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Intercalation in Layered Transition Metal Dichalcogenides

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Intercalated Layered Materials

Part of the book series: Physics and Chemistry of Materials with Layered Structures ((PCMA,volume 6))

Abstract

Layered transition metal dichalcogenides, MCh2 (M, metal; Ch, Chalcogen, S, Se, Te), about 60 in number including the various polymorphs and polytypes, are a distinct class of materials possessing a hexagonal layer structure with a fairly strong intralayer covalent bonding and weak interlayer van der Waals bonding. The valence state and d electron configuration of the metal, bonded to the chalcogen, are responsible for the diverse electrical, magnetic and optical properties while the quasi two-dimensional nature of MCh2 gives rise to marked anisotropy in physical properties. The most important property, however, is that the weak interlayer bonding permits intercalation quite akin to other layer type materials such as graphite and silicate clay minerals by which process it is possible to introduce various metal atoms, ions, organic and inorganic molecules and salt-like species between the layers to form stoichiometric or nonstoichiometric compounds. Depending on the intercalate species, quite unsual and dramatic changes in the physical properties of the host can occur and this exciting possibility has stimulated a lot of research interest in the present decade.

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Authors and Affiliations

  1. Materials Science Research Center, Indian Institute of Technology, Madras, 600 036, India

    G. V. Subba Rao

  2. IBM Thomas J. Watson Research Center, P.O. Box 218, Yorktwon Heights, New York, NY, 10598, USA

    M. W. Shafer

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  1. G. V. Subba Rao
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  1. Laboratoire de Physique Appliquée, EPF, Lausanne, Switzerland

    F. Lévy

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© 1979 D. Reidel Publishing Company, Dordrecht, Holland

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Rao, G.V.S., Shafer, M.W. (1979). Intercalation in Layered Transition Metal Dichalcogenides. In: Lévy, F. (eds) Intercalated Layered Materials. Physics and Chemistry of Materials with Layered Structures, vol 6. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9415-7_3

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