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Tropospheric Ozone: Distribution and Sources

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Global Atmospheric Chemical Change

Abstract

One of the most active research areas of tropospheric chemistry is the study of the processes responsible for the formation and destruction of ozone. This interest is derived from the three-fold importance of ozone in the troposphere.

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References

  1. US Congress, Office of Technology Assessment, Catching our breath: next steps for reducing urban ozone. OTA-0–412, Washington, DC, 1989.

    Google Scholar 

  2. Gidel, L. T. & Shapiro, M., General atmospheric model estimates of the vertical flow of ozone in the lower stratosphere and the implications for the troposphere ozone budget J. Geophys. Res., 85 (1980) 4049–58.

    Article  CAS  Google Scholar 

  3. Mahlman, J. D., Levy, H. II & Moxim, W. J., Three-dimensional tracer structure and behavior as simulated in two ozone precursor experiments. J. Atmos. Sci., 37 (1980) 655–85.

    Article  Google Scholar 

  4. Danielsen, E. F. & Mohnen, V. A., Project Duststorm report: Ozone transport, in situ measurements, and meteorological analyses of tropopause folding. J. Geophys. Res., 82 (1977) 5867–77.

    Article  CAS  Google Scholar 

  5. Regener, E., Ozonschicht und atmosphärische turbulenz. Ber. deut. Wetérdienstes US-Zone, 11 (1949) 45–57.

    Google Scholar 

  6. Fishman, J., Solomon, S. & Crutzen, P. J., Observational and theoretical evidence in support of a significant in-situ photochemical source of tropospheric ozone. Tellus, 31 (1979) 432–46.

    Article  CAS  Google Scholar 

  7. Liu, S. C., Kley, D., McFarland, M., Mahlman, J. D. & Levy, H., II, On the origin of tropospheric ozone. J. Geophys. Res., 85 (1980) 7546–52.

    Article  CAS  Google Scholar 

  8. Liu, S. C. & Trainer, M., Responses of the tropospheric ozone and odd hydrogen radicals to column ozone change. J. Atmos. Chem., 6 (1988) 221–34.

    Article  CAS  Google Scholar 

  9. Aldaz, L., Flux measurements of atmospheric ozone over land and water. J. Geophys. Res., 74 (1969) 6943–6.

    Article  Google Scholar 

  10. Galbally, I. E. & Roy, C. R., Destruction of ozone at the earth’s surface. Quart. J. Roy. Meteorol. Soc., 106 (1980) 599–620.

    Article  CAS  Google Scholar 

  11. Wesely, M. L., Turbulent transport of ozone to surfaces common in the eastern half of the United States. In Trace Atmospheric Constituents, ed. S. E. Schwartz. John Wiley, New York, 1983, pp. 345–70.

    Google Scholar 

  12. Lenschow, D. H., Pearson, R., Jr. & Stankor, B. B., Measurements of ozone vertical flux to ocean and forest. J. Geophys. Res., 87 (1982) 8833–7.

    Article  CAS  Google Scholar 

  13. Colbeck, I. & Harrison R. M., Dry deposition of ozone: Some measurements of deposition velocity and of vertical profiles to 100 meters. Atmos. Environ., 19 (1985) 1807–18.

    Article  CAS  Google Scholar 

  14. Logan, J. A., Prather, M. J., Wofsy, S. C. & McElroy, M. B., Tropospheric chemistry: A global perspective. J., Geophys. Res., 86 (1981) 7210–54.

    Article  CAS  Google Scholar 

  15. Singh, H. B., Salas, L. J., Ridley, B. A., Shetter, J. D., Donahue, N. M., Fehsenfeld, F. C., Fahey, D. W., Parrish, D. D., Williams, E. J., Liu, S. C., Hübler, G. & Murphy, P. C., Relationship between peroxyacetyl nitrate (PAN) and nitrogen oxides in the clean troposphere. Nature, 318 (1985) 347–9.

    Article  CAS  Google Scholar 

  16. Liu, S. C., Trainer, M., Fehsenfeld, F. C., Parrish, D. D., Williams, E. J., Fahey, D. W., Hübler, G. & Murphy, P. C., Ozone production in the rural troposphere and the implications for regional and global ozone distributions. J. Geophys. Res., 92 (1987) 4191–207.

    Article  CAS  Google Scholar 

  17. Fehsenfeld, F. C., Parrish, D. D. & Fahey, D. W., The measurements of NO„ in the non-urban troposphere. In Tropospheric Ozone, ed. I. S. A. Isaksen. D. Reidel, Norwell, MA, 1988, pp. 185–215.

    Chapter  Google Scholar 

  18. McKeen, S. A., Hsie, E. Y., Trainer M., Tallamraju, R. & Liu, S. C., A regional model study of the ozone budget in the Eastern United States. J. Geophys. Res.,96 (1991) 10809–45.

    Google Scholar 

  19. Mohnen, V. A., Hogan, A. & Coffey, P., Ozone measurements in rural areas. J. Geophys. Res., 82 (1977) 5889–95.

    Article  CAS  Google Scholar 

  20. Logan, J. A., Tropospheric ozone: Seasonal behavior trends, and anthropogenic influence. J. Geophys. Res.,90 (1985) 10463–82.

    Article  Google Scholar 

  21. Logan, J. A., The ozone problem in the rural areas of the United States. In Proceedings of the NATO Advanced Research Workshop on Regional and Global Ozone and its Environmental Consequences, ed. I. S. A. Isaksen. NATO ASI Series C, 227, Reidel, Dordrecht, 1988, pp. 327–44.

    Google Scholar 

  22. Logan, J. A., Ozone in rural areas of the United States. J. Geophys. Res., 94 (1989) 8511–32.

    Article  CAS  Google Scholar 

  23. Fishman, J., Watson, C. E., Larsen, J. C. & Logan, J. A., Distribution of tropospheric ozone determined from satellite data. J. Geophys. Res., 85 (1990) 3599–618.

    Article  Google Scholar 

  24. Levy, H., II, Mahlman, J. D., Moxim, W. J. & Liu, S. C., Tropospheric ozone: The role of transport. J. Geophys. Res., 90 (1985) 3753–72.

    Article  CAS  Google Scholar 

  25. Fabian, P., Libby, W. F. & Palmer, C. E. Stratospheric residence time and interhemispheric mixing of strontium 90 from fallout in rain. J. Geophys. Res., 73 (1968) 3611–16.

    Article  Google Scholar 

  26. Chatfield, R. & Harrison, H., Tropospheric ozone H. Variations along a meridional band, J. Geophys. Res., 82 (1977) 5969–76.

    Article  CAS  Google Scholar 

  27. Chatfield, R. & Harrison, H., Tropospheric ozone II. Variations along a meridional band, J. Geophys. Res., 82 (1977) 5969–76.

    Article  CAS  Google Scholar 

  28. Staley, D. O., Strontium-90 in surface air and the stratosphere: Some interpretations of the 1963–1975 data. J. Atmos. Sci., 39 (1981) 1571–90.

    Article  Google Scholar 

  29. Penkett, S. A. & Brice, K. A., The spring maximum in photo-oxidants in the Northern Hemisphere troposphere. Nature, 319 655–8, (1986).

    Article  CAS  Google Scholar 

  30. Fishman, J., personal communication, 1990.

    Google Scholar 

  31. Cox, R. A., Eggleton, A. E. J., Derwent, R. G., Lovelock J. E. & Pack, D. E., Long-range transport of photochemical ozone in North-western Europe. Nature, 255, (1975) 118–21.

    Article  CAS  Google Scholar 

  32. Guicherit, R. & VanDop, H., Photochemical production of ozone in Western Europe (1971–1975) and its relation to meteorology. Atmos. Environ., 11 (1977) 145–56.

    Article  CAS  Google Scholar 

  33. Greenfelt, P. & Schjoldager, J., Photochemical oxidants in the troposphere: A mounting menace. Ambio, 13 (1984) 61–7.

    Google Scholar 

  34. Research Triangle Institute, Investigations of rural oxidant levels as related to urban hydrocarbon control strategies. EPA–450/3–75–036, Environmental Protection Agency, Research Triangle Park, NC, 1975, p. 359.

    Google Scholar 

  35. Vukovich, F. M., Bach, W. D., Jr., Crissman, B. W. & King, W. J., On the relationship between high ozone in the rural surface layer and high pressure systems. Atmos. Environ., 11 (1977) 967–84.

    Article  CAS  Google Scholar 

  36. Vukovich, F. M., Fishman, J. & Browell, E. V., The reservoir of ozone in the boundary layer of the eastern United States and its potential impact on the global tropospheric ozone budget. J. Geophys. Res., 90 (1985) 5687–98.

    Article  CAS  Google Scholar 

  37. Isaksen, I. S. A., Hov, O. & Hesstvedt, E., Ozone generation over rural areas. Environ. Sci. & Tech., 12 (1978) 1279–84.

    Article  CAS  Google Scholar 

  38. Fehsenfeld, F. C., Bollinger, M. J., Liu, S. C., Parrish, D. D., McFarland, M., Trainer, M., Kley, D., Murphy, P. C., Albritton, D. L. & Lenschow, D. H., A study of ozone in the Colorado mountains. J. Atmos. Chem., 1 (1983) 87–105.

    Article  CAS  Google Scholar 

  39. Volz, A. & Kley, D., Evaluation of the Montsouris series of ozone measurements made in the nineteenth century, Nature, 332 (1988) 260–2.

    Article  Google Scholar 

  40. Oltmans, S. J., Surface ozone measurements in clean air. J. Geophys. Res., 86 (1981) 1174–80.

    Article  CAS  Google Scholar 

  41. Liu, S. C., McFarland, M., Kley, D., Zafiriou, O. & Huebert, B., Tropospheric NOx and 03 budgets in the equatorial Pacific. J. Geophys. Res., 88 (1983) 1360–8.

    Article  CAS  Google Scholar 

  42. Angel, J. K., personal communication, 1989.

    Google Scholar 

  43. Angel, J. K., personal communication, 1991.

    Google Scholar 

  44. Wang, W.C., Wuebbles, D. J., Washington, W. M., Isaacs, R. G. & Molnar, G., Trace gases and other potential perturbations to global climate. Rev. Geophys. (1986) 110–40.

    Google Scholar 

  45. Environmental Protection Agency, Development of the 1980 NAPAP Emissions Inventory. EPA/600/4–85–038, US Environmental Protection Agency, Research Triangle, Park, NC, 1986.

    Google Scholar 

  46. Lübkert, B. & Zierock, K.-H., European emission inventories-A proposal of international worksharing. Atmos. Environ., 23 (1989) 37–48.

    Article  Google Scholar 

  47. Lübkert, B. & De Tilly, S., The OECD-Map emission inventory for SO2, NO, and VOC in Western Europe. Atmos. Environ., 23 (1989) 3–15.

    Article  Google Scholar 

  48. Logan, J. A., Nitrogen oxides in the troposphere: Global and regional budget. J. Geophys. Res. 88 (1983) 10785–807.

    Article  CAS  Google Scholar 

  49. Crutzen, P. J., Heidt, L. E., Krasnec, J. P., Pollock, W. H. & Seiler, W., Biomass burning as a source of atmospheric gases CO, H2, N20, NO, CH3CI and COS. Nature, 282 (1979) 253–6.

    Article  CAS  Google Scholar 

  50. Crutzen, P. J., Delany, A. C., Greenberg, J., Haagenson, P., Heidt, L., Lueb, R., Pollock, W., Seiler, W., Wartburg, A. & Zimmerman, P., Tropospheric chemical composition measurements in Brazil during the dry season. J. Atmos. Chem., 2 (1985) 233–56.

    Article  CAS  Google Scholar 

  51. Greenberg, J. P. Zimmerman, P. R., Heidt, L. & Pollock, W., Hydrocarbon and carbon monoxide emissions from biomass burning in Brazil. J. Geophys. Res.,89 (1984) 1350–4.

    Article  CAS  Google Scholar 

  52. Andreae, M. O., Browell, E. V., Garstang, M., Gregory, G. L., Harriss, R. C., Hill, G. F., Jacob, D. J., Pereira, M. C., Sachse, G. W., Setzer, A. W., Silva Dias, P. L, Talbot, R. W., Torres, A. L. & Wofsy, S. C., Biomass-burning emissions and associated haze layers of Amazonia. J. Geophys. Res., 93 (1988) 1509–27.

    Article  CAS  Google Scholar 

  53. Crutzen, P. J. & Andreae, M. O., Biomass burning in the tropics: Impact on atmospheric chemistry and biogeochemical cycles. Science, 250 (1990) 1669–78.

    Article  CAS  Google Scholar 

  54. Galbally, I. E. & Roy, C. R., Loss of fixed nitrogen from soils by nitric oxide exhalation. Nature, 275 (1978) 734–5.

    Article  CAS  Google Scholar 

  55. Galbally, I. E., Factors controlling NOx emissions from soils. In Exchange of Trace Gases Between Terrestrial Ecosystems and the Atmosphere. John Wiley & Sons, New York, 1989, pp. 23–37.

    Google Scholar 

  56. Johansson, C. & Granat, L., Emission of nitric oxide from arable land. Tel-lus,36B (1984) 25–37.

    Google Scholar 

  57. Johansson, C., Field measurements of nitric oxide emissions from fertilized and unfertilized forest soils in Sweden. J. Atmos. Chem., 1 (1984) 429–42.

    Article  CAS  Google Scholar 

  58. Slemr, R. & Seiler, W., Field measurements of NO and NO2 emissions from fertilized and unfertilized soils. J. Atmos. Chem., 2 (1984) 1–24.

    Article  CAS  Google Scholar 

  59. Galbally, I. E., Roy, C. R., Elsworth, C. M. & Rabich, H. A. H., The measurement of nitrogen oxide (NO and NO2) exchange over plant/soil surfaces, Division of Atmospheric Research Technical Paper 8, Commonwealth Scientific and Industrial Research Organization, Australia, 1985.

    Google Scholar 

  60. Anderson, I. C. & Levine, J. S., Simultaneous field measurements of nitric oxide and nitrous oxide. J. Geophys. Res., 92 (1987) 965–76.

    Article  CAS  Google Scholar 

  61. Williams, E. J., Parrish, D. D. & Fehsenfeld, F. C., Determination of nitric oxide emissions from a grassland site in Colorado, United States. J. Geophys. Res., 92 2173–9.

    Google Scholar 

  62. Galbally, E. I., Freney, J. R., Muirhead, W.A., Simpson, J.R., Trevitt, A. C. F. & Chalk, P. M., Emission of nitrogen oxides (NO„) from a flooded soil fertilized with urea; Relation to other nitrogen loss processes. J. Atmos. Chem., 5 (1987) 343–65.

    Article  Google Scholar 

  63. Williams, E. J., Parrish, D. D., Buhr, M. P., Fehsenfeld, F. C. & Fall, R., Measurement of soil NO, emissions in Central Pennsylvania. J. Geophys. Res., 93 (1988) 9539–46.

    Article  CAS  Google Scholar 

  64. Johansson, C., Rodhe H. & Sanhueza, E., Emission of NO in a tropical savanna and a cloud forest during the dry season. J. Geophys. Res., 93 (1988) 7180–92.

    Article  CAS  Google Scholar 

  65. Kaplan, W. A., Wofsy, S. C., Keller, M. & DaCosta, J. M., Emission of NO and deposition of 03 in a tropical forest system. J. Geophys. Res., 93 (1988) 1389–95.

    Article  CAS  Google Scholar 

  66. Anderson, I. C., Levine, J. S., Poth, M. A. & Riggan, P. J., Enhanced biogenic emissions of nitric oxide and nitrous oxide following surface biomass burning. J. Geophys. Res., 93 (1988) 3893–8.

    Article  CAS  Google Scholar 

  67. Johansson, C., Rodhe, H. & Sanhueza, E., Emission of NO in a tropical savanna and a cloud forest during the dry season. J. Geophys. Res., 93 (1988) 7180–92.

    Article  CAS  Google Scholar 

  68. Duffy, L., Galbally, I. E. & Elsworth, C. M., Biogenic NO, emissions in the Latrobe Valley. Clean Air, 22 (1988) 196–8.

    Google Scholar 

  69. Ko, M. K. W., McElroy, M. B., Weisenstein, D. K. & Sze, N. D., Lightning: A possible source of stratospheric odd nitrogen. J. Geophys. Res., 91 (1986) 5395–405.

    Article  CAS  Google Scholar 

  70. Murphy, D. M., Fahey, D. W., Proffitt, M. H., Liu, S. C., Eubank, C. S., Kawa, S. R. & Kelly, K. K., Reactive odd nitrogen and its correlation with ozone in the lower stratosphere and upper troposphere. J. Geophys. Res.,(1992), in press.

    Google Scholar 

  71. Kley, D., Drummond, J. W., McFarland, M. & Liu, S. C., Tropospheric profiles of NO,,. J. Geophys. Res., 86 (1981) 3153–61.

    Article  Google Scholar 

  72. Borucik, W. J. & Chameides, W., Lightning: Estimates of the energy dissipation and nitrogen fixation. Rev. Geophys. Space Phys. 22 (1984) 363–72.

    Article  Google Scholar 

  73. Albritton, D. L., Liu, S. C. & Kley, D., Global nitrate deposition from lightning. In Proceedings of the Conference on the Environmental Impact of Natural Emissions. Research Triangle Park. Pittsburgh, PA, Air Pollution Control Association, 1984, pp. 100–2.

    Google Scholar 

  74. Hameed, S., Paidoussis, O. G. & Stewart, R. W., Implications for the natural sources for the latitudinal gradients of NO in the unpolluted troposphere. Geophys. Res. Lett.,8 (1981) 591–4.

    Google Scholar 

  75. NASA, High Speed Research Program/Atmospheric Effects of Stratospheric Aircraft ( HSRP/AESA ), Annual Report, 1991.

    Google Scholar 

  76. Meyers, E. L., A review of 1986 Philidelphia NMOC, NO, and NMOC/NO, ratio data, an interim report. US Environmental Protection Agency, Research Triangle Park, NC, 1987.

    Google Scholar 

  77. Baugues, K., A review of NMOC, NO„ and NMOC/NO„ ratios measured in 1984 and 1985. EPA–450/4–86–015. US Environmental Protection Agency, Research Triangle Park, NC, 1986.

    Google Scholar 

  78. Research Triangle Institute, Investigation of rural oxidant levels as related to urban hydrocarbon control strategies. EPA–450/3–75–036, 1975.

    Google Scholar 

  79. Decker, C. E., Formation and transport oxidant along Gulf Coast and in the Northern US. EPA–450/3–76–033, 1976.

    Google Scholar 

  80. Martinez, J. R. & Singh, H. B., Survey of the role of NON in non-urban ozone formation, Final report on SRI project 6780–8, prepared for Monitoring and Data Analysis Division, Office of Air Quality Planning and Standards, Research Triangle Park, NC 27711, 1979.

    Google Scholar 

  81. Pratt, G. C., Hendrickson, R. C., Chevore, B. I., Christopherson, D. A., O’Brien, M. V. & Krupa, S. V., Ozone and oxides of nitrogen in the rural upper midwestern U.S.A., Atmos. Environ., 10 (1983) 2013–23.

    Google Scholar 

  82. Parrish, D. D., Williams, E. J., Buhr, M. P., Norton, R. B., Fensenfeld, F. C., Gandrud, B. W., Ridley, B. A. & Shetter, J. D., Partitioning of odd-nitrogen species at a rural eastern U.S. site. EOS, 67 (1986) 891.

    Google Scholar 

  83. Kelly, T. J., Stedman, D. H., Ritter, J. H. & Harvey, R. B., Measurements of oxides of nitrogen and nitric acid in clean air. J. Geophys. Res., 85 (1980) 7417–25.

    Article  Google Scholar 

  84. Kelly, N. A., Wolff, G. T. & Ferman, M. A., Background pollution measurements in air masses affecting the eastern half of the United States. Atmos. Environ., 16 (1982) 1077–88.

    Article  CAS  Google Scholar 

  85. Kelly, T. J., Tanner, R. L., Galvin, D. J. & Kadlecek, J. A., Trace gas and aerosol measurements at a remote site in the northeast US. Atmos. Environ., 18 (1984) 2565–76.

    Article  CAS  Google Scholar 

  86. Bollinger, M. J., Hahn, C. J., Parrish, D. D., Murphy, P. C., Albritton, D. L. & Fehsenfeld, F. C., NON measurements in clean continental air. J. Geophys. Res., 89 (1984) 9623–31.

    Article  CAS  Google Scholar 

  87. Fehsenfeld, F. C., Dickerson, R. R., Hubler, G., Luke, W. T., Nunnermacker, L. J., Willams, E. J., Roberts, J. M., Calvert, J. G., Curran, C. M., Delany, A. C., Eubank, C. S., Fahet, D. W., Fried, A., Gandrud, B. W., Langford, A. C., Murphy, P. C., Norton, R. B., Pickering, K. E. & Ridley, B. A., A ground-based intercomparison of NON, NOy measuring techniques. J. Geophys. Res., 92 (1987) 14710–22.

    Article  CAS  Google Scholar 

  88. Parrish, D. D., Williams, E., Norton, R. B. & Fehsenfeld, F. C., Measurement of odd-nitrogen species and ozone at Point Arena California. EOS, 66 (1985) 820.

    Google Scholar 

  89. Carroll, M. A., Ridley, B. A., Montzka, D. D., Hübler G., Walega, J. G., Norton, R. B., Huebert, B. J., Hahn, C. J. & Merrill, J. T., Measurements of nitric oxide and nitrogen oxide during MLOPEX. J. Geophys. Res.,(1992), in press.

    Google Scholar 

  90. Ridley, B. A. & Robinson, E., The Mauna Loa Observatory Photochemistry Experiment (MLOPEX). J. Geophys. Res., submitted, 1991.

    Google Scholar 

  91. McFarland, M., Kley, D., Drummond, J. W., Schmeltekopf, A. L. & Winkler, R. H., Nitric oxide measurements in the Equatorial Pacific Region. Geophys. Res. Lett., 6 (1979) 605–8.

    Article  CAS  Google Scholar 

  92. Dickerson, R. R., Huffman, G. J., Luke, W. T., Nunnermacker, L. J., Pickering, K. E., Leslie, A. C. D., Lindsey, C. G., Slinn, W. G. N., Kelly, T. J., Daum, P. H., Delany, A. C., Greenberg, J. P., Zimmerman, P. R., Boatman, J. F., Ray, J. D. & Stedman, D. H., Thunderstorms: An important mechanism in the transport of air pollutants. Science, 235 (1987) 460–5.

    Article  CAS  Google Scholar 

  93. Dickerson, R. R., Measurements of reactive nitrogen compounds in the free troposphere. Atmos. Environ., 18, (1984) 2585–93.

    Article  Google Scholar 

  94. Dickerson, R. R. Reactive nitrogen compounds in the Arctic. J. Geophys. Res., 90 (1985) 10739–43.

    Article  Google Scholar 

  95. Kondo, Y., Matthews, W. A., Iwata, A., Morita, Y. & Takagi, M., Aircraft measurements of oxides of nitrogen along the eastern rim of the Asian Continent: Winter observations. J. Atmos. Chem., 5, (1987) 37–58.

    Article  CAS  Google Scholar 

  96. Torres, A. L. & Buchan, H., Tropospheric nitric oxide measurements over the Amazon Basin. J. Geophys. Res., 93 (1988) 1396–406.

    Article  CAS  Google Scholar 

  97. Ridley, B. A., Carroll, M. A. & Gregory, G. L., Measurements of nitric oxide in the boundary layer and fre troposphere over the Pacific Ocean. J. Geophys. Res., 92 (1987) 2025–47.

    Article  CAS  Google Scholar 

  98. Davis, D. D., Bradshw, J. D., Rogers, M. O., Sandholm, S. T. & KeSheng, S., Free tropospheric and boundary layer measurements of NO over the central and eastern North Pacific Ocean. J. Geophys. Res.,92 (1987) 204–970.

    CAS  Google Scholar 

  99. Fahey, D. W., Murphy, D. W., Eubank, C. S. & Proffitt, M. H., National Oceanic and Atmospheric Administration, Boulder CO; K. R. Chan, S. G. Scott & S. W. Bowen, NASA Ames Research Center, Moffett Field, CA, personal communication, 1987.

    Google Scholar 

  100. Drummond, J. W. & Volz, A.: Evidence of Air Pollution in the Upper Troposphere. In: Pollutant Cycles and Transport: Modeling and Field Experiments, ed. F. A. A. M. Deleeuv & N, D. Van Edmond. Bilthoven, 1985.

    Google Scholar 

  101. Drummond, J. W., Ehhalt, D. H. & Volz, A., Measurements of nitric oxide between 0–12 km altitude and 67°N-60°S latitude obtained during STRATOZ III. Geophys. Res.,93 (1988) 15831–49.

    Google Scholar 

  102. Ehhalt, D. H. & Drummond, J. W., The tropospheric of the NO„. In Chemistry of the Unpolluted and Polluted Troposphere, ed. H. W. Georgii & W. Jaeschke. D. Reidel, Hinham, MA, 1982.

    Google Scholar 

  103. Chatfield, R. B. & Crutzen, P. J., Sulfur dioxide in remote oceanic air: Cloud transport of reactive precursors. J. Geophys. Res., 89, (1984) 711–32.

    Article  Google Scholar 

  104. Roe, J. M., A climatology of a newly-defined tropopause using simultaneous ozone-temperature profiles. Air Force Geophysics Laboratory Report Number AFGL-TR-81–0190, 1981.

    Google Scholar 

  105. Parrish, D. D., Buhr, M. P., Trainer, M., Norton, R. B., Shimshock, J. P., Fehsenfeld, F. C., et al.,A comparison of the total reactive nitrogen levels and the partitioning between the individual species at six rural sites in eastern North America. J. Geophys. Res. submitted, (1992).

    Google Scholar 

  106. Parrish, D. D., Heubert, B., Norton, R. B., Bollinger, M. J., Liu, S. C., Trainer, M., Murphy, P. C., Albritton, D. L. & Fensenfeld, F. C., Measurement of HNO3 and NO3 particulates at a rural site in the Colorado mountains. J. Geophys. Res., 91 (1986) 5379–93.

    Article  CAS  Google Scholar 

  107. Parrish, D. D., Hahn, C. H., Fahey, D. W., Williams, E. J., Bollinger, M. J., Hübler, G., Buhr, M. P., Murphy, P. C., Trainer, M., Hsie, E. Y., Liu, S. C. & Fensenfeld, F. C., Systematic variations in the concentration of NO. (NO plus NO) at Niwot Ridge, Colorado. J. Geophys. Res.,95 (199)181–736.

    Google Scholar 

  108. Fahey, D. W., Hübler, G., Parrish, D. D., Williams, E. J., Norton, R. B., Ridley, B. A., Singh, H. G., Liu, S. C. & Fensenfeld, F. C., Reactive nitrogen species in the troposphere: Measurements of NO, NO2, HNO3, particulate nitrate, peroxyacetyl nitrate (PAN), 03, and total reactive odd nitrogen (NOy) at Niwot Ridge, Colorado. J. Geophys. Res., 91 (1986) 9781–93.

    Article  CAS  Google Scholar 

  109. Parrish, D. D., Hahn, C. H., Williams, E. J., Norton, Fenhsenfeld, F. C., Singh, H. B., Shetter, J. B., Gandrud, B. W. & Ridley, B. A., Indications of photochemical histories of Pacific air masses from measurements of atmospheric trace species at Pt. Arena, California, 1991.

    Google Scholar 

  110. Hübler, G., Fahey, D. W., Ridley, B. A., Gregory, G. L., & Fensenfeld, F. C., Airborne measurements of total reactive odd nitrogen. J. Geophys. Res. (1992), in press.

    Google Scholar 

  111. Hübler, G., Fahey, D. W., Kelly, K. K., Montzka, D. D., Carroll, M. A., Tuck, A. F., Heidt, L. E., Pollock, W. H., Gregory, G. L. & Vedder, J. F. Redistribution of reactive odd nitrogen in lower arctic stratosphere. J. Geophys. Res. 17 (1990) 453–6.

    Google Scholar 

  112. Hübler, G., Montzka, D. D., Norton, R. B., Murphy, P. C., Fensenfeld, F. C., Liu, S. C., Ridley, B. A., Walega, J. G., Atlas, E., Grahek, F. E., Heidt, L. E., Merrill, J., Huebert, B. J. & Bodhaine, B. A., Total reactive oxidized nitrogen (NOy) in the remote Pacific troposphere, MLOPEX 1988. J. Geophys. Res., submitted, (1992).

    Google Scholar 

  113. Liu, S. C., Model studies of background ozone formation. In NATO Advanced Research Workshop on Troposphere Ozone, ws. Ilsaksen. Lillehammer, Norway, (1988) 303–18.

    Chapter  Google Scholar 

  114. Liu, S. C., Trainer, M., Carroll, M. A., Hübler, G., Montzka, D. D., Norton, R. B., Ridley, B. A., Walega, J. G., Atlas, E. L., Heikes, B. G., Huebert, B. J. & Warren, W., Photochemistry and budget of ozone during MLOPEX, J. Geophys. Res., submitted, (1992).

    Google Scholar 

  115. Hov, O., Ozone in the troposphere: High level pollution. Ambio, 13 ( 1984; 73–9.

    CAS  Google Scholar 

  116. Fishman, J., Vokovich, F. M. & Browell, E. V., The photochemistry of synoptic-scale ozone synthesis: Implications for the global tropospheric ozone budget. J. Atmos. Chem., 3 (1985) 299–320.

    Article  CAS  Google Scholar 

  117. Delany, A. C., Haagensen, P., Walters, S., Wartburg, A. F. & Crutzen, P. J., Photochemically produced ozone in the emission from large-scale tropical vegetation fires. J. Geophys. Res., 90 (1985) 2425–9.

    Article  CAS  Google Scholar 

  118. Chameides, W. L., Davis, D. D., Rogers, M. O., Bradshaw, J., Sandholm, S., Sachse, G., Hill, G., Gregory, G. & Rasmussen, R., Net ozone photochemical production over the eastern and central north Pacific as inferred from GTE/CITE 1 observations during Fall 1983. J. Geophys. Res., 92 (1987) 2131–52.

    Article  CAS  Google Scholar 

  119. Chameides, W. L., Davis, D. D., Gregory, G. L., Sachse, G. & Torres, A. L., Ozone precursors and ozone photochemistry over eastern North Pacific Ocean during the spring of 1984 based on the NASA GTE/CITE 1 airborne observations. J. Geophys. Res., 94 (1989) 9799–808.

    Article  CAS  Google Scholar 

  120. White, W. H., Patterson D. E. & Wilson, W. E., Jr., Urban exports to the nonurban troposphere: Results from Project MISTT. J. Geophys. Res., 88 (1983) 10745–52.

    Article  CAS  Google Scholar 

  121. Wesely, M. L., Cook, D. R. & Williams, R. M., Field measurement of small ozone fluxes to snow, wet bare soil, and lake winter. Boundary Layer Meteorol., 20 (1981) 459–71.

    Article  Google Scholar 

  122. Platt, U., Winer, A. M., Biermann, H. W., Atkinson, R. & Pitts, J. N., Jr., Measurement of nitrate radical concentrations in continental air. Environ. Sci. Technol., 18 (1984) 365–9.

    Article  CAS  Google Scholar 

  123. Noxon, J. F., NO1 and NO2 in the Mid-Pacific troposphere. J. Geophys. Res., 88 (1983) 11017–21.

    Article  CAS  Google Scholar 

  124. Trainer, M., Hsie, E. Y., McKeen, S. A., Tallamraju, R., Parrish, D. D., Fehsenfeld, F. C. & Liu, S. C., Impact of natural hydrocarbons on hydroxyl and peroxy radicals at a remote site. J. Geophys. Res., 92 (1987) 11879–94.

    Article  CAS  Google Scholar 

  125. Hao, W. M., Liu, M. & Crutzen, P. J., Estimates of annual and regional releases of CO2 and other trace gases to the atmosphere from fires in the Tropics, based on the FAO statistics for the period 1975–1980. In Fire in the Tropical Biota, ed. J. G. Goldammer, (Ecological Studies 84 ) Springer, New York, 1990, pp. 440–62.

    Chapter  Google Scholar 

  126. Gidel, L. T., Cumulus cloud transport of transient tracers. J. Geophys. Res., 88 (1983) 6587–99.

    Article  CAS  Google Scholar 

  127. Crutzen, P. J., The role of NO and NO2 in the chemistry of the troposphere and stratosphere. Ann. Rev. Earth Planet. Sci., 7 (1979) 443–72.

    Article  CAS  Google Scholar 

  128. Kirchoff, V. W. J. H., Surface ozone measurements in Amazonia. J. Geophys. Res., 93 (1988) 1469–76.

    Article  Google Scholar 

  129. Jacob, D. J. & Wofsy, S. C., Photochemistry of biogenic emissions over the Amazon forest. J. Geophys. Res., 93 (1988) 1477–86.

    Article  CAS  Google Scholar 

  130. Junge, C. E., Air Chemistry and Radioactivity. Academic Press, New York and London, 1963.

    Google Scholar 

  131. Fabian, P. & Pruchnieweiz, P. G., Meridi)nal distribution of ozone in the troposphere and its seasonal variation. J. Geophys. Res., 82 (1977) 2063–73.

    Article  CAS  Google Scholar 

  132. Chameides, W. L. & Davis, D. D., The free radical chemistry of cloud droplets and its impact on the composition of rain. J. Geophys. Res., 87 (1982) 4863–78.

    Article  CAS  Google Scholar 

  133. Lelieveld, J. & Crurten, P. J., Influences of cloud photochemical processes on tropospheric ozone. Nature, 343 (1990) 227–33.

    Article  CAS  Google Scholar 

  134. Perner, D., Platt, U., Trainer, M., Hübler, G., Drummond, J., Junker-mann, W., Rudolph, J., Schubert, B., Volz, A., Ehhalt, D. H., Rumpel, K. J. & Helas, G., Measurements of tropospheric OH concentrations: A comparison of field data with model predictions. J. Atmos. Chem., 5 (1987) 185216.

    Google Scholar 

  135. Roberts, J. M., Fehsenfeld, F. C., Liu, S. C., Bollinger, M. J., Hahn, C., Albritton, D. L. & Sievers, R. E., Measurements of aromatic hydrocarbon ratios and NO„ concentrations in the rural troposphere: Observation of air mass photochemical aging and NOx. Atmos. Chem., 18 (1984) 2421–32.

    CAS  Google Scholar 

  136. Mozurkewich, M., McMurray, P. M., Gupta, A. & Calvert, J. G., Mass accomodation coefficient for HO2 radicals on aqueous particles. J. Geophys. Res., 92 (1987) 4163–70.

    Article  CAS  Google Scholar 

  137. Worsnop, D. R., Zahniser, M. S., Kolb, C. E., Sharfman, L. R., Gardner, J. A. & Davidovits, P., Determination of HO2 sticking coefficients on water droplets. EOS, 68, (1987) 270.

    Google Scholar 

  138. Ching, J. K. S. & Alkezweeny, A. J., Tracer study of vertical exchange by cumulus clouds. J. Clim. Appl. Meteorol., 25 (1986) 1720–31.

    Google Scholar 

  139. Dickerson, R. R., Houfman, G. J., Luke, W. T., Nunnermacker, L. J., Pickering, K. E., Leslie, A. C. D., Zimmerman, P. R., Boatrman, J. F., Ray, J. D. & Stedman, D. H., Thunderstorms: An important mechanism in the transport of air pollutants. Science, 235 (1987) 460–5.

    Article  CAS  Google Scholar 

  140. Chatfield, R. B. & Delany, A. C., Convection links biomass burning to increased tropical ozone: However, models will tend to overpredict O. J. Geophys. Res., 95 (1990) 18473–88.

    Article  CAS  Google Scholar 

  141. Pickering, K. E., Thompson, A. M., Dickerson, R. R., Luke, W. T., McNamara, D. P., Greenberg, J. P. & Zimmerman, P. R., Model calculations of tropospheric ozone production potential following observed convective events. J. Geophys. Res., 95 (1990) 14049–62.

    Article  Google Scholar 

  142. Beck, S. M., Bendura, R. J., McDaigal, D. S., Hoell, J. M. Jr, Gregory, G. L., Curfman, H. J. Jr, Davis, D. D., Bradshaw, J., Rodgers, M. 0., Wang, C. C., Davis, L. I., Campbell, M. J., Torres, M. A. A. L, Carroll, M. A., Ridley, B. A., Sachse, G. W., Hill, G. F., London, E. P. & Rasmussen, R. A., Operation overview NASA GTE/CITE 1 airborne instrument inter-comparisons: Carbon monoxide, nitric oxide, and hydroxyl instrumentation. J. Geophys. Res., 92 (1987) 1977–8.

    Article  CAS  Google Scholar 

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Fehsenfeld, F.C., Liu, S.C. (1994). Tropospheric Ozone: Distribution and Sources. In: Hewitt, C.N., Sturges, W.T. (eds) Global Atmospheric Chemical Change. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-3714-8_5

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