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Optimized Perturbation Theory for Calculating the Hyperfine Line Shift and Broadening of Heavy Atoms in a Buffer Gas

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Frontiers in Quantum Methods and Applications in Chemistry and Physics

Part of the book series: Progress in Theoretical Chemistry and Physics ((PTCP,volume 29))

Abstract

A consistent relativistic approach, based on the atomic gauge-invariant relativistic perturbation theory and the exchange perturbation theory, is presented and applied to calculating the interatomic potentials, van der Waals constants, hyperfine structure line collision shift and broadening for heavy atoms in an atmosphere of the buffer inert gas. The corresponding data on the collision hyperfine line shift and broadening for the thallium, alkali (Rb, Cs) and lanthanide (ytterbium) atoms in an atmosphere of the inert gas (He, Kr, Xe) are listed and compared with available alternative theoretical and experimental results.

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Acknowledgments

The support of the Odessa State University—OSENU as well as of the Ministry of Education and Science of Ukraine (2013) is acknowledged. The author would like to thank Prof. Marco Nascimento for his invitation to present this contribution at QSCP-XVIII (Paraty, Rio de Janeiro, Brazil), and Prof. Andrey N. Starostin (Centre for Theoretical Physics and Computational Mathematics, Research State Center of the Russian Federation “Troitsk Institute for Innovation and Fusion Research”, Troitsk, Russian Federation) and Vladimir G. Shevchuk (Department of Chemical Physics, Odessa National University, Odessa, Ukraine) for useful comments.

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  1. Odessa State Environmental University (OSENU), L’vovskaya Str., 15, Odessa-9, 65016, Ukraine

    Olga Yu. Khetselius

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  1. Olga Yu. Khetselius
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Correspondence to Olga Yu. Khetselius .

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Editors and Affiliations

  1. Department of Physical Chemistry, Federal University of Rio de Janeiro, Rio de Janeiro, Brazil

    M.A.C. Nascimento

  2. Laboratoire de Chimie Physique, CNRS & UPMC, Paris, France

    Jean Maruani

  3. Department of Quantum Chemistry, Uppsala University, Uppsala, Sweden

    Erkki J. Brändas

  4. Instituto de Fisica Fundamental, CSIC, Madrid, Spain

    Gerardo Delgado-Barrio

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Khetselius, O.Y. (2015). Optimized Perturbation Theory for Calculating the Hyperfine Line Shift and Broadening of Heavy Atoms in a Buffer Gas. In: Nascimento, M., Maruani, J., Brändas, E., Delgado-Barrio, G. (eds) Frontiers in Quantum Methods and Applications in Chemistry and Physics. Progress in Theoretical Chemistry and Physics, vol 29. Springer, Cham. https://doi.org/10.1007/978-3-319-14397-2_4

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