) with Mild Steel in Acid Solutions.” Res. Chem. Intermed., 39 1169–1182 (2013)
Certhoux, E, Ansart, F, Turq, V, Bonino, JP, Sobrino, JM, Garcia, J, Reby, J, “New Sol–Gel Formulations to Increase the Barrier Effect of a Protective Coating Against the Corrosion of Steels.” Prog. Org. Coat., 76 165–172 (2013)
Wu, KH, Chao, CM, Yeh, TF, “Thermal Stability and Corrosion Resistance of Polysiloxane Coatings on 2024-T3 and 6061-T6 Aluminum Alloy.” Surf. Coat. Technol., 201 5782–5788 (2007)
Zhang, M, Desai, T, Ferrari, M, “Proteins and Cells on PEG Immobilized Silicon Surfaces.” Biomaterials, 19 953–960 (1998)
Fairley, N, CasaXPS VAMAS Processing Software, http://www.casaxps.com/.
Li, D, Neumann, AW, “A Reformulation of the Equation of State for Interfacial-Tensions.” J. Colloid Interface Sci., 137 304–307 (1990)
Naumkin, AV, Kraut-Vass, A, Gaarenstroom, SW, Powell, C.J (eds.), NIST X-ray Photoelectron Spectroscopy Database, http://srdata.nist.gov/xps/.
Chastain, J (ed.) Handbook of X-ray Photoelectron Spectroscopy. Physical Electronics Inc., Eden Prairie, 1995
Kwok, DY, Neumann, AW, “Contact Angle Measurement and Contact Angle Interpretation.” Adv. Colloid Interface Sci., 81 167–249 (1999)
Yu, YY, Chen, CY, Chen, WC, “Synthesis and Characterization of Organic—Inorganic Hybrid Thin Films from Poly(acrylic) and Monodispersed Colloidal Silica.” Polymer, 44 593–601 (2003)
Raistrick, ID, MacDonald, JR, Francschetti, DR, In: MacDonald, JR (ed.) Impedance spectroscopy Emphasizing Solid materials and Systems, Vol. 2, pp. 27–84. Wiley, New York, 1987
Acknowledgment
This work was carried out within the framework of the Slovenian program P2-0132, “Fizika in kemija površin kovinskih materialov” of the Slovenian Research Agency, whose support is gratefully acknowledged by A. Kocijan, M. Conradi, and Dj. Mandrino.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kocijan, A., Conradi, M., Mandrino, D. et al. Comparison and characterization of biocompatible polymer coatings on AISI 316L stainless steel. J Coat Technol Res 12, 1123–1131 (2015). https://doi.org/10.1007/s11998-015-9698-8
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11998-015-9698-8