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Liquid Adsorption Chromatography

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HPLC of Polymers

Part of the book series: Springer Desktop Editions in Chemistry ((SPLABORATORY))

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Abstract

Adsorption chromatography is based on the retention of solute molecules by surface adsorption. Intermittent capture and release of solute molecules by the stationary phase are controlled by two basically different mechanisms or some combinations thereof. In regard to adsorption-desorption phenomena, an abrupt process is the critical step leading to sorption or desorption. This process is typified by molecular desorption from surfaces where molecules can detach, and then do so suddenly, if they possess sufficient activation energy to cause the necessary rearrangement or rupture of chemical or physical bonding. Quite different in effect are the diffusion-controlled sorption-desorption kinetics where a change occurs only gradually as molecules diffuse in and out of localized regions [1].

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Authors and Affiliations

  1. Deutsches Kunststoff-Institut, Schloßgartenstraße 6, D-64289, Darmstadt, Germany

    Priv.-Doz. Dr. Harald Pasch

  2. Institut für Organische Chemie, Karl-Franzens-Universität, Heinrichstraße 28, A-8010, Graz, Austria

    Prof. Dr. Bernd Trathnigg

Authors
  1. Priv.-Doz. Dr. Harald Pasch
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  2. Prof. Dr. Bernd Trathnigg
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© 1999 Springer-Verlag Berlin Heidelberg

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Pasch, H., Trathnigg, B. (1999). Liquid Adsorption Chromatography. In: HPLC of Polymers. Springer Desktop Editions in Chemistry. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-58265-3_5

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  • DOI: https://doi.org/10.1007/978-3-642-58265-3_5

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-65551-0

  • Online ISBN: 978-3-642-58265-3

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