Abstract
Four types of hydrated selenates were investigated by single crystal X-ray and neutron diffraction, by powder X-ray diffraction and by thermal analysis (TG, DSC). The compounds were pentahydrates M”Se04. 5H2O with M” = Mn, Co, Fe, Cu, Zn; hexahydrates M”Se04. 6H20 with M” = Ni, Zn; the Semendozite NaAl(Se04)2.11H20 and alums of the general formula M’Al(Se04)2. 12H20 with M’ = K, Rb, Cs. The aim of our study is to establish a correlation between the thermal stability of a given compound and its dehydration behaviour on one side and the crystal structure and hydrogen bonding network on the other side.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Bacon GE and Titterton DH (1975) Neutron-diffraction studies of CUSO4. 5H20 and CuS04.5D20. Z. Kristallogr. 141, 330–341
Fuess H Joswig W and Ferraris G (1986) Neutron diffraction study of struvite and survey of water molecules donating short hydrogen bonds. Acta Cryst. B42, 253–258
Erfany-Far H and Fuess H (1987) Kristallstruktur und Entwasserung von NaAl(Se04)2 11 H2O. Z. Kristallogr. in press
Fang JH and Robinson PD (1972) Crystal structures and mineral chemistry of double- salt hydrates: II. The crystal structure of mendozite, NaAl(Se04)2 11H2O. Amer. Mineral. 37, 1081–1088
Haussuhl S (1961) Kristallographie der Alaune I. Z. Kristallogr. 116, 371–405
Spangenberg K (1949) Über die Bindungen des Kristallwassers in den Alaunen. N. Jahrb. Mineral. Monatsh. A 99 — 112
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1987 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Erfany-Far, H., Fuess, H. (1987). Hydrogen Bonding and Dehydration in Selenate Hydrates. In: Kleeberg, H. (eds) Interactions of Water in Ionic and Nonionic Hydrates. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-72701-6_10
Download citation
DOI: https://doi.org/10.1007/978-3-642-72701-6_10
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-17846-0
Online ISBN: 978-3-642-72701-6
eBook Packages: Springer Book Archive