Skip to main content

Oxygen Permeability of Layer Silicate Reinforced Polymer Nanocomposites

  • Chapter
  • First Online:
Nanoclay Reinforced Polymer Composites

Part of the book series: Engineering Materials ((ENG.MAT.))

  • 1162 Accesses

Abstract

Reinforcement of organically modified nanoclay into different synthetic and biopolymer matrices was performed by several techniques. For high density polyethylene (HDPE) and polyamide (PA6) based nanocomposites, single screw compounding process was adopted, whereas; for polymethylmethacrylate (PMMA), polyacrylonitrile (PAN) based nanocomposites in situ polymerization technique was taken into consideration. For protein and biopolymer based nanocomposites; nano clays were made to disperse through solution casting technique. The structural analysis of all the polymer/clay nanocomposites or bionanocomposites was performed through X-ray diffraction (XRD) and Fourier transform infrared (FTIR) studies, whereas; the morphological analysis was carried out through transmission electron microscope (TEM). The oxygen permeability of nano clay reinforced polymer nanocomposites was measured as function of clay content and pressure. It was found to be decreased with increase in clay content as compared to their neat polymers. Along with the clay content, ultrasonic treatment also affect the nature of dispersion of nanoclay and thereby the oxygen permeability of the fabricated nanocomposites. The enhanced obstacle towards the path of gas transportation within the fabricated polymer nanocomposite may enable the material for food packaging applications.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Abreu, D., Losada, P., Angulo, I., Cruz, J.M.: Development of new polyolefin films with nanoclays for application in food packaging. Eur. Polym. J. 43, 2229–2243 (2007)

    Article  Google Scholar 

  • Ball, A., Jones, R.A.L.: Conformational changes in adsorbed proteins. Langmuir 11, 3542–3548 (1995)

    Article  Google Scholar 

  • Barbee, R., Matayabas, C.: Nanocomposites for high barrier applications (2002). United States Patent WO2000078855A1, 26 Nov 2002

    Google Scholar 

  • Boricha, A.B., Mody, H.M., Das, A., Bajaj, H.C.: Facile dehydroxylation of styrene using clay based catalyst. Appl. Catal. A Gen. 179, 5–10 (1999)

    Article  Google Scholar 

  • Dash, S., Kisku, S.K., Swain, S.K.: Effect of nanoclay on morphological, thermal, and barrier properties of albumin bovine. Polym. Compos. 33, 2201–2206 (2012)

    Article  Google Scholar 

  • Dash, S., Swain, S.K.: Effect of nano-boron nitride on the physical and chemical properties of soy protein. Compos. Sci. Technol. 84, 39–43 (2013a)

    Article  Google Scholar 

  • Dash, S., Swain, S.K.: Synthesis of thermal and chemical resistant oxygen barrier starch with reinforcement of nano silicon carbide. Carbohydr. Polym. 97, 758–763 (2013b)

    Article  Google Scholar 

  • Dons, A., Steven, J., Prestrelski, S.J., Allison, S., Carpenter, J.F.: Infrared spectroscopic studies of lyophilization and temperature-induced protein aggregation. J. Pharm. Sci. 84, 415–424 (1995)

    Article  Google Scholar 

  • Frounchi, M., Dadbin, S., Salehpour, Z., Noferesti, M.: Gas barrier properties of PP/EPDM blend nanocomposites. J. Membr. Sci. 282, 142–148 (2006)

    Article  Google Scholar 

  • Fukushima, Y., Inagoki, S.: Synthesis of an intercalating compound of monontmorilonite and 6-polyamide. J Inclusion Phenom 5, 473–482 (1987)

    Article  Google Scholar 

  • Gilman, J.W.: Flammability and thermal stability studies of polymer layered-silicate (clay) nanocomposites. Appl. Clay Sci. 15, 31–49 (1999)

    Article  Google Scholar 

  • Halligudi, S.B., Bajaj, H.C., Bhatt, K.N., Krishnaratnam, M.: Hydrogenation of benzene to cyclohexane catalyzed by rhodium (I) complex supported an Montmorillonite clay. React. Kinet. Catal. Lett. 48, 547–552 (1992)

    Article  Google Scholar 

  • Jang, B.Z.: Nanocomposite compositions for hydrogen storage and methods for supplying hydrogen to fuel cells (2006). US2006030483, 09 Feb 2006

    Google Scholar 

  • Khan, B.T., Najmuddin, K., Shamsuddin, S., Annapooma, K., Bhatt, J.: synthesis, antimicrobial antitumor activity of a series of palladium (II) mixed ligand complexes. J. Inorg. Biochem. 44, 55–63 (1991)

    Article  Google Scholar 

  • Kim, M.H., Lee, S.H.: Nanocomposite blend composition having excellent barrier property (2006). JP2006328426, 07 Dec 2006

    Google Scholar 

  • Kisku, S.K., Sarkar, N., Dash, S., Swain, S.K.: Preparation of starch/PVA/CaCO3 nanobiocomposite films: study of fire retardant, thermal resistant, gas barrier and biodegradable properties. Polym. Plast. Technol. Eng. 53, 1664–1670 (2014)

    Article  Google Scholar 

  • Kisku, S.K., Swain, S.K.: Synthesis and characterization of chitosan/boron nitride composites. J. Am. Ceram. Soc. 95, 2753–2757 (2012)

    Article  Google Scholar 

  • Lapshin, S., Swain, S.K., Isayev, A.I.: Ultrasound aided extrusion process for preparation of polyolefin-clay nanocomposites. Polym. Eng. Sci. 48, 1584–1591 (2008)

    Article  Google Scholar 

  • Lv, J., Liu, W.: Flame retardancy and mechanical properties of EVA nanocomposites based on magnesium hydroxide nanoparticles/microcapsulated red phosphorus. J. Appl. Polym. Sci. 105, 333–340 (2007)

    Article  Google Scholar 

  • Oh, J.S., Isayev, A.I., Rogunova, M.A.: Continuous ultrasonic process for in situ compatibilization of polypropylene/natural rubber blends. Polymer 44, 2337–2349 (2003)

    Article  Google Scholar 

  • Osman, M., Atallah, A.: High-density polyethylene micro- and nanocomposites: effect of particle shape, size and surface treatment on polymer crystallinity and gas permeability. Macromol. Rapid Commun. 25, 1540–1544 (2004)

    Article  Google Scholar 

  • Park, K., Chowdhury, S.R., Park, C., Kim, G.: Effect of dispersion state of organoclay on cellular foam structure and mechanical properties of ethylene vinyl acetate copolymer/ethylene-1-butenecopolymer/organoclay nanocomposite foams. J. Appl. Polym. Sci. 104, 3879–3885 (2007)

    Google Scholar 

  • Patra, S.K., Swain, S.K.: Effect of organoclays on the thermal, mechanical, and oxygen barrier properties of poly (methylmethacrylateco-acrylonitrile)/clay nanocomposites. Polym. Compos. 33, 796–802 (2012)

    Article  Google Scholar 

  • Patra, S.K., Prusty, G., Swain, S.K.: Ultrasound assisted sythesis of PMMA/clay nanocomposites: study of oxygen permeation and flame retardant properties. Bull. Mater. Sci. 35, 27–32 (2012)

    Article  Google Scholar 

  • Patra, S.K., Prusty, G., Swain, S.K.: Synthesis of PAN/clay nanocomposites: study of gas permeation properties. Int. J. Nanosci. 10, 1101–1105 (2011)

    Article  Google Scholar 

  • Patra, S.K., Prusty, G., Swain, S.K.: Ultrasound assisted synthesis of PMMA/clay nanocomposites: study of oxygen permeation and flame retardant properties. Bull. Mater. Sci 35, 27–32 (2012)

    Google Scholar 

  • Pradhan, A.K., Swain, S.K.: Electrical conductivity and oxygen permeability of polyacrylonitrile/multiwalled carbon nanotubes composites. Polym. Compos. 33, 1114–1119 (2012)

    Article  Google Scholar 

  • Prasad, K., Grubb, D.T.: Direct observation of taut tie molecules in high-strength polyethylene fibers by Raman spectroscopy. J. Polym. Sci. Part B Polym. Phys. 27, 381–403 (1989)

    Article  Google Scholar 

  • Rana, P.K., Swain, S.K., Sahoo, P.K.: Synthesis, characterization, and properties of intercalated poly (2-ethyl hexylacrylate)/silicate nanocomposites: XRD, TEM, IR, TGA, superabsorbency, pressure-sensitive adhesion, and biodegradation. J. Appl. Polym. Sci. 93, 1007–1011 (2004)

    Google Scholar 

  • Sahoo, P.K., Dey, M., Swain, S.K.: Emulsifier-free emulsion polymerization of acrylonitrile: effect of in situ developed Cu (II)/glycine chelate complex initiated by monopersulfate. J. Appl. Polym. Sci. 74, 2785–2790 (1999)

    Google Scholar 

  • Sahoo, P.K., Samal, R., Swain, S.K., Rana, P.K.: Synthesis of poly (butyl acrylate)/sodium silicate nanocomposite fire retardant. Eur. Polym. J. 44, 3522–3528 (2008)

    Article  Google Scholar 

  • Sikdar, D., Katti, D., Kalpana, K., Mohanty, B.: Effect of organic modifiers on dynamic and static nano-mechanical properties and crystallinity of intercalated clay-polycaprolactam nanocomposites. J. Appl. Polym. Sci. 105, 790–802 (2007)

    Google Scholar 

  • Swain, S.K.: Ultrasound assisted process of PA6/clay nanocomposites: mechanical, rheological and barrier properties. J. Polym. Eng. 31, 185–189 (2011)

    Article  Google Scholar 

  • Swain, S.K., Isayev, J.S.: Effect of ultrasound on HDPE/clay nanocomposites: rheology, structure and properties. Polymer 48, 281–289 (2007)

    Article  Google Scholar 

  • Swain, S.K., Kisku, S.K., Sahoo, G.: Preparation of thermal resistant gas barrier chitosan nanobiocomposites. Polym. Compos. 35, 2324–2328 (2014)

    Article  Google Scholar 

  • Swain, S.K., Priyadarshini, P.P., Patra, S.K.: Soy protein/clay bionanocomposites as ideal packaging materials. Polym. Plast. Technol. Eng. 51, 1282–1287 (2012)

    Article  Google Scholar 

  • Swain, S.K., Prusty, G., Jena, I.: Conductive, gas barrier, and thermal resistant behaviour of poly (methyl methacrylate) composite by dispersion of ZrO2 nanoparticles. Int. J. Polym. Mater. Polym. Biomater. 62, 733–736 (2013)

    Article  Google Scholar 

  • Swain, S.K., Isayev, A.I.: PA6/clay nanocomposites by continuous sonication process. J. Appl. Polym. Sci. 114, 2378–2387 (2009)

    Article  Google Scholar 

  • Wang, X., Du, Y., Yang, J., Wang, X., Shi, Y., Hu, X.: Preparation, characterization and antimicrobial activity of chitosan/layered silicate nanocomposites. Polymer 47, 6738–6744 (2006)

    Article  Google Scholar 

  • Yang, Y., Gu, H.: Preparation and properties of deep dye fibers from poly (ethylene terephthalate)/SiO2 nanocomposites by in situ polymerization. J. Appl. Polym. Sci. 105, 2363–2369 (2007)

    Article  Google Scholar 

  • Zhang, J., Zhuag, W., Zhang, Q., Liu, B., Wang, W., Hu, B., Shen, J.: Novel polylactide/vermiculite nanocomposites by in situ intercalative polymerization. I. Preparation, characterization, and properties. Polym. Compos. 28, 545–550 (2007)

    Article  Google Scholar 

  • Zhong, Y., Janes, D., Zhang, Y., Hetzer, M., Kee, D.: Mechanical and oxygen barrier properties of organoclay-polyethylene nanocomposite films. Polym. Eng. Sci. 47, 1101–1107 (2007)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sarat K. Swain .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2016 Springer Science+Business Media Singapore

About this chapter

Cite this chapter

Swain, S.K., Sarkar, N., Sahoo, G., Sahu, D. (2016). Oxygen Permeability of Layer Silicate Reinforced Polymer Nanocomposites. In: Jawaid , M., Qaiss, A., Bouhfid, R. (eds) Nanoclay Reinforced Polymer Composites. Engineering Materials. Springer, Singapore. https://doi.org/10.1007/978-981-10-1953-1_6

Download citation

Publish with us

Policies and ethics