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Superconductivity of the Ti — D and Zr — D Alloys Under Pressure

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Hydrogen Materials Science and Chemistry of Metal Hydrides

Part of the book series: NATO Science Series ((NAII,volume 71))

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Abstract

The superconducting temperature of the near-eutectoid TiD0.74 and ZrD0.48 alloys is measured in dependence on pressure to 30 and 41.5 GPa, respectively. We find that TiD0.74 becomes a superconductor at a pressure corresponding to its transformation to the high-pressure phase. The T c(P) dependence is an increasing function of pressure. The extrapolated to zero pressure value, 7c(0) = 4.0 K, is small compared to the superconducting temperature of the metastable χ-phase earlier obtained after thermobaric treatment, which is indicative of structural inconsistency between the χ- and high-pressure phases. The T c(P) dependence observed on ZrD0.48 is much the same as in pure Zr. The ZrD0.48 superconductivity behavior under pressure is therefore related to the superconducting properties of the high-pressure ω-phase and the ω − ß transition under pressure.

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Abbreviations

T:

temperature

Tc :

the superconducting transition temperature

P:

pressure

c:

concentration (atomic percentage)

x=H/Me:

the atomic hydrogen-to-metal ratio

χ:

magnetic susceptibility

c/a and b/a:

the lattice parameter ratios

α:

the hexagonal close-packed (HCP) phase of Ti and Zr and hydrogen solid solutions in it

β:

the body-centered cubic (BCC) phase of Ti and Zr and hydrogen solid solutions in it,

ω:

the hexagonal high-pressure phase of Ti and Zr and hydrogen solid solution in it

γ:

the ordered face-centered orthorhombic monohydride in the Ti - H and Zr - H systems

δ:

the face-centered cubic (FCC) non-stoichiometric dihydride in both systems

ε:

the face-centered tetragonal (FCT) dihydride in both systems with the H content up to x = 2

ζ:

the FCT high-pressure phase in the Ti - H system around the eutectoid composition

χ:

the metastable FCT phase due to low-temperature quenching of the ζ-phase under pressure

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Authors and Affiliations

  1. Institute of Solid State Physics, Russian Academy of Sciences Chernogolovka, Moscow district, 142432, Russia

    I. O. Bashkin, M. V. Nefedova, V. G. Tissen & E. G. Ponyatovsky

Authors
  1. I. O. Bashkin
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  2. M. V. Nefedova
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  3. V. G. Tissen
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  4. E. G. Ponyatovsky
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Editor information

Editors and Affiliations

  1. Department of Chemistry, University of Central Florida, Orlando, Florida, USA

    Michael D. Hampton

  2. Institute of Hydrogen and Solar Energy, Ukrainian Academy of Sciences, Kiev, Ukraine

    Dmitry V. Schur

  3. Institute for Problems of Materials Science, Ukrainian Academy of Sciences, Kiev, Ukraine

    Svetlana Yu. Zaginaichenko  & V. I. Trefilov  & 

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Bashkin, I.O., Nefedova, M.V., Tissen, V.G., Ponyatovsky, E.G. (2002). Superconductivity of the Ti — D and Zr — D Alloys Under Pressure. In: Hampton, M.D., Schur, D.V., Zaginaichenko, S.Y., Trefilov, V.I. (eds) Hydrogen Materials Science and Chemistry of Metal Hydrides. NATO Science Series, vol 71. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0558-6_1

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  • DOI: https://doi.org/10.1007/978-94-010-0558-6_1

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-0731-6

  • Online ISBN: 978-94-010-0558-6

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