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Development of Hierarchical MCM-22 Layered Zeolite for Selective Glycerol Dehydration

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Advances in Spectroscopy: Molecules to Materials

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 236))

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Abstract

MCM-22 (SiO2/Al2O3 = 30) was synthesized using colloidal silica and modified in the presence of an organic template, surface active agent, and strong base under alkali treatment conditions. The catalyst characterization techniques confirmed its improved physical and structural properties. The results of the characterization show that modified MCM-22 plays significant role in structure, acidity, and desilication. The experimental studies revealed that hierarchical catalyst was formed by organic species—hexamethyleneimine (HMI) and quaternary ammonium hydroxide (TPAOH), which raised the pH of the solution, thereby increased the solubility of silica in the presence of sodium hydroxide and created mesoporosity. MCM-22 and modified MCM-22 show vital role in catalytic selective glycerol dehydration.

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Authors and Affiliations

  1. School of Technology, Department of Science, Pandit Deendayal Petroleum University, Gandhinagar, 382007, India

    Riddhi Thakkar & Rajib Bandyopadhyay

Authors
  1. Riddhi Thakkar
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  2. Rajib Bandyopadhyay
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Correspondence to Rajib Bandyopadhyay .

Editor information

Editors and Affiliations

  1. Department of Physics, Institute of Infrastructure Technology Research And Management, Ahmedabad, Gujarat, India

    Dheeraj Kumar Singh

  2. Department of Chemistry, Institute of Infrastructure Technology Research And Management, Ahmedabad, Gujarat, India

    Sourav Das

  3. Department of Physics and Earth Science, Jacobs University Bremen gGmbH, Bremen, Germany

    Arnulf Materny

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Thakkar, R., Bandyopadhyay, R. (2019). Development of Hierarchical MCM-22 Layered Zeolite for Selective Glycerol Dehydration. In: Singh, D., Das, S., Materny, A. (eds) Advances in Spectroscopy: Molecules to Materials. Springer Proceedings in Physics, vol 236. Springer, Singapore. https://doi.org/10.1007/978-981-15-0202-6_22

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  • DOI: https://doi.org/10.1007/978-981-15-0202-6_22

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  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-15-0201-9

  • Online ISBN: 978-981-15-0202-6

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