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Molecules Between the Stars

Complex Organics in Interstellar Space

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Life on Earth and other Planetary Bodies

Part of the book series: Cellular Origin, Life in Extreme Habitats and Astrobiology ((COLE,volume 24))

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Abstract

The interstellar medium (ISM) is a complex physical and chemical environment which gives rise to a variety of spectral features. This chapter gives a brief overview on the diversity of chemical species that are observed in diffuse interstellar clouds, tenuous entities of gas, and dust scattered throughout the galaxy and beyond. The growing evidence for the existence of large organic, prebiotic molecules in these astrophysical environments is discussed.

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References

  • Adams WS, Dunham TJ (1938) Ultraviolet absorption spectra of some early-type stars. Astrophys J 87:102

    Article  ADS  Google Scholar 

  • Adamson AJ, Whittet DCB, Duley WW (1990) The 3.4-micron interstellar absorption feature in CYG OB no. 12. Mon Not R Astron Soc 243:400

    ADS  Google Scholar 

  • Bless RC, Savage BD (1972) Ultraviolet photometry from the orbiting astronomical observatory. Astrophys J 171:293

    Article  ADS  Google Scholar 

  • Butchart I, McFadzean AD, Whittet DCB, Geballe TR, Greenberg JM (1986) Three micron spectroscopy of the galactic centre source IRS 7. Astron Astrophys Lett 154:5

    ADS  Google Scholar 

  • Cami J, Sonnentrucker P, Ehrenfreund P, Foing BH (1997) Diffuse interstellar bands in single clouds: new families and constraints on the carriers. Astron Astrophys 326:822

    ADS  Google Scholar 

  • Cami J, Salama F, Jimenez-Vicente J, Galazutdinov GA, Krelowski J (2004) The rotational excitation temperature of the 6614 diffuse interstellar band carrier. Astrophys J 611:113

    Article  ADS  Google Scholar 

  • Cami J, Bernard-Salas J, Peeters E, Malek SE (2010) Detection of C60 and C70 in a young planetary nebula. Science 329:1180

    Article  ADS  Google Scholar 

  • Charnley SB, Kuan Y-J, Huang H-C, Botta O, Butner HM, Cox N, Despois D, Ehrenfreund P, Kisiel Z, Lee Y-Y, Markwick AJ, Peeters Z, Rodgers SD (2005) Astronomical searches for nitrogen heterocycles. Adv Space Res 36:137

    Article  ADS  Google Scholar 

  • Cordiner MA, (2005) Diffuse interstellar bands and the structure of the ISM, PhD Thesis, University of Nottingham

    Google Scholar 

  • Cordiner MA, Cox NLJ, Trundle C, Evans CJ, Hunter I, Przybilla N, Bresolin F, Salama F (2008a) Detection of diffuse interstellar bands in M31. Astron Astrophys 480:13

    Article  ADS  Google Scholar 

  • Cordiner MA, Smith KT, Cox NLJ, Evans CJ, Hunter I, Przybilla N, Bresolin F, Sarre PJ (2008b) Diffuse interstellar bands in M33. Astron Astrophys 492:5

    Article  ADS  Google Scholar 

  • Cox NLJ, Cordiner MA, Cami J, Foing BH, Sarre PJ, Kaper L, Ehrenfreund P (2006) The Large Magellanic Cloud: diffuse interstellar bands, atomic lines and the local environmental conditions. Astron Astrophys 447:991

    Article  ADS  Google Scholar 

  • Cox NLJ, Boudin N, Foing BH, Schnerr RS, Kaper L, Neiner C, Henrichs H, Donati J-F, Ehrenfreund P (2007) Linear and circular polarisation of diffuse interstellar bands. Astron Astrophys 465:899

    Article  ADS  Google Scholar 

  • Crawford MK, Tielens AGGM, Allamandola LJ (1985) Ionized polycyclic aromatic hydrocarbons and the diffuse interstellar bands. Astrophys J Lett 293:45

    Article  ADS  Google Scholar 

  • Destree JD, Snow TP, Eriksson K (2007) The presence of diffuse interstellar bands in the spectra of cool stars. Astrophys J 664:909

    Article  ADS  Google Scholar 

  • Draine BT (2003) Interstellar dust grains. Annu Rev Astron Astrophys 41:241

    Article  ADS  Google Scholar 

  • Draine BT, Li A (2001) Infrared emission from interstellar dust. I. Stochastic heating of small grains. Astrophys J 551:807

    Article  ADS  Google Scholar 

  • Duley WW (2006) Dehydrogenated cations of corone. Astrophys J Lett 643:21

    Article  ADS  Google Scholar 

  • Duley WW, Williams DA (1986) PAH molecules and carbon dust in interstellar clouds. Mon Not R Astron Soc 219:859

    ADS  Google Scholar 

  • Dunham TJ (1937) Interstellar neutral potassium and neutral calcium. Publ Astron Soc Pac 49:26

    Article  ADS  Google Scholar 

  • Eddington AS (1926) Diffuse matter in interstellar space. Observatory 49:304

    ADS  Google Scholar 

  • Edwards SA, Leach S (1993) Simulated rotational band contours of C60 and their comparison with some of the diffuse interstellar bands. Astron Astrophys 272:533

    ADS  Google Scholar 

  • Ehrenfreund P, Foing BH (1996) Resolved profiles of diffuse interstellar bands: evidence fou rotationalcontours of gas phase molecules.Astron Astrophys 307:L25

    ADS  Google Scholar 

  • Fitzpatrick EL, Massa D (2007) An analysis of the shapes of interstellar extinction curves. Astrophys J 663:320

    Article  ADS  Google Scholar 

  • Foing BH, Ehrenfreund P (1994) Detection of two interstellar absorption bands coincident with spectral features of C +60 . Nature 369:296

    Article  ADS  Google Scholar 

  • Frenklach M, Feigelson ED (1989) Formation of polycyclic aromatic hydrocarbons in circumstellar envelopes. Astrophys J 341:372

    Article  ADS  Google Scholar 

  • Galazutdinov G, Pebtlewski A, Musaev F, Moutou C, Lo Curto G, Krelowski J (2002) An upper limit to the interstellar C5 abundance in translucent clouds. Astron Astrophys 395:223

    Article  ADS  Google Scholar 

  • Galazutdinov GA, Musaev FA, Bondar AV, Krelowski J (2003) Very high resolution profiles of four diffuse interstellar bands. Mon Not R Astron Soc 345:365

    Article  ADS  Google Scholar 

  • Hartmann J (1904) Investigations on the spectrum and orbit of delta Orionis. Astrophys J 19:268

    Article  ADS  Google Scholar 

  • Heger ML (1919) Stationary sodium lines in spectroscopic binaries. Publ Astron Soc Pac 31:304

    Article  ADS  Google Scholar 

  • Heger ML (1922) Further study of the sodium lines in class B stars. Lick Obs Bull 10:141

    ADS  Google Scholar 

  • Herbig G (1975) The diffuse interstellar bands. IV – the region 4400–6850. Astrophys J 196:129

    Article  ADS  Google Scholar 

  • Herbig G (1993) The diffuse interstellar bands. IX – constraints on the identification. Astrophys J 407:142

    Article  ADS  Google Scholar 

  • Herbig G (1995) The diffuse interstellar bands. Annu Rev Astron Astrophys 33:19

    Article  ADS  Google Scholar 

  • Herbst E, Van Dishoeck EF (2009) Complex organic interstellar molecule. Annu Rev Astron Astrophys 47:427

    Article  ADS  Google Scholar 

  • Hobbs LM (1979) Interstellar C2 molecules toward Zeta Persei. Astrophys J 232:175

    Article  ADS  Google Scholar 

  • Hobbs LM, York DG, Snow TP, Oka T, Thorburn JA, Bishof M, Friedman SD, McCall BJ, Rachford B, Sonnentrucker P, Welty DE (2008) A catalog of diffuse interstellar bands in the spectrum of HD 204827. Astrophys J 680:1256

    Article  ADS  Google Scholar 

  • Iglesias-Groth S (2004) Fullerenes and buckyonions in the interstellar medium. Astrophys J Lett 608:37

    Article  ADS  Google Scholar 

  • Iglesias-Groth S (2007) Fullerenes and the 4430 A diffuse interstellar band. Astrophys J Lett 661:167

    Article  ADS  Google Scholar 

  • Iglesias-Groth S, Manchado A, Garcia-Hernandez DA, Gonzalez-Hernandez JI, Lambert DL (2008) Evidence for the naphthalene cation in a region of the interstellar medium with anomalous microwave emission. Astrophys J Lett 685:55

    Article  ADS  Google Scholar 

  • Iglesias-Groth S, Manchado A, Rebolo R, Gonzalez-Hernandez JI, Garcia-Hernandez DA, Lambert DL (2010) A search for interstellar anthracene towards the Perseus anomalous microwave emission region. Mon Not R Astron Soc 407:2157

    Article  ADS  Google Scholar 

  • Kerr TH, Hibbins RE, Miles JR, Fossey SJ, Sommerville WB, Sarre PJ (1996) Molecular rotational contour fitting of ultra-high-resolution profiles of diffuse interstellar bands. Mon Not R Astron Soc 283:105

    ADS  Google Scholar 

  • Krelowski J, Walker GAH (1987) Three families of diffuse interstellar bands? Astrophys J 312:860

    Article  ADS  Google Scholar 

  • Krelowski J, Westerlund BE (1988) High-resolution profiles of diffuse interstellar bands as functions of the structure of the interstellar medium. Astron Astrophys 190:339

    ADS  Google Scholar 

  • Kuan Y-J, Charnley SB, Huang H-C, Kisiel Z, Ehrenfreund P, Tseng W-L, Yan C-H (2004) Searches for interstellar molecules of potential prebiotic importance. Adv Space Res 33:31

    Article  ADS  Google Scholar 

  • Lambert DL, Sheffer Y, Federman SR (1995) Hubble space telescope observations of C2 molecules in diffuse interstellar clouds. Astrophys J 438:740

    Article  ADS  Google Scholar 

  • Le Page V, Snow TP, Bierbaum VM (2003) Hydrogenation and charge states of polycyclic aromatic hydrocarbons in diffuse clouds. Astrophys J 584:316

    Article  ADS  Google Scholar 

  • Leger A, d’Hendecourt L (1985) Are polycyclic aromatic hydrocarbons the carriers of the diffuse interstellar bands in the visible? Astron Astrophys 146:81

    ADS  Google Scholar 

  • Liszt HS, Lucas R, Pety J (2006) Comparative chemistry in diffuse clouds. Astron Astrophys 448:253

    Article  ADS  Google Scholar 

  • Liszt HS, Pety J, Lucas R (2008) Limits on chemical complexity in diffuse clouds. Astron Astrophys 486:493

    Article  ADS  Google Scholar 

  • Luna R, Cox NLJ, Satorre MA, Garcia Hernandez DA, Suarez OGarcia, Lario P (2008) A search for diffuse bands in the circumstellar envelopes of post-AGB stars. Astron Astrophys 480:133

    Article  ADS  Google Scholar 

  • Maier JP, Lakin NM, Walker GAH, Bohlender DA (2001) Detection of C3 in diffuse interstellar clouds. Astrophys J 553:267

    Article  ADS  Google Scholar 

  • Maier JP, Walker GAH, Bohlender DA (2002) Limits to interstellar C4 and C5 toward Zeta Ophiuchi. Astrophys J 566:332

    Article  ADS  Google Scholar 

  • McFadzean AD, Whittet DCB, Longmore AJ, Bode MF, Adamson AJ (1989) Infrared studies of dust and gas towards the Galactic Centre -3-5 micron spectroscopy. Mon Not R Astron Soc 241:873

    Google Scholar 

  • Mennella V, Colangeli L, Bussoletti E, Palumbo P, Rotundi A (1998) A new approach to the puzzle of the ultraviolet interstellar extinction bump. Astrophys J Lett 507:177

    Article  ADS  Google Scholar 

  • Merrill PW (1934) Unidentified interstellar lines. Publ Astron Soc Pac 46:206

    Article  ADS  Google Scholar 

  • Merrill PW, Wilson OC (1938) Unidentified interstellar lines in the yellow and red. Astrophys J 87:9

    Article  ADS  Google Scholar 

  • Merrill PW, Sanford RF, Wilson OC, Burwell CG (1937) Intensities and displacements of interstellar lines. Astrophys J 86:274

    Article  ADS  Google Scholar 

  • Oka T, Thorburn JA, McCall BJ, Friedman SD, Hobbs LM, Sonnentrucker P, Welty DE (2003) Observations of C3 in translucent sightlines. Astrophys J 582:823

    Article  ADS  Google Scholar 

  • Pendleton YJ, Sandfor SA, Allamandola LJ, Tielens AGGM, Sellgren K (1994) Near-infrared absorption spectroscopy of interstellar hydrocarbon grains. Astrophys J 437:683

    Article  ADS  Google Scholar 

  • Phillips JG (1948a) A new band system of the C2 molecule. Astrophys J 107:389

    Article  ADS  Google Scholar 

  • Phillips JG (1948b) An extension of the Swan system of the C2 molecule. Astrophys J 108:434

    Article  ADS  Google Scholar 

  • Plaskett JS (1924) The O-type stars. Publ Dom Astrophys Obs Vic 2:287

    ADS  Google Scholar 

  • Ruiterkamp R, Cox NLJ, Spaans M, Kaper L, Foing BH, Salama F, Ehrenfreund P (2005) PAH charge state distribution and DIB carriers. Astron Astrophys 432:515

    Article  ADS  Google Scholar 

  • Russell HN (1935) The analysis of spectra and its application in astronomy. Mon Not R Astron Soc 95:610

    ADS  MATH  Google Scholar 

  • Salama F, Bakes ELO, Allamandola LJ, Tielens AGGM (1996) Assessment of the polycyclic aromatic hydrocarbon – diffuse interstellar band proposal. Astrophys J 458:621

    Article  ADS  Google Scholar 

  • Sandford SA, Pendleton YJ, Allamandola LJ (1995) The Galactic distribution of aliphatic hydrocarbons in the diffuse interstellar medium. Astrophys J 440:697

    Article  ADS  Google Scholar 

  • Sarre PJ (2006) The diffuse interstellar bands. J Mol Spec 238:1

    Article  ADS  Google Scholar 

  • Sarre PJ, Miles JR, Scarrott SM (1995a) Molecular diffuse interstellar band carriers in the Red Rectangle. Science 269:674

    Article  ADS  Google Scholar 

  • Sarre PJ, Miles JR, Kerr TH, Hibbins RE, Fossey SJ, Somerville WB (1995b) Resolution of intrinsic fine structure in spectra of narrow diffuse interstellar bands. Mon Not R Astron Soc 277:41

    ADS  Google Scholar 

  • Sellgren K, Werner MW, Ingalls JG, Smith JDT, Carleton TM, Joblin C (2010) C60 in reflection nebulae. Astrophys J 722:L54–L57

    Article  ADS  Google Scholar 

  • Smith AM, (2006) Dust and molecules in interstellar, circumstellar and extragalactic environments, PhD Thesis, University of Nottingham

    Google Scholar 

  • Sonnentrucker P, Foing BH, Breitfellner M, Ehrenfreund P (1999) Distribution of gas, dust and the 6613 DIB carrier in the Perseus OB2 association. Astron Astrophys 346:936

    ADS  Google Scholar 

  • Souza SP, Lutz BL (1977) Detection of C2 in the interstellar spectrum of Cygnus OB2 12. Astrophys J 216:49

    Article  ADS  Google Scholar 

  • Stecher TP (1965) Interstellar extinction in the ultraviolet. Astrophys J 142:1683

    Article  ADS  Google Scholar 

  • Struve O (1927) On the effect of distance upon the intensities of detached calcium lines. Pop Astron 35:212

    ADS  Google Scholar 

  • Struve O (1930) The coexistence of stellar and interstellar calcium lines in the eclipsing binary U Ophiuchi. Astrophys J 72:199

    Article  ADS  Google Scholar 

  • Swings P (1937) A note on molecular absorption in interstellar space. Mon Not R Astron Soc 97:212

    ADS  Google Scholar 

  • Tielens AGGM (2008) Interstellar polycyclic aromatic hydrocarbon molecules. Annu Rev Astron Astrophys 46:289

    Article  ADS  Google Scholar 

  • Van der Zwet GP, Allamandola LJ (1985) Polycyclic aromatic hydrocarbons and the diffuse interstellar bands. Astron Astrophys 146:76

    ADS  Google Scholar 

  • Van Winckel H, Cohen M, Gull TR (2002) The ERE of the Red Rectangle revisited. Astron Astrophys 390:147

    Article  ADS  Google Scholar 

  • Vos DAI, Cox NLJ, Kaper L, Spaans M, Ehrenfreund P (2011) Diffuse interstellar band in Upper Scorpius. Astron Astrophys 533:A129

    Google Scholar 

  • Welty DE, Federman SR, Gredel R, Thorburn JA, Lambert DL (2006) VLT UVES observations of interstellar molecules and diffuse bands in the Magellanic Clouds. Astrophys J 165:138

    Article  ADS  Google Scholar 

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Cox, N. (2012). Molecules Between the Stars. In: Hanslmeier, A., Kempe, S., Seckbach, J. (eds) Life on Earth and other Planetary Bodies. Cellular Origin, Life in Extreme Habitats and Astrobiology, vol 24. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-4966-5_6

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