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Calorimetry at the Solid–Liquid Interface

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Calorimetry and Thermal Methods in Catalysis

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 154))

Abstract

Broad principles of Solid-Liquid calorimetry together with some illustrative examples of its use in the field of catalysis are presented here. The first use is related to the determination of surface properties of catalysts, adsorbents and solid materials in contact with liquids. In particular, it is shown how to evaluate the capacity of a given solid to establish different types of interaction with its liquid environment or to calculate its specific surface area accessible to liquids. The second use includes the measurement of the heat effects accompanying catalytic reactions and the related interfacial phenomena at Solid-Liquid and Liquid-Liquid interfaces. Examples of competitive ion adsorption from dilute aqueous solutions, as well as the formation of surfactant aggregates either in aqueous solution or at the Solid-Liquid interface are considered in view of potential applications in Environmental Remediation and Micellar Catalysis.

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  1. Institut Charles Gerhardt Montpellier, UMR-5253 CNRS-UM2 Equipe Agrégats, Interface, et Matériaux pour l’Energie (AIME), Université Montpellier 2, C.C. 1502 Place Eugène Bataillon, 34095, Montpellier Cedex 5, France

    Jerzy Jozef Zajac

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Zajac, J.J. (2013). Calorimetry at the Solid–Liquid Interface. In: Auroux, A. (eds) Calorimetry and Thermal Methods in Catalysis. Springer Series in Materials Science, vol 154. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-11954-5_6

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