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Structure of adsorption layers of ionic surfactants at the solid/liquid interface

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Abstract

A large number of experimental results of different surfactant adsorption systems (mainly on the silicas) obtained from both equilibrium and kinetic studies under different conditions are interpreted by a model of small individual surface aggregates. The adsorption model is contrasted with the influences of various factors, including electrostatic interaction, hydrophobic interaction, concentrations, types of coions, types of counterions, surfactant structure, alkyl chain length, types of head groups, neutral electrolytes, pH, adsorbent structure, porosity, surface charge density, and surface polarity.

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Author notes

  1. H. Rupprecht

    Present address: Institut für Pharmazie, Universität Regensburg, Universitätsstr. 31, D-8400, Regensburg, FRG

  2. T. Gu

    Present address: Department of Chemistry, Peking University, Universitätsstr. 31, D-8400, Beijing, China

Authors and Affiliations

  1. Institut für Pharmazie, Universität Regensburg, Universitätsstr. 31, D-8400, Regensburg, FRG

    T. Gu

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  1. H. Rupprecht
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Dedicated to Frau Professor Dr. Elsa Ullmann on the occasion of her 80th birthday

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Rupprecht, H., Gu, T. Structure of adsorption layers of ionic surfactants at the solid/liquid interface. Colloid Polym Sci 269, 506–522 (1991). https://doi.org/10.1007/BF00655889

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  • DOI: https://doi.org/10.1007/BF00655889

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