Abstract
Intense Raman scattering by acetophenone molecules adsorbed on colloidal silver particles is reported. Greater enhancement is observed for the ring breathing and ring stretching vibrations. The orientation determination analysis shows that the adsorption of acetophenone molecule is neither through its co-ordinating site nor through itsπ-orbital system and there is no strong chemical interaction. However significant intensity enhancement for several vibrations suggests that the contribution is from classical electromagnetic field on the rough surface.
Similar content being viewed by others
References
R L Garrel,Anal. Chem. 61, 401A (1989)
K V von Raben, R K Chang, B L Laube and P W Barber,J. Phys. Chem. 88, 5290 (1984)
V Ramakrishnan, N Krishnamurthy, M Gurunathan and V J P Srivatsavoy,Spectrochim. Acta A46, 1615 (1990)
G Varsanyi,Vibrational spectra of benzene derivatives (Academic Press, New York, 1969) p. 232, 150, 251, 294
N Colthup, L H Daly and S E Wiberly,Introduction to infrared and Raman spectroscopy (Academic Press, New York, 1975) p. 261
X Gao, J P Davies and M J Weaver,J. Phys. Chem. 94, 6858 (1990)
P Gao and M J Weaver,J. Phys. Chem. 89, 5040 (1985)
M Moskovits and J S Suh,J. Am. Chem. Soc. 107, 6826 (1985)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Jayaraj, S.E., Ramakrishnan, V., Perumal, S. et al. Surface enhanced Raman scattering studies of acetophenone on colloidal silver particles. Pramana - J. Phys. 47, 255–259 (1996). https://doi.org/10.1007/BF02847769
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02847769