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Noncovalent Functionalization of Carbon Nanotubes

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Abstract

In the first section, the suitability of seven different perylene bisimide derivatives (1–7) with respect to nanotube dispersion and exfoliation in water has been investigated (Scheme 3.1) [1, 2]. The syntheses of these systems is described in the literature [2, 3]. As outlined by numerous studies [4–12], the inclusion of polycyclic aromatic units in nanotube dispersion additives enhances the interaction with the aromatic nanotube scaffold in comparison to classical detergents where the interaction is limited to van der Waals attraction.

Structures of the perylene bisimide derivatives and the reference systems applied for the dispersion of HiPco SWCNTs. The anchor unit to the SWCNT surface is indicated by the blue squares, the solvophylic moieties by the grey circles

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Notes

  1. 1.

    Special thanks is credited to Dr. W. Wohlleben from BASF SE for providing the opportunity to carry out the experiments on the designed MWL AUCand for the help with the data evaluation.

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  1. ZMP-Institute of Advanced Materials and Processes, Universität Erlangen-Nürnberg, Dr. Mack Str 81, 90762, Fürth, Germany

    Claudia Backes

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Backes, C. (2012). Results and Discussion. In: Noncovalent Functionalization of Carbon Nanotubes. Springer Theses. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-27582-1_3

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