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Kinetics of the reverse-Boudouard reaction over supported nickel catalysts

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Summary

A new method determining the specific rate with no information about the number of active sites was applied to the reverse-Boudourad reaction over supported Ni catalysts.  It was found that the catalyst support hardly affected the specific rate.  The activity pattern and activation energies agreed well with those obtained by a conventional method using TG, suggesting the validity of the new method for studying the kinetics.  

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Authors and Affiliations

  1. National Institute of Advanced Industrial Science and Technology (AIST), 2266-98, Anagahora, Shimoshidami, Moriyama-ku, Nagoya 463-8560, Japan

    Toshihiko Osaki

  2. National Institute of Advanced Industrial Science and Technology (AIST), Present address: Department of Materials Science and Technology, Faculty of Science and Technology, Hirosaki University, 2266-98, Anagahora, Shimoshidami, Moriyama-ku, Nagoya 463-8560, Japan Bunkyo-cho, Hirosaki 036-8561, Japan

    Toshiaki Mori

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  1. Toshihiko Osaki
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  2. Toshiaki Mori
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Osaki, T., Mori, T. Kinetics of the reverse-Boudouard reaction over supported nickel catalysts . React Kinet Catal Lett 89, 333–339 (2006). https://doi.org/10.1007/s11144-006-0145-9

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  • DOI: https://doi.org/10.1007/s11144-006-0145-9

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