Abstract
Wastewater from various industries majorly includes organic pollutants and heavy metals. They pose a serious threat to the environment because they are toxic and not biodegradable. In this scenario, metallic nanoparticles such as gold, silver, platinum, iron, copper and selenium are explored for wastewater treatment. However, nanoscale zero-valent iron (nZVI), representing the forefront of technologies, has been considered as promising material, due to its high reducibility and strong adsorption capability. ZVI is typically applied as a reductant and is capable of transforming, degrading or sequestering a variety of contaminants. ZVIs can be applied as either a single or a bimetallic system as well as advanced oxidation processes (AOPs). Moreover, core–shell type nanoparticles are a type of biphasic materials which have an inner core structure and an outer shell made of different components. Organic shells, consisting in most cases of polymers, proteins or complex sugars, can improve the performance of inorganic nanoparticles by enhancing their biocompatibility, acting as anchor sites for molecular linkages, or protecting them from oxidation. In this chapter, we will be focusing on the role of zero-valent iron and hybrid metallic nanoparticles in wastewater treatment due to their ability for the removal of various pollutants with a special emphasis on adsorption and photocatalysis. Further, this chapter focuses on challenges addressing the treatment and future trends.
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References
Ahmad Z, Shah SA, Khattak I, Ullah H, Khan AA, Shah RA, Khan SA, Khan SB (2020) Melia Azedarach impregnated Co and Ni zero-valent metal nanoparticles for organic pollutants degradation: validation of experiments through statistical analysis. J Mater Sci: Mater Electron 31(19):16938–16950
Ahmadi, M., Foladivanda, M., Jaafarzadeh, N., Ramezani, Z., Ramavandi, B., Jorfi, S., & Kakavandi, B. (2017). Synthesis of chitosan zero-valent iron nanoparticles-supported for cadmium removal: characterization, optimization and modeling approach. Journal of Water Supply: Research and Technology—Aqua, 66(2), 116–130.
Ahmaruzzaman M (2021) Biochar based nanocomposites for photocatalytic degradation of emerging organic pollutants from water and wastewater. Mater Res Bull 140:111262
Ali F, Khan SB, Kamal T, Alamry KA, Asiri AM (2018) Chitosan-titanium oxide fibers supported zero-valent nanoparticles: highly efficient and easily retrievable catalyst for the removal of organic pollutants. Sci Rep 8(1):1–18
Ali F, Khan SB, Kamal T, Anwar Y, Alamry KA, Asiri AM (2017) Anti-bacterial chitosan/zinc phthalocyanine fibers supported metallic and bimetallic nanoparticles for the removal of organic pollutants. Carbohyd Polym 173:676–689
Badmus KO, Wewers F, Al-Abri M, Shahbaaz M, Petrik LF (2021) Synthesis of Oxygen Deficient TiO2 for Improved Photocatalytic Efficiency in Solar Radiation. Catalysts 11(8):904
Baloochi SJ, Nazar ARS, Farhadian M (2018) 2, 4-Dichlorophenoxyacetic acid herbicide photocatalytic degradation by zero-valent iron/titanium dioxide based on activated carbon. Environ Nanotechnol Monit Manage 10:212–222
Bhatti HN, Iram Z, Iqbal M, Nisar J, Khan MI (2020) Facile synthesis of zero valent iron and photocatalytic application for the degradation of dyes. Materials Research Express 7(1):015802
Bokare AD, Choi W (2009) Zero-valent aluminum for oxidative degradation of aqueous organic pollutants. Environ Sci Technol 43(18):7130–7135
Boparai HK, Joseph M, O’Carroll DM (2011) Kinetics and thermodynamics of cadmium ion removal by adsorption onto nano zerovalent iron particles. J Hazard Mater 186(1):458–465
Cheng Y, Dong H, Hao T (2021) CaCO3 coated nanoscale zero-valent iron (nZVI) for the removal of chromium (VI) in aqueous solution. Sep Purif Technol 257:117967
Dada AO, Adekola FA, Odebunmi EO (2017) Kinetics, mechanism, isotherm and thermodynamic studies of liquid phase adsorption of Pb2+ onto wood activated carbon supported zerovalent iron (WAC-ZVI) nanocomposite. Cogent Chemistry 3(1):1351653
Deng M, Wang X, Li Y, Wang F, Jiang Z, Liu Y, Gu Z, Xia S, Zhao J (2020) Reduction and immobilization of Cr (VI) in aqueous solutions by blast furnace slag supported sulfidized nanoscale zerovalent iron. Sci Total Environ 743:140722
Devi P, Saroha AK (2015) Simultaneous adsorption and dechlorination of pentachlorophenol from effluent by Ni–ZVI magnetic biochar composites synthesized from paper mill sludge. Chem Eng J 271:195–203
Du Q, Zhang S, Pan B, Lv L, Zhang W, Zhang Q (2013) Bifunctional resin-ZVI composites for effective removal of arsenite through simultaneous adsorption and oxidation. Water Res 47(16):6064–6074
Ebrahiminezhad A, Taghizadeh S, Ghasemi Y, Berenjian A (2018) Green synthesized nanoclusters of ultra-small zero valent iron nanoparticles as a novel dye removing material. Sci Total Environ 621:1527–1532
Eglal MM, Ramamurthy AS (2015) Removal of Pb (II), Cd (II), Cu (II) and trichloroethylene from water by Nanofer ZVI. Journal of Environmental Science and Health, Part A 50(9):901–912
Fu F, Dionysiou DD, Liu H (2014) The use of zero-valent iron for groundwater remediation and wastewater treatment: a review. J Hazard Mater 267:194–205
Galdames A, Ruiz-Rubio L, Orueta M, Sánchez-Arzalluz M, Vilas-Vilela JL (2020) Zero-Valent Iron Nanoparticles for Soil and Groundwater Remediation. Int J Environ Res Public Health 17(16):5817
Gil-Díaz M, Álvarez MA, Alonso J, Lobo MC (2020) Effectiveness of nanoscale zero-valent iron for the immobilization of Cu and/or Ni in water and soil samples. Sci Rep 10(1):1–10
He D, Ma X, Jones AM, Ho L, Waite TD (2016a) Mechanistic and kinetic insights into the ligand-promoted depassivation of bimetallic zero-valent iron nanoparticles. Environ Sci Nano 3(4):737–744
He X, Aker WG, Pelaez M, Lin Y, Dionysiou DD, Hwang HM (2016b) Assessment of nitrogen–fluorine-codoped TiO2 under visible light for degradation of BPA: implication for field remediation. J Photochem Photobiol, A 314:81–92
Hsieh WP, Pan JR, Huang C, Su YC, Juang YJ (2010) Enhance the photocatalytic activity for the degradation of organic contaminants in water by incorporating TiO2 with zero-valent iron. Sci Total Environ 408(3):672–679
Hua Z, Dai Z, Bai X, Pan W, Zhang X, Ma W, Huang X, Gu L (2014) Zero-valent nanophase iron and nitrogen co-modified titania nanotube arrays: Synthesis, characterization, and enhanced visible-light photocatalytic performance. Mater Sci Semicond Process 26:410–418
Jacob JM, Sinharoy A, Lens PN (2020) Photocatalytic degradation of Congo Red by zinc sulfide quantum dots produced by anaerobic granular sludge. Environ Technol. https://doi.org/10.1080/09593330.2020.1856940
Jia H, Wang C (2013) Comparative studies on montmorillonite-supported zero-valent iron nanoparticles produced by different methods: reactivity and stability. Environ Technol 34(1):25–33
Jiang Z, Lv L, Zhang W, Du Q, Pan B, Yang L, Zhang Q (2011) Nitrate reduction using nanosized zero-valent iron supported by polystyrene resins: role of surface functional groups. Water Res 45(6):2191–2198
Khuntia BK, Anwar MF, Alam T, Samim M, Kumari M, Arora I (2019) Synthesis and Characterization of Zero-Valent Iron Nanoparticles, and the Study of Their Effect against the Degradation of DDT in Soil and Assessment of Their Toxicity against Collembola and Ostracods. ACS Omega 4(20):18502–18509
Kim SA, Kamala-Kannan S, Lee KJ, Park YJ, Shea PJ, Lee WH, Oh BT (2013) Removal of Pb (II) from aqueous solution by a zeolite–nanoscale zero-valent iron composite. Chem Eng J 217:54–60
Kishimoto N, Narazaki Y, Takemoto K (2018) Reusability of zero-valent iron particles for zinc ion separation. Sep Purif Technol 193:139–146
Koutsospyros A, Pavlov J, Fawcett J, Strickland D, Smolinski B, Braida W (2012) Degradation of high energetic and insensitive munitions compounds by Fe/Cu bimetal reduction. J Hazard Mater 219:75–81
Krishnan SK, Subbiah K, Kalivel P, Subramanian K (2021) Degradation of azo dye RED ME4BL treated with immobilised bimetallic zero-valent iron nanoparticles doped with palladium. Int J Environ Anal Chem. https://doi.org/10.1080/03067319.2021.2007381
Kumar R, Rashid J, Barakat MA (2015) Zero valent Ag deposited TiO2 for the efficient photocatalysis of methylene blue under UV-C light irradiation. Colloids and Interface Science Communications 5:1–4. https://doi.org/10.1016/j.colcom.2015.05.001
Lai B, Zhang Y, Chen Z, Yang P, Zhou Y, Wang J (2014) Removal of p-nitrophenol (PNP) in aqueous solution by the micron-scale iron–copper (Fe/Cu) bimetallic particles. Appl Catal B 144:816–830
Lee C, Kim JY, Lee WI, Nelson KL, Yoon J, Sedlak DL (2008) Bactericidal effect of zero-valent iron nanoparticles on Escherichia coli. Environ Sci Technol 42(13):4927–4933
Li S, Wang W, Liang F, Zhang WX (2017) Heavy metal removal using nanoscale zero-valent iron (nZVI): theory and application. J Hazard Mater 322:163–171
Li Y, Zhang Y, Li J, Zheng X (2011) Enhanced removal of pentachlorophenol by a novel composite: nanoscale zero valent iron immobilized on organobentonite. Environ Pollut 159(12):3744–3749
Li Y, Zhao HP, Zhu L (2021) Remediation of soil contaminated with organic compounds by nanoscale zero-valent iron: A review. Sci Total Environ 760:143413
Liu F, Shan C, Zhang X, Zhang Y, Zhang W, Pan B (2017a) Enhanced removal of EDTA-chelated Cu (II) by polymeric anion-exchanger supported nanoscale zero-valent iron. J Hazard Mater 321:290–298
Liu J, Mwamulima T, Wang Y, Fang Y, Song S, Peng C (2017b) Removal of Pb (II) and Cr (VI) from aqueous solutions using the fly ash-based adsorbent material-supported zero-valent iron. J Mol Liq 243:205–211
Liu M, Wang Y, Chen L, Zhang Y, Lin Z (2015) Mg(OH)2 supported nanoscale zero valent iron enhancing the removal of Pb (II) from aqueous solution. ACS Appl Mater Interfaces 7(15):7961–7969
Liu Y, Wang J (2019) Reduction of nitrate by zero valent iron (ZVI)-based materials: a review. Sci Total Environ 671:388–403
Madaffari MG, Bilardi S, Calabro PS, Moraci N (2017) Nickel removal by zero valent iron/lapillus mixtures in column systems. Soils Found 57(5):745–759
Mandal S, Pu S, Wang X, Ma H, Bai Y (2020) Hierarchical porous structured polysulfide supported nZVI/biochar and efficient immobilization of selenium in the soil. Sci Total Environ 708:134831
Mesa-Medina S, Villajos B, Gascó A, Hermosilla D (2021) Cutting-edge materials combining zero-valent iron applied to the photocatalytic treatment of organic contaminants of emerging concern in wastewater. Current Opinion in Green and Sustainable Chemistry 30:100484. https://doi.org/10.1016/j.cogsc.2021.100484
Morrison SJ, Metzler DR, Dwyer BP (2002) Removal of As, Mn, Mo, Se, U, V and Zn from groundwater by zero-valent iron in a passive treatment cell: reaction progress modeling. J Contam Hydrol 56(1–2):99–116
Mortazavian S, An H, Chun D, Moon J (2018) Activated carbon impregnated by zero-valent iron nanoparticles (AC/nZVI) optimized for simultaneous adsorption and reduction of aqueous hexavalent chromium: Material characterizations and kinetic studies. Chem Eng J 353:781–795
Murtaza B, Shah NS, Sayed M, Khan JA, Imran M, Shahid M, Niazi NK (2019) Synergistic effects of bismuth coupling on the reactivity and reusability of zerovalent iron nanoparticles for the removal of cadmium from aqueous solution. Sci Total Environ 669:333–341
Nie X, Liu J, Zeng X, Yue D (2013) Rapid degradation of hexachlorobenzene by micron Ag/Fe bimetal particles. J Environ Sci 25(3):473–478
Niu H, Yang Y, Zhao W, Lv H, Zhang H, Cai Y (2021) Single-crystalline Fe7S8/Fe3O4 coated zero-valent iron synthesized with vacuum chemical vapor deposition technique: Enhanced reductive, oxidative and photocatalytic activity for water purification. J Hazard Mater 401:123442
Ombaka LM, Curti M, McGettrick JD, Davies ML, Bahnemann DW (2020) Nitrogen/Carbon-Coated Zero-Valent Copper as Highly Efficient Co-catalysts for TiO2 Applied in Photocatalytic and Photoelectrocatalytic Hydrogen Production. ACS Appl Mater Interfaces 12(27):30365–30380
Petala E, Dimos K, Douvalis A, Bakas T, Tucek J, Zbořil R, Karakassides MA (2013) Nanoscale zero-valent iron supported on mesoporous silica: characterization and reactivity for Cr (VI) removal from aqueous solution. J Hazard Mater 261:295–306
Radini IA, Hasan N, Malik MA, Khan Z (2018) Biosynthesis of iron nanoparticles using Trigonella foenum-graecum seed extract for photocatalytic methyl orange dye degradation and antibacterial applications. J Photochem Photobiol B: Biol 183:154–163
Raez JM, Arencibia A, Segura Y, Arsuaga JM, López-Muñoz MJ (2021) Combination of immobilized TiO2 and zero valent iron for efficient arsenic removal in aqueous solutions. Sep Purif Technol 258:118016
Rahman MU, Qazi UY, Hussain T, Nadeem N, Zahid M, Bhatti HN, Shahid I (2021) Solar driven photocatalytic degradation potential of novel graphitic carbon nitride based nano zero-valent iron doped bismuth ferrite ternary composite. Opt Mater 120:111408
Ruan Y, Zhang H, Yu Z, Diao Z, Song G, Su M, Hou LA, Chen D, Wang S, Kong L (2022) Phosphate enhanced uranium stable immobilization on biochar supported nano zero valent iron. J Hazard Mater 424:127119
Sheng G, Tang Y, Linghu W, Wang L, Li J, Li H, Wang X, Huang Y (2016) Enhanced immobilization of ReO4− by nanoscale zerovalent iron supported on layered double hydroxide via an advanced XAFS approach: Implications for TcO4− sequestration. Appl Catal B 192:268–276
Shih YH, Tso CP, Tung LY (2010) Rapid degradation of methyl orange with nanoscale zerovalent iron particles. Nanotechnology 7(16):7
Sinharoy A, Baskaran D, Pakshirajan K (2020a) Process integration and artificial neural network modeling of biological sulfate reduction using a carbon monoxide fed gas lift bioreactor. Chem Eng J 391:123518
Sinharoy A, Lens PN (2020) Biological removal of selenate and selenite from wastewater: options for selenium recovery as nanoparticles. Current Pollution Reports 6:230–249
Sinharoy A, Pakshirajan K (2019) Heavy metal sequestration by sulfate reduction using carbon monoxide as the sole carbon and energy source. Process Biochem 82:135–143
Sinharoy A, Pakshirajan K, Lens PN (2020b) Biological sulfate reduction using gaseous substrates to treat acid mine drainage. Current Pollution Reports 6:328–344
Statham TM, Mumford KA, Stark SC, Gore DB, Stevens GW (2015) Removal of copper and zinc from ground water by granular zero-valent iron: a mechanistic study. Sep Sci Technol 50(16):2427–2435
Sun YP, Li XQ, Cao J, Zhang WX, Wang HP (2006) Characterization of zero-valent iron nanoparticles. Adv Coll Interface Sci 120(1–3):47–56
Sun YP, Li XQ, Zhang WX, Wang HP (2007) A method for the preparation of stable dispersion of zero-valent iron nanoparticles. Colloids Surf, A 308(1–3):60–66
Tang W, Li Q, Gao S, Shang JK (2011) Arsenic (III, V) removal from aqueous solution by ultrafine α-Fe2O3 nanoparticles synthesized from solvent thermal method. J Hazard Mater 192(1):131–138
Tarekegn MM, Hiruy AM, Dekebo AH (2021) Nano zero valent iron (nZVI) particles for the removal of heavy metals (Cd2+, Cu2+ and Pb2+) from aqueous solutions. RSC Adv 11(30):18539–18551
Vilardi G, Di Palma L, Verdone N (2019) A physical-based interpretation of mechanism and kinetics of Cr (VI) reduction in aqueous solution by zero-valent iron nanoparticles. Chemosphere 220:590–599
Vogel M, Georgi A, Kopinke FD, Mackenzie K (2019) Sulfidation of ZVI/AC composite leads to highly corrosion-resistant nanoremediation particles with extended life-time. Sci Total Environ 665:235–245
Wang X, Wang A, Lu M, Ma J (2018) Synthesis of magnetically recoverable Fe0/graphene-TiO2 nanowires composite for both reduction and photocatalytic oxidation of metronidazole. Chem Eng J 337:372–384
Wang X, Xie Y, Ma J, Ning P (2019) Facile assembly of novel gC 3 N 4@ expanded graphite and surface loading of nano zero-valent iron for enhanced synergistic degradation of tetracycline. RSC Adv 9(59):34658–34670
Wang Y, Gong Y, Lin N, Yu L, Du B, Zhang X (2022) Enhanced removal of Cr (VI) from aqueous solution by stabilized nanoscale zero valent iron and copper bimetal intercalated montmorillonite. J Colloid Interface Sci 606:941–952
Wu, Y., Guan, C. Y., Griswold, N., Hou, L. Y., Fang, X., Hu, A., ... & Yu, C. P. (2020). Zero-valent iron-based technologies for removal of heavy metal (loid) s and organic pollutants from the aquatic environment: recent advances and perspectives. Journal of Cleaner Production, 123478.
Wu Y, Yue Q, Ren Z, Gao B (2018) Immobilization of nanoscale zero-valent iron particles (nZVI) with synthesized activated carbon for the adsorption and degradation of Chloramphenicol (CAP). J Mol Liq 262:19–28
Xi Y, Mallavarapu M, Naidu R (2010) Reduction and adsorption of Pb2+ in aqueous solution by nano-zero-valent iron—a SEM, TEM and XPS study. Mater Res Bull 45(10):1361–1367
Xu F, Deng S, Xu J, Zhang W, Wu M, Wang B, Yu G (2012) Highly active and stable Ni–Fe bimetal prepared by ball milling for catalytic hydrodechlorination of 4-chlorophenol. Environ Sci Technol 46(8):4576–4582
Yun DM, Cho HH, Jang JW, Park JW (2013) Nano zero-valent iron impregnated on titanium dioxide nanotube array film for both oxidation and reduction of methyl orange. Water Res 47(5):1858–1866
Zhang J, Zhang T, Liang X, Wang Y, Shi Y, Guan W, Liu D, Ma X, Pang J, Xie X, Hong K (2020) Efficient photocatalysis of CrVI and methylene blue by dispersive palygorskite-loaded zero-valent iron/carbon nitride. Appl Clay Sci 198:105817
Zhou L, Li R, Zhang G, Wang D, Cai D, Wu Z (2018) Zero-valent iron nanoparticles supported by functionalized waste rock wool for efficient removal of hexavalent chromium. Chem Eng J 339:85–96
Zhou Y, Gao B, Zimmerman AR, Chen H, Zhang M, Cao X (2014) Biochar-supported zerovalent iron for removal of various contaminants from aqueous solutions. Biores Technol 152:538–542
Zhou Z, Dai C, Zhou X, Zhao J, Zhang Y (2015) The removal of antimony by novel NZVI-zeolite: the role of iron transformation. Water Air Soil Pollut 226(3):1–16
Zou Y, Wang X, Khan A, Wang P, Liu Y, Alsaedi A, Wang X (2016) Environmental remediation and application of nanoscale zero-valent iron and its composites for the removal of heavy metal ions: a review. Environ Sci Technol 50(14):7290–7304
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Sinharoy, A., Uddandarao, P. (2023). Zero-Valent Nanomaterials for Wastewater Treatment. In: Shah, M.P. (eds) Advanced Application of Nanotechnology to Industrial Wastewater. Springer, Singapore. https://doi.org/10.1007/978-981-99-3292-4_4
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