Skip to main content

Hydrogen Depth-Profiling and Desorption Kinetics in Rapidly Solidified Al-Fe Alloys

  • Conference paper
ICAA13 Pittsburgh

Abstract

Hydrogen surface segregation and trapping in rapidly solidified Al-0.2; 0.5 at % Fe alloys has been studied through elastic recoil detection technique, Rutherford backscattering spectroscopy and thermal desorption spectroscopy. It was detected that most hydrogen was localized in the subsurface regions (400 nm) and estimated to be 3.6 at % in Al-0.2 Fe alloy. Strong hydrogen segregation on air-side surface in alloy showed increase in its content up to 9.6 at % after heat treatment at 500°C. Our results indicated that solute-vacancy interactions and microstructural features affect hydrogen behaviour in Al-Fe alloys. The hydrogen trapping at iron atoms in the substitutional sites was concluded to be predominant.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 279.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. A. Kamegawa and M. Okada. “Hydrogen storage technology in high pressure science”, The Rev. High Pressure Sci. Technol, 17 (2007), 173–179.

    Article  Google Scholar 

  2. J.R. Scully, G.A. Young, and S.W. Smith. “Hydrogen embrittlement of aluminum and aluminum-based alloys”, ed. R.P. Gangloff and B.P. Somerday, Gaseous hydrogen embrittlement of materials in energy technologies, vol. 1 (Cambridge: Woodhead Publishing Limited, 2012) 707–768.

    Chapter  Google Scholar 

  3. I.I. Tashlykova-Bushkevich, “Patterns of concentration-depth profiles in melt-substrate quenched aluminium alloys”, (Paper presented at the 12th ICAA Int. Conf. on Aluminium alloys, Yokohama, Japan, 7 September 2010), 1800–1805.

    Google Scholar 

  4. I. Tashlykova-Bushkevich, T. Shikagawa, V. Shepelevich, and G. Itoh. “Effect of rapid solidification processing on hydrogen behaviour in aluminium”, Mater. Sci. Forum, 654–656 (2010), 998–1001.

    Article  Google Scholar 

  5. I. Tashlykova-Bushkevich, G. Itoh, V. Shepelevich, and T. Shikagawa. “Kinetics of hydrogen desorption from rapidly solidified Al-Cr alloys”, Mater. Trans., 52 (2011), 895–899.

    Article  Google Scholar 

  6. I. Tashlykova-Bushkevich, T. Shikagawa, T. Suzuki, V. Shepelevich, and G. Itoh. “Effect of Cr and Zr dopes on hydrogen behaviour in rapidly solidified aluminium foils”, Mater. Sci. Forum, 638–642 (2010), 465–468.

    Article  Google Scholar 

  7. T. Izumi and G. Itoh. “Thermal desorption spectroscopy study on the hydrogen trapping states in a pure aluminum”, Mater. Trans., 52 (2011), 130–134.

    Article  Google Scholar 

  8. C.E. Buckley and H.K. Birnbaum. “Characterization of the charging techniques used to introduce hydrogen in aluminum”, J. Alloys Compd., 330–332 (2002), 649–653.

    Article  Google Scholar 

  9. G.A. Young and J.R. Scully. “The diffusion and trapping of hydrogen in high purity aluminum”, Acta Mater., 46 (1998), 6337–6349.

    Article  Google Scholar 

  10. I. Tashlykova-Bushkevich, Cz. Kozak, and V. Shepelevich, “Microstructural features of Al-Fe alloy foils”, Przeglad Elektrotechniczny, 84 (2008), 93–95 (in Russian).

    Google Scholar 

  11. G. Lu, D. Orlikowski, I. Park, O. Politano, and E. Kaxiras, “Energetics of hydrogen impurities in aluminum and their effect on mechanical properties”, Phys. Rev. B, 65 (2002), 064102-1–064102-8.

    Google Scholar 

  12. P. Rozenak, B. Ladna, and H.K. Birnbaum. “SIMS study of deuterium distribution in chemically charged aluminum containing oxide layer defects and trapping sites”, J. Alloys Compd., 415 (2006), 134–142.

    Article  Google Scholar 

  13. J.C. Liu, A.D. Marwick, and F.K. LeGoues. “Hydrogen segregation and trapping in the Al/Si(111) interface”, Phys. Rev. B, 44 (1991), 1861–1874.

    Article  Google Scholar 

  14. D. Milcius, L.L. Pranevicius, and C. Templier. “Hydrogen storage in the bubbles formed by high-flux ion implantation in thin Al films”, J. Alloys Compd., 398 (2005), 203–207.

    Article  Google Scholar 

  15. I. Tashlykova-Bushkevich and G. Itoh. “Effect of rapid solidification on microstructural features of Al-Cr alloys”, Mater. Sci. Forum, 706–709 (2012), 301–304.

    Article  Google Scholar 

  16. H. Umeda, G. Itoh, and Y. Kato. “Effect of heat treatment condition on the hydrogen content in Al-4 % Mg alloys”, J. Japan Inst. Light Metals, 56 (2006), 203–209.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2012 TMS (The Minerals, Metals & Materials Society)

About this paper

Cite this paper

Tashlykova-Bushkevich, I.I., Itoh, G. (2012). Hydrogen Depth-Profiling and Desorption Kinetics in Rapidly Solidified Al-Fe Alloys. In: Weiland, H., Rollett, A.D., Cassada, W.A. (eds) ICAA13 Pittsburgh. Springer, Cham. https://doi.org/10.1007/978-3-319-48761-8_9

Download citation

Publish with us

Policies and ethics