Abstract
The electrochemical capacitor has received remarkable attention due to its bridging performance for the power/energy interval between conventional capacitors and batteries/fuel cells. The electrochemical behavior of capacitors is mainly influenced by using electrode materials. One of the promising pseudocapacitive materials is metal hydroxide, whose electrochemical performances originated from reversible Faradaic reactions between the electrode and electrolyte interface. It is necessary to use advanced pseudocapacitive materials to manufacture supercapacitors to solve their problem of lower energy density (E) compared to lithium batteries. Different strategies, such as doping, various synthesis methods, fabrication of composites, and utilization of conductive substrates, have been introduced. This chapter represents investigations on pseudocapacitive electrode materials, essentially transition metal hydroxides. Some published reports about applications of metal hydroxides as pseudocapacitive electrode materials with their different structures and composites are summarized in this chapter. Some strategies to improve the electrochemical performance of transition metal hydroxides are mentioned.
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References
G. Xiong, K. Hembram, R.G. Reifenberger, T.S. Fisher, MnO2-coated graphitic petals for supercapacitor electrodes. J. Power Sourc. 227, 254–259 (2013)
H.Y. Lee, S.W. Kim, H.Y. Lee, Expansion of active site area and improvement of kinetic reversibility in electrochemical pseudocapacitor electrode. Electrochem. Solid-State Lett. 4, A19 (2001)
X. Cai, S.H. Lim, C.K. Poh, L. Lai, J. Lin, Z. Shen, High-performance asymmetric pseudocapacitor cell based on cobalt hydroxide/graphene and polypyrrole/graphene electrodes. J. Power Sourc. 275, 298–304 (2015)
D.-D. Zhao, S.-J. Bao, W.-J. Zhou, H.-L. Li, Preparation of hexagonal nanoporous nickel hydroxide film and its application for electrochemical capacitor. Electrochem. Commun. 9, 869–874 (2007)
D.-S. Kong, J.-M. Wang, H.-B. Shao, J.-Q. Zhang, C. Cao, Electrochemical fabrication of a porous nanostructured nickel hydroxide film electrode with superior pseudocapacitive performance. J. Alloy. Compd. 509, 5611–5616 (2011)
A. Shaikh, B.K. Singh, K. Purnendu, P. Kumari, P.R. Sankar, G. Mundra, S. Bohm, Utilization of the nickel hydroxide derived from a spent electroless nickel plating bath for energy storage applications. RSC Sustain. (2023)
P.E. Lokhande, K. Pawar, U.S. Chavan, Chemically deposited ultrathin α-Ni(OH)2 nanosheet using surfactant on Ni foam for high performance supercapacitor application. Mater. Sci. Energy Technol. 1, 166–170 (2018)
X. Xiong, D. Ding, D. Chen, G. Waller, Y. Bu, Z. Wang, M. Liu, Three-dimensional ultrathin Ni(OH)2 nanosheets grown on nickel foam for high-performance supercapacitors. Nano Energy 11, 154–161 (2015)
A.V. Radhamani, M.K. Surendra, M.S.R. Rao, Tailoring the supercapacitance of Mn2O3 nanofibers by nanocompositing with spinel-ZnMn2O4. Mater. Des. 139, 162–171 (2018)
R.M. Obodo, N.M. Shinde, U.K. Chime, S. Ezugwu, A.C. Nwanya, I. Ahmad, M. Maaza, P.M. Ejikeme, F.I. Ezema, Recent advances in metal oxide/hydroxide on three-dimensional nickel foam substrate for high performance pseudocapacitive electrodes. Curr. Opin. Electrochem. 21, 242–249 (2020)
H.B. Li, M.H. Yu, X.H. Lu, P. Liu, Y. Liang, J. Xiao, Y.X. Tong, G.W. Yang, Amorphous cobalt hydroxide with superior pseudocapacitive performance. ACS Appl. Mater. Interfaces 6, 745–749 (2014)
M.C. Bernard, R. Cortes, M. Keddam, H. Takenouti, P. Bernard, S. Senyarich, Structural defects and electrochemical reactivity of β-Ni(OH)2. J. Power Sourc. 63, 247–254 (1996)
Z. Tian, C. Liang, J. Liu, H. Zhang, L. Zhang, Reactive and photocatalytic degradation of various water contaminants by laser ablation-derived SnOx nanoparticles in liquid. J. Mater. Chem. 21, 18242–18247 (2011)
D. Liang, S. Wu, J. Liu, Z. Tian, C. Liang, Co-doped Ni hydroxide and oxide nanosheet networks: laser-assisted synthesis, effective doping, and ultrahigh pseudocapacitor performance. J. Mater. Chem. A 4, 10609–10617 (2016)
Y.J. Mai, J.P. Tu, X.H. Xia, C.D. Gu, X.L. Wang, Co-doped NiO nanoflake arrays toward superior anode materials for lithium ion batteries. J. Power Sourc. 196, 6388–6393 (2011)
X. Liu, R. Ma, Y. Bando, T. Sasaki, A general strategy to layered transition-metal hydroxide nanocones: tuning the composition for high electrochemical performance. Adv. Mater. 24, 2148–2153 (2012)
X. Ma, J. Liu, C. Liang, X. Gong, R. Che, A facile phase transformation method for the preparation of 3D flower-like β-Ni(OH)2/GO/CNTs composite with excellent supercapacitor performance. J. Mater. Chem. A 2, 12692–12696 (2014)
Z. Lu, Z. Chang, W. Zhu, X. Sun, Beta-phased Ni(OH)2 nanowall film with reversible capacitance higher than theoretical Faradic capacitance. Chem. Commun. 47, 9651–9653 (2011)
G. Lee, C.V. Varanasi, J. Liu, Effects of morphology and chemical doping on electrochemical properties of metal hydroxides in pseudocapacitors. Nanoscale 7, 3181–3188 (2015)
X. Ma, Y. Li, Z. Wen, F. Gao, C. Liang, R. Che, Ultrathin β-Ni(OH)2 nanoplates vertically grown on nickel-coated carbon nanotubes as high-performance pseudocapacitor electrode materials. ACS Appl. Mater. Interfaces. 7, 974–979 (2015)
X.H. Xia, J.P. Tu, Y.Q. Zhang, Y.J. Mai, X.L. Wang, C.D. Gu, X.B. Zhao, Three-dimentional porous nano-Ni/Co(OH)2 nanoflake composite film: a pseudocapacitive material with superior performance. J. Phys. Chem. C 115, 22662–22668 (2011)
D. Xia, H. Chen, J. Jiang, L. Zhang, Y. Zhao, D. Guo, J. Yu, Facilely synthesized α phase nickel–cobalt bimetallic hydroxides: Tuning the composition for high pseudocapacitance. Electrochim. Acta 156, 108–114 (2015)
H.-Y. Hsu, K.-H. Chang, R.R. Salunkhe, C.-T. Hsu, C.-C. Hu, Synthesis and characterization of mesoporous Ni–Co oxy-hydroxides for pseudocapacitor application. Electrochim. Acta 94, 104–112 (2013)
R.R. Salunkhe, K. Jang, S. Lee, H. Ahn, Aligned nickel-cobalt hydroxide nanorod arrays for electrochemical pseudocapacitor applications. RSC Adv. 2, 3190–3193 (2012)
H. Chen, J. Jiang, L. Zhang, Y. Zhao, D. Guo, Y. Ruan, D. Xia, One-pot fabrication of layered α-phase nickel-cobalt hydroxides as advanced electrode materials for pseudocapacitors. ChemPlusChem. 80, 181–187 (2015)
Y. Zhang, Z. Shi, L. Liu, Y. Gao, J. Liu, High conductive architecture: bimetal oxide with metallic properties@ bimetal hydroxide for high-performance pseudocapacitor. Electrochim. Acta 231, 487–494 (2017)
G. Xiong, P. He, L. Liu, T. Chen, T.S. Fisher, Plasma-grown graphene petals templating Ni–Co–Mn hydroxide nanoneedles for high-rate and long-cycle-life pseudocapacitive electrodes. J. Mater. Chem. A 3, 22940–22948 (2015)
G. Xiong, K. Hembram, D.N. Zakharov, R.G. Reifenberger, T.S. Fisher, Controlled thin graphitic petal growth on oxidized silicon. Diam. Relat. Mater. 27, 1–9 (2012)
C. Choi, H.J. Sim, G.M. Spinks, X. Lepró, R.H. Baughman, S.J. Kim, Elastomeric and dynamic MnO2/CNT core–shell structure coiled yarn supercapacitor. Adv. Energy Mater. 6, 1502119 (2016)
M. Zhi, C. Xiang, J. Li, M. Li, N. Wu, Nanostructured carbon–metal oxide composite electrodes for supercapacitors: a review. Nanoscale 5, 72–88 (2013)
D.Y. Lee, S.J. Yoon, N.K. Shrestha, S.-H. Lee, H. Ahn, S.-H. Han, Unusual energy storage and charge retention in Co-based metal–organic-frameworks. Microporous Mesoporous Mater. 153, 163–165 (2012)
K. Zhang, Q. Xu, X. Liu, J. Zhang, Y. Xu, M. Zhou, J. Li, M. Du, X. Qian, B. Xu, A ship-in-a-bottle architecture transmission metal hydroxides@ conducting MOF on carbon nanotube yarn for ultra-stable quasi-solid-state supercapacitors. J. Mater. Chem. A (2023)
W. Liu, X. Hu, H. Li, H. Yu, Pseudocapacitive Ni–Co–Fe Hydroxides/N-doped carbon nanoplates-based electrocatalyst for efficient oxygen evolution. Small 14, 1801878 (2018)
P. Sun, R. Ma, X. Bai, K. Wang, H. Zhu, T. Sasaki, Single-layer nanosheets with exceptionally high and anisotropic hydroxyl ion conductivity. Sci. Adv. 3, e1602629 (2017)
M.A. Woo, M.-S. Song, T.W. Kim, I.Y. Kim, J.-Y. Ju, Y.S. Lee, S.J. Kim, J.-H. Choy, S.-J. Hwang, Mixed valence Zn–Co-layered double hydroxides and their exfoliated nanosheets with electrode functionality. J. Mater. Chem. 21, 4286–4292 (2011)
J. Yingchang, S. Yun, L. Yanmei, T. Wenchao, P. Zhichang, Y. Peiyu, L. Yuesheng, G. Qinfen, H. Linfeng, Charge transfer in ultrafine LDH nanosheets/graphene interface with superior capacitive energy storage performance (2017)
H. Chen, L. Hu, M. Chen, Y. Yan, L. Wu, Nickel–cobalt layered double hydroxide nanosheets for high-performance supercapacitor electrode materials. Adv. Func. Mater. 24, 934–942 (2014)
Z. Pan, Y. Jiang, P. Yang, Z. Wu, W. Tian, L. Liu, Y. Song, Q. Gu, D. Sun, L. Hu, In situ growth of layered bimetallic ZnCo hydroxide nanosheets for high-performance all-solid-state pseudocapacitor. ACS Nano 12, 2968–2979 (2018)
N. Mahmood, M. Tahir, A. Mahmood, W. Yang, X. Gu, C. Cao, Y. Zhang, Y. Hou, Role of anions on structure and pseudocapacitive performance of metal double hydroxides decorated with nitrogen-doped graphene. Sci. China Mater. 58, 114–125 (2015)
T. Xu, X. Wu, Y. Li, W. Xu, Z. Lu, Y. Li, X. Lei, X. Sun, Morphology and phase evolution of CoAl layered double hydroxides in an alkaline environment with enhanced pseudocapacitive performance. ChemElectroChem. 2, 679–683 (2015)
X. Wu, Z. Zhao, B. Huang, 0CoP-Doped nickel aluminum double hydroxide as superior electrode for boosting pseudocapacitive storage. Electrochim. Acta 361, 137092 (2020)
J. Cha, E.B. Park, S.W. Han, Y.D. Kim, D. Jung, Core‐shell structured cobalt sulfide/cobalt aluminum hydroxide nanosheet arrays for pseudocapacitor application. Chem.—Asian J. 14 (2019) 446–453.
X. Hao, Y. Zhang, Z. Diao, H. Chen, A. Zhang, Z. Wang, Engineering one-dimensional and two-dimensional birnessite manganese dioxides on nickel foam-supported cobalt–aluminum layered double hydroxides for advanced binder-free supercapacitors. RSC Adv. 4, 63901–63908 (2014)
B. Wang, G.R. Williams, Z. Chang, M. Jiang, J. Liu, X. Lei, X. Sun, Hierarchical NiAl layered double hydroxide/multiwalled carbon nanotube/nickel foam electrodes with excellent pseudocapacitive properties. ACS Appl. Mater. Interfaces. 6, 16304–16311 (2014)
Y. Gu, Z. Lu, Z. Chang, J. Liu, X. Lei, Y. Li, X. Sun, NiTi layered double hydroxide thin films for advanced pseudocapacitor electrodes. J. Mater. Chem. A 1, 10655–10661 (2013)
G. Li, X. Zhang, D. Qiu, Z. Liu, C. Yang, C.B. Cockreham, B. Wang, L. Fu, J. Zhang, B. Sudduth, Tuning Ni/Al ratio to enhance pseudocapacitive charge storage properties of nickel–aluminum layered double hydroxide. Adv. Electron. Mater. 5, 1900215 (2019)
I. Lee, G.H. Jeong, S. An, S.-W. Kim, S. Yoon, Facile synthesis of 3D MnNi-layered double hydroxides (LDH)/graphene composites from directly graphites for pseudocapacitor and their electrochemical analysis. Appl. Surf. Sci. 429, 196–202 (2018)
X. Ge, C.D. Gu, X.L. Wang, J.P. Tu, Ionothermal synthesis of cobalt iron layered double hydroxides (LDHs) with expanded interlayer spacing as advanced electrochemical materials. J. Mater. Chem. A 2, 17066–17076 (2014)
P. Huang, C. Cao, Y. Sun, S. Yang, F. Wei, W. Song, One-pot synthesis of sandwich-like reduced graphene oxide@ CoNiAl layered double hydroxide with excellent pseudocapacitive properties. J. Mater. Chem. A 3, 10858–10863 (2015)
J. Zou, J. Zou, W. Zhong, Q. Liu, X. Huang, Y. Gao, L. Lu, S. Liu, PEDOT coating boosted NiCo-LDH nanocage on CC enable high-rate and durable pseudocapacitance reaction. J. Electroanal. Chem. 928, 117069 (2023)
D.S. Patil, S.A. Pawar, J.C. Shin, H.J. Kim, Layered double hydroxide based on ZnCo@ NiCo-nano-architecture on 3D graphene scaffold as an efficient pseudocapacitor. J. Power Sourc. 435, 226812 (2019)
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Mohammadian Sarcheshmeh, H., Mazloum Ardakani, M. (2024). Electrochemical Properties of Metal Hydroxides. In: Gupta, R.K. (eds) Pseudocapacitors. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-031-45430-1_7
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DOI: https://doi.org/10.1007/978-3-031-45430-1_7
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