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Analysis of compositional and structural heterogeneities of polymers by non-exclusion HPLC

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Biopolymers/Non-Exclusion HPLC

Part of the book series: Advances in Polymer Science ((POLYMER,volume 79))

Abstract

High performance liquid chromatography (HPLC) of polymers is often thought to be synonymous with Size Exclusion Chromatography for separation by molar size. The present article deals with non-exclusion chromatography of polymers which enables separation by differences in the chemical structure and composition.

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Abbreviations

AN:

Acrylonitrile

AC:

Adsorption chromatography

AcN:

Acetonitrile

CF:

Cross fractionation

CCF:

Chromatographic cross-fractionation

CCD:

Chemical-composition distribution

HIC:

Hydrophobic interaction chromatography

IEC:

Ion exchange chromatography

MEK:

Methyl ethyl ketone

MMD:

Molar-mass distribution

RP:

Reversed phase

RPC:

Reversed-phase chromatography

PS:

Polystyrene

SAN:

Poly(styrene-co-acrylonitrile)

SMA:

Poly(styrene-co-methyl acrylate)

SMMA:

Poly(styrene-co-methyl methacrylate)

SEC:

Size exclusion chromatography

SBR:

Styrene-butadiene rubber

THF:

Tetrahydrofuran

TLC:

Thin-layer chromatography

dO :

Pore diameter

dP :

Particle size of packing materials

P:

Degree of polymerization

M:

Molar mass

\(\overline M\) n :

Number average of M

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    Gottfried Glöckner

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Glöckner, G. (1986). Analysis of compositional and structural heterogeneities of polymers by non-exclusion HPLC. In: Biopolymers/Non-Exclusion HPLC. Advances in Polymer Science, vol 79. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-16422-7_10

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  • DOI: https://doi.org/10.1007/3-540-16422-7_10

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