Skip to main content

Metallurgical Processing of Polymetallic Ocean Nodules

  • Chapter
  • First Online:
Deep-Sea Mining

Abstract

During the last five decades metallurgical processing of polymetallic nodule is of global interest—as well as a challenge—for researchers, and industries. This has generated a vast knowledge base, but till now there is no commercial operation. Some of the main reasons are: (1) lack of a techno-economically feasible mining operation, (2) poor economics of metal extraction, in comparison with similar terrestrial resources, and (3) environmental impact of mining as well as metal extraction. For metallurgists, the processing of polymetallic nodules becomes more challenging with passage of time because the environmental and processing norms keep changing for lean resources like polymetallic nodules. Considering the processes developed for nodule, and the current trend, the authors feel (1) production of alloy pig iron for use in series 200 stainless steel, and (2) aqueous reduction processes based on sulphuric acid, HCl/Cl2, or ammonia under atmospheric conditions hold good promise for a cost-effective, low capex, and environmentally accepted process.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Institutional subscriptions

References

  • Acharya S, Anand S, Das SC et al (1989) Ammonia leaching of ocean nodules using various reductants. Ertzmetall 42(2):66–73

    Google Scholar 

  • Acharya S, Das RP (1987) Kinetics and mechanism of the reductive ammonia leaching of ocean nodules by manganous ion. Hydrometallurgy 19:169–186

    Article  Google Scholar 

  • Acharya R, Ghosh MK, Anand S et al (1999) Leaching of metals from Indian ocean nodules in SO2-H2O-H2SO4-(NH4)2SO4 medium. Hydrometallurgy 53(2):169–175

    Article  Google Scholar 

  • Agarwal B, Hu P, Placidi M et al (2012) Feasibility study on manganese nodules recovery in the Clarion-Clipperton Zone. https://www.southampton.ac.uk/assetsimported/transforms/peripheral-block/UsefulDownloads_Download/8BC7B9645A8E4690A375D527F98DF7EC/LRET%20Collegium%202012%20Volume%202.pdf

    Google Scholar 

  • Agarwal JC, Wilder TC (1974) Recovery of metal values from manganese nodules. U.S. Patent 3,788,841, 29 Jan 1974

    Google Scholar 

  • Agarwal JC, Wilder TC (1975) Recovery of metal values from manganese nodules. Canadian Patent 980,130, 23 Dec 1975

    Google Scholar 

  • Agarwal JC, Barner HE, Beecher N et al (1978) Kennecott process for recovery of copper, nickel, cobalt and molybdenum from ocean nodules. Paper presented at AIME Annual Meeting, Denver, CO, February, SME preprint, pp 788–789

    Google Scholar 

  • Agarwal JC, Barner HE, Beecher N et al (1979) Kennecott process for recovery of copper, nickel, cobalt and molybdenum from ocean nodules. Min Eng 31(12):1704–1709

    Google Scholar 

  • Anand S, Das SC, Das RP et al (1988a) Leaching of manganese nodules at elevated temperature and pressure in the presence of oxygen. Hydrometallurgy 20:155–168

    Article  Google Scholar 

  • Anand S, Das SC, Das RP et al (1988b) Leaching of manganese nodule in ammoniacal medium using ferrous sulphate as reductant. Metall Trans B 19B:331–335

    Article  Google Scholar 

  • Anon (2006) 200 series stainless—an overview. Stainless Steel Industry, p 6–8

    Google Scholar 

  • Asai S, Negi H, Konishi Y (1986) Reductive dissolution of manganese dioxide in aqueous sulphur dioxide. Can J Chem Eng 64:237–242

    Article  Google Scholar 

  • Bhattacharya IN, Anand S, Das SC et al (1989) Ammonia leaching of manganese nodules in nodule test plant. Trans Indian Inst Metals 42(4):385–392

    Google Scholar 

  • Caron MH (1924) Process of recovering values from nickel and cobalt-nickel ores. US Patent 1,487,145, 18 Mar 1924

    Google Scholar 

  • Chen HH, Fu C, Zheng DJ (1992) Reduction leaching of manganese nodules by nickel matte in hydrochloric acid solution. Hydrometallurgy 28:269–275

    Article  Google Scholar 

  • Choi KS, Sohn JW (1995) Reduction leaching of manganese nodules with sodium sulfite in ammonium chloride solution. In: Proceedings of the ISOPE—ocean mining symposium, Tsukuba, Japan, 21–22 Nov, pp 193–200

    Google Scholar 

  • Das GK, Anand S, Das RP et al (2000) Sulfur dioxide—a leachant for oxidic materials in aqueous and non-aqueous media. Miner Process Extr Metall Rev 20(4–6):377–407

    Article  Google Scholar 

  • Das PK, Anand S, Das RP (1997) Minimization of nickel precipitation from H2O-NH3 (NH4)2SO4-SO2-MnO2 system. Int J Miner Process 50:77–86

    Article  Google Scholar 

  • Das RP (2001) India’s demonstration metallurgical plant to treat ocean nodule. In: Proceedings of the 4th ocean mining symposium, ISOPE, Szczecin, Poland, 23–27 Sept, pp 163–167

    Google Scholar 

  • Das RP, Anand S (1997) Aqueous reduction of polymetallic nodule for metal extraction. In: Proceedings of the 2nd ocean mining symposium, ISOPE, Seoul, 24–26 Nov, pp 165–171

    Google Scholar 

  • Das RP, Anand S, Das SC et al (1986) Leaching of manganese nodules in ammoniacal medium using glucose as a reductant. Hydrometallurgy 16:335–344

    Article  Google Scholar 

  • Das SC, Anand S, Das RP et al (1989) Sulphuric acid leaching of manganese nodules in the presence of charcoal. AusIMM Bull Proc 294(1):73–76

    Google Scholar 

  • Demopoulos GP, Li Z, Becze MG et al (2008) New technologies for HCl regeneration in chloride hydrometallurgy. World Metallurgy Erzmetall 61(2):89–98

    Google Scholar 

  • Fuerstenau DW, Han KN (1983) Metallurgy and processing of marine manganese nodules. Miner Process Technol Rev 1:1–83

    Article  Google Scholar 

  • Ghosh MK, Barik SP, Anand S (2008) Sulphuric acid leaching of polymetallic nodules using paper as a reductant. Trans Indian Inst Metals 61(6):477–481

    Article  Google Scholar 

  • Han KN, Fuerstenau DW (1975) Acid leaching of ocean nodules at elevated temperatures. Int J Miner Process 2(2):163–171

    Article  Google Scholar 

  • Han KN (1997) Strategies for processing of ocean floor manganese nodules. Trans Indian Inst Metals 51(1):41–54

    Google Scholar 

  • Han KN, Fuerstenau DW (1986) Extraction behaviour of metallic elements from deep sea manganese nodules in reducing medium. Mar Min 2:155–169

    Google Scholar 

  • Hanieg G, Meixner MJ (1974) Pressure leaching of manganese nodule with sulphuric acid. Erzmetall 27(7–8):335

    Google Scholar 

  • Hariprasad D, Mohapatra M, Anand S (2013) Non-isothermal self-sustained one pot dissolution of metal values from manganese nodule using NH3OHCl as a novel reductant in sulphuric acid medium. J Chem Technol Biotechnol 88(6):1114–1120

    Article  Google Scholar 

  • Harris BG, Lakshmanan VI, Sridhar R (2004) Process for the recovery of value metals from material containing base metal oxides. Patent WO/2004/101833, 25 Nov 2004

    Google Scholar 

  • Harris B, White C, Jansen M et al (2006) A new approach to the high concentration chloride leaching of nickel laterites. In: ALTA Ni/Co, vol 11, Perth, Australia, 4–7 July 2006, pp 1–20

    Google Scholar 

  • Haynes BW, Law SL, Barron DC, et al. (1985) Pacific manganese nodules: characterization and processing. Bulletin 679, U.S. Bureau of Mines

    Google Scholar 

  • Hsiaohong C, Chongyue F, Di-Ji Z (1992) Reduction leaching of manganese nodules by nickel matte in hydrochloric acid solution. Hydrometallurgy 28:269–272

    Article  Google Scholar 

  • Hubred GL (1973) An extractive metallurgy study on deep sea manganese nodules with special emphasis on the sulphuric acid autoclave leach. Ph.D. thesis, University of California, Berkley, p 220

    Google Scholar 

  • Hubred GL (1980) Manganese nodule extractive metallurgy: a review 1973–1978. Mar Min 2:191–212

    Google Scholar 

  • ISA (2008) Workshop on polymetallic nodule mining technology, status and challenges ahead. NIOT, Chennai. www.isa.org.jm/files/documents/EN/Pubs/Chennai.pdf.. Accessed 18–22 Feb 2008

  • Jana RK, Akerkar DD (1989) Studies of the metal–ammonia–carbon dioxide–water system in extraction metallurgy of poly metallic sea nodules. Hydrometallurgy 22:363–378

    Article  Google Scholar 

  • Jana RK, Murthy DSR, Nayak AK et al (1990) Leaching of roast-reduced poly metallic sea nodules to optimize the recoveries of copper, nickel and cobalt. Int J Miner Process 30:127–141

    Article  Google Scholar 

  • Jana RK, Singh DDN, Roy SK (1993) Hydrochloric acid leaching of sea nodules with methanol and ethanol addition. Mater Trans JIM (Japan) 34(70):593–598

    Article  Google Scholar 

  • Jana RK, Singh DDN, Roy SK (1995) Alcohol-modified hydrochloric acid leaching of sea nodules. Hydrometallurgy 38(3):289–298

    Article  Google Scholar 

  • Jana RK, Srikanth S, Pandey BD et al (1999a) Processing of deepsea manganese nodules at NML for recovery of copper, nickel and cobalt. Met Mater Process 11:133–144

    Google Scholar 

  • Jana RK, Pandey BD, Premchand (1999b) Ammoniacal leaching of roast reduced deep-sea manganese nodules. Hydrometallurgy 53:45–56

    Article  Google Scholar 

  • Jennings PH, Stanley RW, Ames HL et al (1973) Development of a process for purifying molybdenite concentrates. In: Evans DJI (ed) Proceedings of second international symposium on hydrometallurgy, AIME, Chicago, New York, 25 Feb–1 Mar 1973, p 868

    Google Scholar 

  • Jiang K, Jiang X, Feng L et al (2013) Study on self-catalysis reduction leaching of ocean Co-Mnpolymetallic ores in ammonia solution. In: Proceedings of the ISOPE ocean mining and gas hydrate symposium. Szczecin, Poland, 22–26 Sept

    Google Scholar 

  • Junghanss H, Roever W (1976) Method for reprocessing of manganese nodules and extraction of valuable materials contained in them. German Patent 2,501,284, 1 Sept 1976

    Google Scholar 

  • Kanungo SB (1999a) Rate process of the reduction leaching of manganese nodules in dilute HCl in the presence of pyrite Part-1: dissolution behavior of iron and sulphur species during leaching. Hydrometallurgy 52:313–330

    Article  Google Scholar 

  • Kanungo SB (1999b) Rate process of the reduction leaching of manganese nodules in dilute HCl in presence of pyrite Part-2: leaching behavior of manganese. Hydrometallurgy 52:331–347

    Article  Google Scholar 

  • Kanungo SB, Das RP (1988) Extraction of metals from manganese nodules of Indian ocean by leaching in aqueous solution of sulphur dioxide. Hydrometallurgy 20:135–146

    Article  Google Scholar 

  • Kanungo SB, Jena PK (1988a) Reduction leaching of manganese nodules of Indian Ocean origin in dilute hydrochloric acid. Hydrometallurgy 21(1):41–58

    Article  Google Scholar 

  • Kanungo SB, Jena PK (1988b) Studies on the dissolution of metal values in manganese nodules of Indian Ocean origin in dilute hydrochloric acid. Hydrometallurgy 21(1):23–39

    Article  Google Scholar 

  • Kawahara M, Mitsuo T (1992) Dilute sulphuric acid leaching of manganese nodules using hydrogen peroxide as a reductant. J Min Mater Process Inst Japan 108(5):396–401

    Google Scholar 

  • Khalafalla S, Pahlman JE (1981) Selective extraction of metals from Pacific sea nodules. JOM 33(8):37–42

    Article  Google Scholar 

  • Kim DJ, Park KH (1997) Study on the leaching mechanism of Cu and Ni from deep sea manganese nodules with hydrochloric acid. In: Proceedings of the 2nd ocean mining symposium, ISOPE, Seoul, Korea, 24–26 Nov, pp 172–176

    Google Scholar 

  • Kim I-S, Park K-H, Kim H-I (2005) Electroleaching of Fe-Ni-Cu-Co alloy. In: Proceedings of 6th ISOPE ocean mining symposium, Changsha, Hunan, China, 9–13 Oct, p 223

    Google Scholar 

  • Kotlinski R (1999) Metallogenesis of the world’s ocean against the background of oceanic crust evolution. Polish Geological Institute Special Papers, 4, 1999

    Google Scholar 

  • Kotlinski R, Stoyanova HV, Avramov HA (2008) An overview of the interoceanmetal (IOM) deep sea technology development (mining and processing). http://www.isa.org.jm/files/documents/EN/Workshops/Feb2008/IOM-Abst.pdf

  • Kyle J (2010) Nickel laterite processing technologies—whereto next? In: ALTA 2010 Nickel/cobalt/copper conference, Perth, WA, Australia, 24–27 May

    Google Scholar 

  • Lee JH, Gilje J, Zeitlin H (1978) Low temperature interaction of sulphur dioxide with Pacific ferromanganese nodules. Environ Sci Technol 12(13):1428–1431

    Article  Google Scholar 

  • Martino S, Parson LM (2012) A comparison between manganese nodules and cobalt crust economics in a scenario of mutual exclusivity. Mar Policy 36:790–800

    Article  Google Scholar 

  • Mehta KD, Das C, Pandey BD (2010) Leaching of copper, nickel and cobalt from Indian Ocean manganese nodules by Aspergillus niger. Hydrometallurgy 105:89–95

    Article  Google Scholar 

  • Mehta KD, Kumar R, Pandey BD et al (2008) Bio-dissolution of metals from activated nodules of Indian Ocean. Paper presented at International conference on Frontiers in Mechanochemistry and Mechanical Alloying held at CSIR-National Metallurgical Laboratory (CSIR-NML), Jamshedpur, India, 1–4 Dec 2008, under the aegis of International Mechanochemistry Association (IMA)

    Google Scholar 

  • Mishra D, Srivastava RR, Sahu KK et al (2011) Leaching of roast-reduced manganese nodules in NH3–(NH4)2CO3 medium. Hydrometallurgy 109:215–220

    Article  Google Scholar 

  • Mittal NK, Sen PK (2003) India's first medium scale demonstration plant for treating polymetallic nodules. Miner Eng 6:865–868

    Article  Google Scholar 

  • Mohanty PS, Ghosh MK, Anand S et al (1994) Leaching of manganese nodules in ammoniacal medium with elemental sulphur as reductant. Trans Inst Min Metall Sec C 103:C151–C155

    Google Scholar 

  • Mohapatra M, Mishra D, Anand S et al (2000) Aqueous reduction of cobalto-cobaltic oxides in ammoniacal medium using ammonium sulphite as the reductant. Hydrometallurgy 58(3):193–202

    Article  Google Scholar 

  • Monhemius AJ (1980) The extractive metallurgy of deep sea manganese nodule. In: Burkin R (ed) Topics in non ferrous extractive metallurgy. Society of Chemical Industry, London, pp 42–69

    Google Scholar 

  • Mukherjee A, Raichur AM, Modak JM et al (2003a) Bioprocessing of Indian Ocean nodules using marine isolate—effect of organics. Miner Eng 16:651–657

    Article  Google Scholar 

  • Mukherjee A, Raichur AM, Modak JM et al (2003b) Solubilisation of cobalt from ocean nodules at neutral pH—a novel bioprocess. J Ind Microbiol Biotechnol 30(10):606–612

    Article  Google Scholar 

  • Mukherjee A, Raichur AM, Modak JM et al (2004) Exploring process options to enhance metal dissolution in bioleaching of Indian Ocean nodules. J Chem Technol Biotechnol 79(5):512–517

    Article  Google Scholar 

  • Mohwinkel D, Kleint C, Koschinsky A (2014) Phase associations and potential selective extraction methods for selected high-tech metals from ferromanganese nodules and crusts with siderophores. Appl Geochem 43:13–21

    Article  Google Scholar 

  • Neuschutz D, Scheffler U, Junghans H (1977) Verfahren Zur Aufarbeitung von Manganknollen Durch Schwefelsaure Drucklaugung. (Method for the processing of manganese nodules by sulphuric acid pressure leaching). Erzmetall 30(2):61–67

    Google Scholar 

  • Pahlman JE, Khalafalla SE (1979) Selective recovery of nickel, cobalt, manganese from sea nodules with sulfurous acid. US patent 4,138,465, 6 Feb 1979

    Google Scholar 

  • Paramaguru RK, Kanungo SB (1998) Electrochemical phenomena in MnO2-FeS2 leaching in dilute HCl. Part-3: manganese dissolution from Indian Ocean nodules. Can Metall Q 37(5):405–417

    Google Scholar 

  • Park KH, Kim DJ (1999) Kinetics of copper and nickel leaching of manganese nodules with hydrochloric acid. Met Mater Process 11(2):117–124

    Google Scholar 

  • Park KH, Mohapatra D, Reddy BR et al (2007) A study on the oxidative ammonia-ammonium sulphate leaching of a complex (Cu-Ni-Co-Fe) matte. Hydrometallurgy 86:164–171

    Article  Google Scholar 

  • Parhi PK, Park KH, Nam CW, Park JT et al (2013) Extraction of rare earth metals from deep sea nodule using H2SO4 solution. Int J Miner Process 119:89

    Article  Google Scholar 

  • Parhi PK, Park KH, Kim HI et al (2011) Recovery of molybdenum from the sea nodule leach liquor by solvent extraction using Alamine 304-I. Hydrometallurgy 105:195–200

    Article  Google Scholar 

  • Parhi PK, Park KH, Nam CW et al (2015) Liquid-liquid extraction and separation of total rare earth (RE) metals from polymetallic manganese nodule leaching solution. J Rare Earths 3(2):207–213

    Article  Google Scholar 

  • Pophanken A, Friedrich B (2013) Challenges in the metallurgical processing of marine mineral resources. In: EMC 2013, University of Notre Dame, Indiana, 26–28 June 2013, p 681

    Google Scholar 

  • Premchand P, Jana RK (1999) Processing of polymetallic sea nodules: an overview. In: Proceedings of the 3rd ocean mining symposium, ISOPE, Goa, India, 8–10 Nov, pp 237–245

    Google Scholar 

  • Randhawa NS, Jana RK, Das NN (2013) Silicomanganese production utilising low grade manganese nodules leaching residue. Trans Inst Min Metall Sec C 122(1):6–14

    Google Scholar 

  • Rodriguez MP, Mosqueda AM, Ariza SB (2001) Hydrometallurgical processing technology of the polymetallic nodules from Interoceanmetal mining site. In: Proceedings of the 4th ISOPE ocean mining symposium, Szczecin, Poland, 23–27 Sept, p 177

    Google Scholar 

  • Rodriguez MP, Aja R, Miyares RC (2013) Optimization of the existing methods for recovery of basic metals from polymetallic nodules. In: Proceedings of the 10th ISOPE ocean mining and gas hydrates symposium, Szczecin, Poland, 22–26 Sept 2013, p 173

    Google Scholar 

  • Rokukawa N (1990) Extraction of nickel, cobalt and copper from ocean manganese nodules with mixed solution of ammonium carbonate and ammonium sulphite. Shigen-to-Sozai 106(4):205–209

    Article  Google Scholar 

  • Rokukawa N (1995) Development for hydrometallurgical process of cobalt rich crusts. In: Proceedings of the ISOPE—ocean mining symposium, Tsukuba, Japan, 21–22 Nov, pp 217–221

    Google Scholar 

  • Rao M, Li G, Jiang T, Luo J et al (2013) Carbothermic reduction of nickeliferous laterite ores for nickel pig iron production in China: a review. JOM 65(11):1573–1583

    Article  Google Scholar 

  • Sanjay K, Subbaiah T, Anand S et al. (1999) Manganese recovery from leach liquors/residues generated during hydrometallurgical processing of manganese nodules. In: Proceedings of the 3rd ocean mining symposium, ISOPE, Goa, India, 8–10 Nov 1999, p 246

    Google Scholar 

  • Sazbo LJ (1976) Recovery of metal values from manganese deep sea nodules using ammoniacal cuprous leach solutions. US patent 3,983,017, 28 Sept 1976

    Google Scholar 

  • Sen PK (1999) Processing of sea nodules: current status and future needs. Met Mater Process 11(2):85–100

    Google Scholar 

  • Sen PK (2010) Metals and materials from deep sea nodules: an outlook for the future. Int Mater Rev 55(6):364–391

    Article  Google Scholar 

  • Shen YF, Xue WY, Niu WY (2008) Recovery of Co(II) and Ni(II) from hydrochloric acid solution of alloy scrap. Trans Nonferrous Metals Soc China 18(5):1262–1268

    Article  Google Scholar 

  • Smit JT, Steyl IDT (2005) Leaching process in the presence of hydrochloric acid for the recovery of a value metal from an ore. WIPO Patent Application PCT/IB2005/003136, 21 Oct 2005

    Google Scholar 

  • Sridhar R (1974) Thermal upgrading of sea nodules. J Metals 26(12):18–22

    Google Scholar 

  • Sridhar R, Jones WE, Warner JS (1976) Extraction of copper, nickel, cobalt from sea nodules. J Metals 28(4):32–37

    Google Scholar 

  • Sridhar R, Warner JS, Bell MCE (1977) Non-ferrous metal recovery from deep sea nodules. US Patent 4,049,438, 20 Sept 1977

    Google Scholar 

  • Sridhar V, Verma JK (2011) Extraction of copper, nickel and cobalt from the leach liquor of manganese-bearing sea nodules using LIX 984 N and ACORGA M5640. Miner Eng 24:959–962

    Article  Google Scholar 

  • Srikanth S, Alex TC, Agrawal A et al. (1997) Reduction roasting of deep-sea manganese nodules using liquid and gaseous reductants. In: Proceedings of the 2nd ocean mining symposium, Seoul, South Korea, 24–26 Nov 1997, pp 177–184

    Google Scholar 

  • Stefanova VP, Iliev PK, Stefanov BS (2013) Copper, nickel and cobalt extraction from FeCuNiCoMn alloy obtained after pyrometallurgical processing of deep sea nodules. In: Proceedings of the 10th ISOPE ocean mining and gas hydrates symposium, Szczecin, Poland, 22–26 Sept 2013, p 180

    Google Scholar 

  • Stefanova VP, Iliev PK, Stefanov BS et al (2009) Selective dissolution of FeCuNiCoMn alloy obtained after pyrometallurgical processing of polymetallic nodules. In: Proceedings of the 8th ISOPE ocean mining symposium, Chennai, India, Sept 2009, p 186

    Google Scholar 

  • Vranka F (2001) Optimisation of technologies for processing of polymetallic nodules. In: Proceedings of the 4th ocean mining symposium, ISOPE, Szczecin, Poland, 23–27 Sept 2001, pp 172–175

    Google Scholar 

  • Vranka F, Kotlinski R (2005) Polymetallic nodules processing in Interoceanmetal—the present and the future. In: Proceedings of the 15th International offshore and polar engineering conference, Seoul, Korea, 19–24 June, pp 392–397

    Google Scholar 

  • Vu H, Jandova J, Lisa K et al (2005) Leaching of manganese deep ocean nodules in FeSO4–H2SO4–H2O solutions. Hydrometallurgy 77:147–153

    Article  Google Scholar 

  • Wang C-Y, Qiu D-F, Yin F et al (2010) Slurry electrolysis of ocean polymetallic nodule. Trans Nonferrous Metals Soc China 20:s60–s64

    Article  Google Scholar 

  • Wang Y, Li Z, Li H (2005) A new process for leaching metal values from ocean polymetallic nodules. Miner Eng 18:1093–1098

    Article  Google Scholar 

  • Watanabe A, Miwa S, Sakakibara S (1982) Sulphuric acid leaching of manganese nodules at elevated temperature. Nogoya Kogyo Gijutsu Shikensho Hokoku 31(6–7):190 (Japan), (CA 100: 107148)

    Google Scholar 

  • Wilder TC, Galin WE (1976) Reduction smelting of manganese nodules with a liquid reductant. U.S. Patent 3,957,485, 18 May 1976

    Google Scholar 

  • Xiang Z, Zequan H, Yujun S et al. (1999) The smelting–rusting-solvent extraction processes to recover valuable metals from polymetallic nodules. In: Proceedings of the 3rd ocean mining symposium, ISOPE, Goa, India, 8–10 Nov 1999, pp 227–231

    Google Scholar 

  • Zhang Y, Liu Q, Sun C (2001a) Sulphuric acid leaching of ocean manganese nodules using phenols as reducing agents. Miner Eng 14(5):525–537

    Article  Google Scholar 

  • Zhang Y, Liu Q, Sun C (2001b) Sulphuric acid leaching of ocean manganese nodules using aromatic amines as reducing agents. Miner Eng 14(5):539–542

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. P. Das .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2017 Springer International Publishing AG

About this chapter

Cite this chapter

Das, R.P., Anand, S. (2017). Metallurgical Processing of Polymetallic Ocean Nodules. In: Sharma, R. (eds) Deep-Sea Mining. Springer, Cham. https://doi.org/10.1007/978-3-319-52557-0_12

Download citation

Publish with us

Policies and ethics