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Metal-Based Chalcogenide Anode Materials for Lithium-Ion Batteries

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Nanostructured Materials for Next-Generation Energy Storage and Conversion

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Abstract

Rechargeable lithium-ion batteries (LIBs) have become state-of-art and are widely used in portable electronic devices and electric vehicles. With the development of materials and batteries technology, the performance of batteries has achieved enormous progress since its commercialization in the early 1990s. Recently, we saw this development slow down, as it is nearing the theoretical limit of the present system. A new battery system is necessary to meet the rigorous demands of high energy density. Under this circumstance, the innovation of anode materials is expected to be a promising way to remarkably increase the capacity of lithium-ion batteries. Metal-based chalcogenide (MXs, M = Sn, Mo, Fe, or Ge; X = O, S or Se) is a promising material for the anode of lithium-ion batteries (LIBs), because of their higher theoretical capacity when compared to conventional carbonaceous anodes. However, the wide application of chalcogenide anode in rechargeable battery is still hindered by the low efficiency and poor cycle performance caused by a large volume change during fully discharge and charge. Recently, there has been much interest in using nanostructured and carbon composite method in lithium-ion batteries to alleviate their inherent drawback. This chapter will provide an overview of the chalcogenide anode materials which are being studied experimentally in order to develop next-generation anodes for high-performance lithium-ion batteries.

Author Contribution: Q. Tang and Q. Jiang wrote this chapter. J. Wu. and X. Liu provided the relevant instruction.

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Acknowledgments

This work is partially supported by Shenzhen Fundamental Research Program of Subject Distribution (JCYJ20170413102735544) and Natural Science Foundation of Guangdong (2018A030313721).

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  1. Shenzhen Key Laboratory of Advanced Materials, Department of Materials Science and Engineering, Harbin Institute of Technology (Shenzhen), Shenzhen, China

    Qiming Tang, Qin Jiang, Junwei Wu & Xingjun Liu

Authors
  1. Qiming Tang
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  2. Qin Jiang
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  3. Junwei Wu
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  4. Xingjun Liu
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Corresponding author

Correspondence to Junwei Wu .

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Editors and Affiliations

  1. Nano-Science and Nano-Technology, Shanghai University, Shanghai, China

    Qiang Zhen

  2. Department of Chemistry, Texas A&M University Kingsville, Kingsville, TX, USA

    Sajid Bashir

  3. Department of Chemistry, Texas A&M University Kingsville, Kingsville, TX, USA

    Jingbo Louise Liu

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Tang, Q., Jiang, Q., Wu, J., Liu, X. (2019). Metal-Based Chalcogenide Anode Materials for Lithium-Ion Batteries. In: Zhen, Q., Bashir, S., Liu, J. (eds) Nanostructured Materials for Next-Generation Energy Storage and Conversion. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-58675-4_6

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