Abstract
Using melt superheating as a means to control the structure and properties of metallic alloys has been studied extensively and demonstrated some promising results, though the industrial implementation is limited due to the required high energy for melt heating and holding. The physical mechanisms behind this technology can be divided into two major groups: (1) achieving homogeneous metallic melt with the resultant high undercooling upon solidification and (2) formation of heterogeneous substrates either by formation or transformation of insoluble impurities. In this chapter, we first discuss the structure of melts and its changes with temperature during high-temperature holding. Although mostly of academic interest, these studies demonstrate the complexity of temperature influence on the molten and solidifying melt. Some examples on the effects of the initial melt condition on the solidification microstructures are given as well. After that we consider some practical implications of the changes in insoluble impurities with temperature on the microstructure formed during solidification in some metallic alloys.
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References
P.S. Popel, Chernaja Metallurgija 5, 34–41 (1985)
P.S. Popel, E.L. Demina, E.L. Arkhangel’skii, B.A. Baum, TVT 25(3), 487–491 (1987); High Temp. 25(3), 360–364 (1987)
V.P. Manov, A.B. Manukhin, P.S. Popel, Doklady AN SSSR 281, 107–109 (1985)
P.S. Popel, O.A. Chikova, V.M. Matveev, High Temp. Mater. Process. 4, 219–233 (1995)
I.G. Brodova, P.S. Popel, G.I. Eskin, Liquid Metal Processing. Application to Aluminium Alloy Production (Taylor and Francis, New York, 2002)
V. Manov, P.S. Popel, E. Brook-Levinson, V. Molokanov, M. Calvo-Dahlborg, U. Dahlborg, V. Sidorov, L. Son, Y. Tarakanov, Mater. Sci. Eng. A 304–306, 54–60 (2001)
P.S. Popel, M. Calvo-Dahlborg, U. Dahlborg, J. Non-Cryst. Solids 353, 3243–3253 (2007)
J.R. Morris, U. Dahlborg, M. Calvo-Dahlborg, J. Non-Cryst. Solids 353, 3444–3453 (2007)
H. Tanaka, Eur. Phys. J. E 35, 113 (2012)
L. Son, J. Non-Cryst. Solids 401, 213–218 (2014)
L. Son, Physica A 449, 395–400 (2016)
F.-Q. Zu, Metals 5, 395–417 (2015)
P.-F. Paradis, T. Ishikawa, G.-W. Lee, D. Holland-Moritz, J. Brillo, W.-K. Rhim, J.T. Okada, Mater. Sci. Eng. R 76, 1–53 (2014)
A. Guinier, G. Fournet, Small-Angle Scattering of X-rays (Chapman & Hall. Ltd, London, 1955)
G. Kostorz, Physical Metallurgy, vol II, 5th edn. (Elsevier, Amsterdam, 2004), pp. 1227–1316
Y. Waseda, The Structure of Non-Crystalline Materials (McGraw-Hill, New York, 1980)
I. Kaban, S. Gruner, W. Hoyer, P. Jóvári, R.G. Delaplane, A. Wannberg, J. Non-Cryst. Solids 353, 3027–3031 (2007)
U. Dahlborg, M. Calvo-Dahlborg, P.S. Popel, V.E. Sidorov, Eur. Phys. J. B. 14, 639–648 (2000)
M. Calvo-Dahlborg, P.S. Popel, M.J. Kramer, M. Besser, J.R. Morris, U. Dahlborg, J. Alloys Compd. 550, 9–22 (2013)
F.-G. Li, J. Zhang, Y.-B. Dai, F.-G. Bian, Y.-F. Han, B.-D. Sun, Mater. Chem. Phys. 143, 471–475 (2014)
R.L. McGreevy, L. Pusztai, Mol. Simul. 1, 359–367 (1988)
R.L. McGreevy, J. Phys, Condens. Matter 13, R877 (2001)
J. Brillo, A. Bytchkov, I. Egry, L. Hennet, G. Mathiak, I. Pozdnyakova, D.L. Price, D. Thiaudiere, D. Zanghi, J. Non-Cryst. Solids 352, 4008–4012 (2006)
G.J. Cuello, R. Fernández-Perea, F.J. Bermejo, G. Román-Ross, J. Campo, J. Non-Cryst. Solids 353, 2987–2992 (2007)
U. Dahlborg, M.J. Kramer, M. Besser, J.R. Morris, M. Calvo-Dahlborg, J. Non-Cryst. Solids 361, 63–69 (2013)
O.S. Roik, O.M. Yakovenko, V.P. Kazimirov, O.O. Bilovodska, N.V. Golovataya, V.E. Sokol’skii, J. Mol. Liq. 220, 155–160 (2016)
U. Dahlborg, M. Besser, M.J. Kramer, J.R. Morris, M. Calvo-Dahlborg, Physica B 412, 50–60 (2013)
S.Y. Wang, M.J. Kramer, M. Xu, S. Wu, S.G. Hao, D.J. Sordelet, K.M. Ho, C.Z. Wang, Phys. Rev. B 79, 144205 (2009)
A.K. Gangopadhyay, M.E. Blodgett, M.L. Johnson, J. McKnight, V. Wessels, A.J. Vogt, N.A. Mauro, J.C. Bendert, R. Soklaski, L. Yang, K.F. Kelton, J. Chem. Phys. 140, 044505 (2014)
H.B. Lou, X.D. Wang, Q.P. Cao, D.X. Zhang, J. Zhang, T.D. Hu, H.-K. Mao, J.-Z. Jiang, Proc. Natl. Acad. Sci. U. S. A. 110, 10068–10072 (2013)
P. Srirangam, M.J. Kramer, S. Shankar, Acta Mater. 59, 503–513 (2011)
S. Mudry, I. Shtablavyi, Chem. Met. Alloys 1, 163–167 (2008)
O.S. Roik, V.P. Kazimirov, V.E. Sokolskii, S.M. Galushko, J. Non-Cryst. Solids 364, 34–39 (2013)
O.M. Yakovenko, O.S. Roik, V.P. Kazimirov, V.E. Sokol’skii, N.V. Golovataya, G.M. Zelinskaya, T.M. Mika, J. Non-Cryst. Solids 455, 75–82 (2017)
O.S. Muratov, O.S. Roik, V.P. Kazimirov, N.V. Golovataya, V.K. Nosenko, G.M. Zelinskaya, T.M. Mika, V.E. Sokol’skii, J. Mol. Liq. 200, 213–222 (2014)
O.S. Muratov, O.S. Roik, V.P. Kazimirov, V.K. Nosenko, G.M. Zelinskaya, J. Non-Cryst. Solids 401, 44–49 (2014)
M. Shimoji, Liquid Metals: An Introduction to the Physics and Chemistry of Metals in the Liquid State (Academic Press, London, 1977)
T. Iida, R.I.L. Guthrie, The Physical Properties of Liquid Metals (Clarendon, Oxford, 1988)
I. Egry, Treatise on Process Metallurgy, vol I (Elsevier, Amsterdam, 2014), pp. 61–148
W. Chen, L. Zhang, Y. Du, B. Huang, Phil. Mag. 94, 1552–1577 (2014)
V.V. Makeev, E.L. Demina, P.S. Popel’, E.L. Arkhangel’skii, TVT 27(5), 889–895 (1989); High Temperature 27(5), 701–706 (1989)
J. Cheng, J. Grӧbner, N. Hort, K.U. Kainer, R. Schmid-Fetzer, Meas. Sci. Technol. 25, 062001 (2014)
Y.Q. Wu, X.F. Bian, T. Mao, X.L. Li, T.B. Li, C.D. Wang, Phys. Let. A 361, 265–269 (2007)
K. Khalouk, M. Mayoufi, J.G. Gasser, Phil. Mag. 90, 2695–2709 (2010)
A.L. Bel’tyukov, S.G. Men’shikova, V.I. Lad’yanov, J. Non-Cryst, Solids 410, 1–6 (2015)
A.L. Bel’tyukov, S.G. Men’shikova, V.I. Lad’yanov, A.Y. Korepanov, High Temp. 54, 667–674 (2016)
A.V. Borisenko, D.A. Yagodin, V.V. Filippov, P.S. Popel, A.G. Mozgovoj, Metally 8, 659–666 (2012)
X. Liu, J.F. Zhang, H.Y. Li, Q.C. Le, Z.Q. Zhang, W.Y. Hu, L. Bao, Ultrasonics 55, 6–9 (2015)
V.I. Lad’yanov, S.G. Men’shikova, A.I. Bel’tyukov, B.B. Maslov, Bull. Russ. Acad. Sci. Phys. 74, 1176–1178 (2010)
M.G. Vasin, S.G. Men’shikova, M.D. Ivshin, Physica A 449, 64–73 (2016)
G.M. Sivkov, D.A. Yagodin, P.S. Popel, High Temp. 44, 535–541 (2006)
J. Schmitz, B. Hallstedt, J. Brillo, I. Egry, M. Schick, J. Mater. Sci. 47, 3706–3712 (2012)
N.Y. Konstantinova, A.R. Kurochkin, A.V. Borisenko, V.V. Filippov, P.S. Popel, Metally 2, 144–149 (2016)
M. Schick, J. Brillo, I. Egry, B. Hallstedt, J. Mater. Sci. 47, 8145–8152 (2012)
A.R. Kurochkin, P.S. Popel, D.A. Yagodin, A.V. Borisenko, A.V. Okhapkin, High Temp. 51, 197–205 (2013)
A.R. Kurochkin, P.S. Popel, A.V. Borisenko, D.A. Yagodin, High Temp.-High Press. 44, 265–283 (2015)
G.M. Sivkov, D.A. Yagodin, P.S. Popel, Rasplavy 3, 37–39 (2006)
G. Sivkov, D. Yagodin, S. Kofanov, O. Gornov, S. Volodin, V. Bykov, P. Popel, V. Sidorov, C. Bao, M. Calvo-Dahlborg, U. Dahlborg, D. Sordelet, J. Non-Cryst. Sol. 353, 3274–3278 (2007)
F.-Q. Zu, J. Chen, X.-F. Li, L.-N. Mao, Y.-C. Liu, J. Mater. Res. 24, 2378–2384 (2008)
S. Okavi, M. Emuna, Y. Greenberg, E. Yahel, G. Makov, J. Mol. Liq. 220, 788–794 (2016)
Y. Plevachuk, V. Sklyarchuk, G. Gerbeth, S. Eckert, R. Novakovic, Surf. Sci. 605, 1034–1042 (2011)
F.Q. Zu, Z.G. Zhu, L.J. Guo, B. Zhang, J.P. Shui, C.S. Liu, Phys. Rev. B 64, 180203R (2001)
X.G. Song, X.F. Bian, J.X. Zhang, J. Zhang, J. Alloys Compd. 479, 670–673 (2009)
T. Gancarz, Fluid Phase Equilib. 427, 97–103 (2016)
S.A. Uporov, V.A. Bykov, D.A. Yagodin, J. Alloys Compd. 589, 420–424 (2014)
A. Yakymovych, V. Vus, S. Mudry, J. Mol. Liq. 219, 845–850 (2016)
A.L. Bel’tyukov, V.I. Lad’yanov, A.I. Shishmarin, S.G. Men’shikova, J. Non-Cryst. Solids 401, 245–249 (2014)
Y.N. Taran, V.I. Mazur, Structure of Eutectic Alloys (Metallurgiya, Moscow, 1978)
V.I. Nikitin, K.V. Nikitin, Hereditey in Cast Alloys (Mashinostroyenie, Moscow, 2005)
W. Jie, Z. Chen, W. Reif, K. Müller, Metall. Mater. Trans. A 34A, 799–806 (2003)
Q.Q. Sun, L.J. Liu, X.F. Li, F.Q. Zum, G.H. Ding, L.L. Guo, J. Chen, Z.Y. Huang, Mater. Sci. Technol. 25, 35–38 (2009)
Y. Xi, F.Q. Zu, L.J. Liu, R.R. Shen, X.F. Li, Z.H. Chen, Kovove Mater. 43, 432–439 (2005)
G.G. Krushenko, V.I. Shpakov, Tekhnol. Legk. Spl. 4, 59–62 (1973)
D.G. Eskin, Tsvetn. Met. (5), 97–99 (1989)
D.G. Eskin, Z. Metallkde. 87, 295–299 (1996)
B.A. Baum, G.V. Tjagunov, P.S. Popel, G.A. Hasin, L.V. Kovalenko, Steel USSR, 17, 21 (1987)
E.V. Kolotukhin, B.A. Baum, G.V. Tjagunov, V.N. Larionov, Izv. Akad. Nauk SSSR. Met. (2), 10 (1989)
E.A. Kuleshova, E.V. Kolotukhin, E.E. Baryshev, et al., Metalloved. Termich. Obrab. Met. 11, 61 (1990)
B.A. Baum, V.N. Larionov, L.V. Kovalenko, G.V. Tjagunov, E.A. Kuleshova, E.E. Baryshev, E.E. Tretjakova, E.V. Kolotukhin, Metally (1), 31–37 (1993)
V.I. Dobatkin, R.M. Gabidullin, B.A. Kolachev, G.S. Makarov, Gases and Oxides in Aluminum Wrought Alloys (Metallurgiya, Moscow, 1976)
R.-S. Zhou, R.L. Snyder, Acta Crystal. B47, 617–630 (1991)
H.-L. Gross, W. Mader, Chem. Comm. 1, 55–56 (1997)
P. Souza Santos, H. Souza Santos, S.P. Toledo, Mater. Res. 3(4), 104–114 (2000)
G.W. Brindley, J.O. Choe, J. Mineral. Soc. Am. 46, 771–785 (1961)
P. Šebo, J. Ivan, L. Táborský, A. Havalda, Kovove Mater. 11, 173–180 (1973)
J.A. Champion, B.J. Keene, J.M. Sillwood, J. Mater. Sci. 4, 39–49 (1969)
H. John, H. Hausner, J. Mater. Sci. Lett. 5, 540–551 (1986)
T.V. Atamanenko, D.G. Eskin, L. Zhang, L. Katgerman, Metall. Mater. Trans. A 41A, 2056–2066 (2010)
G.I. Eskin, Ultrasonic Treatment of Light Alloy Melts (Gordon & Breach OPA, Amsterdam, 1998)
G.I. Eskin, D.G. Eskin, Z. Metallkde. 95, 682–690 (2004)
F. Wang, D. Eskin, J. Mi, T. Connolley, M. Mounib, L. Lindsay, Acta Mater. 116, 354–363 (2016)
P. Li, V.I. Nikitin, E.G. Kandalova, K.V. Nikitin, Mater. Sci. Eng. A 332, 371 (2002)
D.H. StJohn, M. Qian, A. Easton, P. Cao, Z. Hildebrand, Metall. Mater, Trans. A 36A, 1669–1679 (2005)
D. Qiu, M.-X. Zhang, J.A. Taylor, P.M Kelly. Solidification Processing, in Proceedings of the 5th Decennial International Conference on Solidification Processing, ed. by H. Jones (University of Sheffield, Sheffield, 2007), pp. 153–158
E.F. Emley, Principles of Magnesium Technology (Pergamon, Oxford, 1966)
P. Cao, M. Qian, D.H. StJohn, Scr. Mater. 53, 841–844 (2005)
F.S. Yin, X.F. Sun, J.G. Li, H.R. Guan, Z.Q. Hu, Scripta Mater 48, 425 (2003)
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Dahlborg, U., Calvo-Dahlborg, M., Eskin, D.G., Popel, P.S. (2018). Thermal Melt Processing of Metallic Alloys. In: Eskin, D., Mi, J. (eds) Solidification Processing of Metallic Alloys Under External Fields. Springer Series in Materials Science, vol 273. Springer, Cham. https://doi.org/10.1007/978-3-319-94842-3_8
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