Abstract
The feasibility of simultaneous vanadium extraction and phosphorus removal from vanadium-containing hot metal was demonstrated with laboratory experimental investigation. The effect of CaO addition on the distribution behavior of vanadium, phosphorus between basic vanadium slag and semi-steel as well as the influence of basicity on the leaching behavior of vanadium, phosphorus was particularly studied. Results show that vanadium oxidation ratio slightly decreases with the increase of basicity, but phosphorus oxidation ratio rapidly increases with the increase of basicity. The leaching of roasted vanadium slag with various CaO contents indicated that the optimal slag basicity for extracting vanadium was 1.5. The maximum leaching efficiency of vanadium could reach 84.02% and the sequence of vanadium leaching efficiency by using different leaching reagents was: 160 g/L Na2CO3 > 100 g/L NaHCO3 > 400 g/L (NH4)2CO3 > 5% H2SO4.
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References
R.R. Moskalyk, A.M. Alfantazi, Processing of vanadium: a review. Miner. Eng. 16, 793 (2003)
D.X. Huang, Vanadium Extraction and Steelmaking (Metallurgical Industry Press, Beijing, China, 2000), p. 35
D.S. Bradbury, The production of vanadium pentoxide, in The 41st Annual Conference of Metallurgists of CIM, Vanadium-Geology, Processing and Applications, Montreal, Quebec, Canada (2002), p. 115
Z.H. Tian, B.H. Li, X.M. Zhang, Z.H. Jiang, Double slag operation dephosphorization in BOF for producing low phosphorus steel. J. Iron. Steel Res. Int. 16(3), 6 (2009)
X. Yang, F.M. Sun, J.L. Yang, F. Liu, K.S. Cheng, J.H. Wang, Optimization of low phosphorus steel production with double slag process in BOF. J. Iron. Steel Res. Int. 20(8), 41 (2013)
Y.L. Zhang, F. Zhao, Y.G. Wang, Effects of influencing factors on distribution behaviors of vanadium between hot metal and FeO–SiO2–MnO(–TiO2) slag system. Steel Res. Int. 82(8), 940 (2011)
S.Y. Gao, Z.H. Tian, L.X. Zhu, C.L. Zhao, Z.H. Yan, B.G. Luo, G. Wei, Study on dephosphoriztion of hot metal in coverter, J. Univ. Sci. Technol. Beijing, 33(supp1.1), 63 (2011)
D.Y. Shin, C.H. Wee, M.S. Kim et al., Distribution behavior of vanadium and phosphorus between slag and molten steel. Met. Mater. Int. 13(2), 171 (2007)
F. Pahlevani, H. Shibata, N. Maruoka et al., Behavior of vanadium and niobium during hot metal dephosphorization by CaO–SiO2–FetO slag. ISIJ Int. 51(10), 1624 (2011)
X. Qiu, B. Xie, L. Jiang et al., Experimental study of phosphorus distribution between slag and metal during duplex dephosphorus converter processing, in 4th International Symposiumon High-Temperature Metallurgical Processing-Held during the TMS 2013 Annual Meeting and Exhibition, San Antonio, Texas, USA (2013), p. 199
X.P. Zhen, B. Xie, C.Y. Zhao et al., Vanadium distribution behavior at the end point of vanadium extraction byconverter process. J. Univ. Sci. Technol. Beijing 34(12), 1371 (1013)
H.Y. Li, N. Wang, B. Xie, Vanadium extraction from high calcium-content vanadium slag by calcification roasting, in Chen Honorary Symposium on Hydrometallurgy, Electrometallurgy and Materials Characterization-Held during the TMS 2012 Annual Meeting and Exhibition. Oakland, California, USA (2012), p. 621
X.S. Li, B. Xie, Extraction of vanadium from high calcium vanadium slag using direct roasting and soda leaching. Int. J. Miner. Metall. Mater. 19(7), 595 (2012)
R. Inoue, H. Suito, Distribution of vanadium between liquid iron and MgO saturated slag of the system CaO–MgO–FeOx–SiO2. Trans. Iron Steel Inst. Jpn. 22(9), 705 (1982)
S. Basu, A.K. Lahiri, S. Seetharaman, Phosphorus partition between liquid steel and CaO–SiO2–FeOx–P2O5–MgO slag containing 15 to 25 Pct FeO. Metall. Mater. Trans. B 38B(4), 623 (2007)
J. Diao, Applied fundamental research on medium and high phosphorus hot metal refining by duplex process in converter [Dissertation] (in Chinese), ChongQing university, ChongQing, China (2010) p. 41
Q.M. Feng, Y.H. Shao, L.M. Ou et al., Vanadium recovery by hydrometallurgy from V-containing deposition residue of sodium aluminate solution. Nonferrous Met. 62(4), 57 (2010)
H.Y. Li, N. Wang, B. Xie, Y. Wang, C. Li, H.X. Fang, A Method for Extracting Vanadium from Vanadium Bearing Roasted Materials (in Chinese), Chinese Patent, Appl. 201210066735.5 (2012)
Z.J. Ju, C.Y. Wang, F. Yin, Y.Q. Yang, D.F. Li, Process of vanadium extraction from stone coal vanadium ore byactivated sulfuric acid leaching at atmospheric pressure. Chin. J. Nonferrous Met. 22(7), 2061 (2012)
Acknowledgements
This work was financially supported by the National Basic Research and Development Program of China (No. 2013CB632604), Scientific and Technological Research Program of Chongqing Municipal Education Commission (Grant No. KJ1601403, KJ1601412), and Scientific Research Program of Chongqing University of Education (Grant No. KY201551C).
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Zhang, T., Wang, Z., Li, DW., Jiang, D. (2017). Effect of CaO Addition on the Behavior of Vanadium and Phosphorus During Oxidation and Leaching Process. In: Hwang, JY., et al. 8th International Symposium on High-Temperature Metallurgical Processing. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-51340-9_52
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DOI: https://doi.org/10.1007/978-3-319-51340-9_52
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