Abstract
To determine the extent of comparability of sampling and analytical procedures for atmospheric mercury (Hg) being used by different scientific groups around the world and hence the compatibility of measurement results, the Atmospheric Environment Service (AES) co-ordinated a field intercomparison study in Windsor, Ontario, over a period of 5 days during Sept./Oct.,1993. This study brought together 2 groups (University of Michigan Air Quality Laboratory; Chemistry Institute of GKSS) which performed conventional (manual) sample collection procedures for total gaseous mercury (TGM) and for particulate-phase mercury (PPM), followed by cold-vapor atomic fluorescence spectrophotometric (CVAFS) analysis in the respective laboratories. Two other groups (Ontario Hydro, and the Ontario Ministry of Environment & Energy) each operated a novel mercury vapor analyzer produced by Tekran Inc. of Toronto. As is the case for the manual methods, this analyzer also uses gold amalgamation and CVAFS. During the intercomparison, meteorological parameters (air temperature, barometric pressure, wind speed/direction and relative humidity) were obtained at the study site.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
ACS Committee on Environmental Improvement: 1980. Anal. Chem. 52, 2242–2249.
ASTM: 1977. Standards on Precision & Accuracy for Various Applications. American Society for Testing and Materials, Phil, PA.
Baeyens, W.: 1992. Trends Anal. Chem. 11: 245–254.
Bloom, N.S.: 1989. Can. J. Fish. Aquat. Sci. 46,1131–1140.
Bloom, N.S. and Fitzgerald, W.F.: 1988. Anal. Chim. Acta 208,151–161.
Brosset, C. and Iverfeldt, A.: 1989. Water. Air. Soil Pollut. 43, 147–168.
CSA: 1987, Measurement of total mercury in air cold vapour atomic absorption spectrophotometric method. Report CAN/CSA-Z223.26-M87, Canadian Standards Association, Rexdale (Toronto), Ontario, Canada
Cotton, FA. and Wilkinson, G.: 1962, Advanced Inorganic Chemistry. Interscience Publishers, London, U.K
Dumarey, R, Dams, R. and Hoste, J.: 1985. Anal. Chem. 57, 2638–2643
Fitzgerald, W.F. and Gill, GA: 1979. Anal. Chem. 51,1714–1720
Lindqvist, O. (Ed.): 1991. Water. Air. Soil Pollut. 55(Sp. Ed.) Ch.3; App.I
McNerney, JJ., Buseck, P R. and Hanson, R.C.: 1972, Science 178, 611–612
Ohkawa, T., Uenoyama, H. and Kondo, M.: 1976. Eisei Kagaku fJ. Hygienic Chemistrvl 22,11–19
Schroeder, W.H.: 1982, Environ. Sci. Technol. 16, 362A-400A
Schroeder, W.H. and Jackson, RA.: 1985 Intern. J. Environ. Anal. Chem. 22, 1–18
Schroeder, W.H., Hamilton, M.C. and Stobart, S.R.: 1985. Revs. Anah Chem. 8,179–209
Slemr, F., Seiler, W., Eberling, C. and Roggendorf, P.: 1979. Anal. Chim. Acta 110, 35–47
Soldano, BA., Bien, P. and Kwan, P.: 1975. Atmos. Environ. 9, 941–944; 10,171–172.
Youden, WJ. and Steiner, E.H.: 1975, Statistical Manual Association of Official Analytical Chemists. AOAC, Arlington, VA.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1995 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Schroeder, W.H., Keeler, G., Kock, H., Roussel, P., Schneeberger, D., Schaedlich, F. (1995). International Field Intercomparison of Atmospheric Mercury Measurement Methods. In: Porcella, D.B., Huckabee, J.W., Wheatley, B. (eds) Mercury as a Global Pollutant. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0153-0_67
Download citation
DOI: https://doi.org/10.1007/978-94-011-0153-0_67
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-4069-3
Online ISBN: 978-94-011-0153-0
eBook Packages: Springer Book Archive