Abstract
Soft Fe LIII,II X-ray emission spectra of wustite have been recorded by EPMA in the 690–730 eV energy range. Using these spectra for different electron beam excitation voltages, the self-absorption Fe LIII-spectrum was formed. By comparing Fe LIII,II X-ray emission and Fe LIII-self-absorption spectra of wustite, relative energies of the valence-conduction band orbitals could be determined as well as the splitting of these orbitals in the crystal field and the size of their spin splitting.
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References
J. A. Tossell, G. V. Gibbs, Phys. Chem. Minerals 1977, 2, 21.
D.J. Vaughan, J. A. Tossell, K. H. Johanson, Geochim. Cosmochim. Acta 1974,38,939.
R.J. Liefeld, Soft X-ray Band Spectra, Academic Press, New York, 1968, p. 133.
M. K. Pavicevic, Dissertation, Univ. Heidelberg, 1971.
M. K. Pavicevic, P. Ramdor, A. El Goresy, Geochim. Cosmochim. Acta, 1972,3, [Suppl.] 295.
M. K. Pavicevic, in: Analyse extraterrestischen Materials (W. Kiesl, H. Malissa jun., eds.), Springer, Berlin, Heidelberg, New York, 1974, p. 289.
M. K. Pavicevic, Predavanja odrzana u JAZU, Svezak 42, Zagreb, 1974, p. 1 (in Serbo-Croatian).
D. W. Fisher, J. Phys. Chem. Solids 1971,32, 2455.
C. Bonnell, Physical Methods in Advanced Inorganic Chemistry, Interscience, New York, 1968, p.45.
J. A. Tossell, D. J. Vaughan, K. H. Johnson, Am. Mineral. 1974,59,319.
R. K. O’Nions, D, G. W. Smith, Am. Mineral 1971, 56, 1452.
M. Romand, J. S. Solomon, W. L. Brun, J. Phys. Chem. Solids 1973, 34, 1765.
C. G. Dodd, P. H. Ribe, Phys. Chem. Minerals 1978,3,145.
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© 1992 Springer-Verlag Wien
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Timotijevic, D.M., Pavicevic, M.K. (1992). Electron Configuration of the Valence-Conduction Band of the Mineral Wustite. In: Boekestein, A., Pavićević, M.K. (eds) Electron Microbeam Analysis. Mikrochimica Acta, vol 12. Springer, Vienna. https://doi.org/10.1007/978-3-7091-6679-6_28
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DOI: https://doi.org/10.1007/978-3-7091-6679-6_28
Publisher Name: Springer, Vienna
Print ISBN: 978-3-211-82359-0
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