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Pseudocapacitive Materials for Metal-Sulfur Batteries

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Pseudocapacitors

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Abstract

Alkali metal-sulfur batteries have developed profound interest among researchers due to their high theoretical energy density (>2500 Wh kg−1). However, their commercial exploitation potential is hindered due to the lower electronic conductivity of sulfur and other discharging products, deteriorating polysulfide shuttling, and substantial volume variations during discharging. Pseudocapacitive materials can address these issues. Their superior intrinsic properties, such as higher electronic conductivity, better ionic conduction, and abundant functional groups that, trap polysulfides and make them suitable candidates for batteries. Pseudocapacitive materials such as layered transition metal oxides (TMOs), phosphides (TMPs), chalcogenides (TMCs), MXenes, etc. have the metal center acting as Lewis’s entity to attract polysulfide anions. In contrast, the anionic species, such as oxides/phosphides and chalcogens, react with metal ions (Li, Na, and K) to provide the synergetic effect. This chapter discusses the benefits of using these materials for metal-sulfur batteries and associated challenges in a detailed manner.

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Authors and Affiliations

  1. Department of Physics, Malaviya National Institute of Technology Jaipur, Jaipur, Rajasthan, 302017, India

    Yogita Dahiya, Manoj Kumar & Debasish Sarkar

  2. Department of Physics, JECRC University, Jaipur, India

    Shivani Agarwal

  3. Centre for Renewable Energy and Storage, Suresh Gyan Vihar University, Jaipur, Rajasthan, 302017, India

    Ankur Jain

  4. Natural Science Centre for Basic Research and Development, Hiroshima University, Higashi-Hiroshima, Japan

    Ankur Jain

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  1. Yogita Dahiya
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  4. Debasish Sarkar
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  5. Ankur Jain
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Correspondence to Ankur Jain .

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  1. Polymer Chemistry, Department of Chemistry, National Institute for Materials Advancement, Pittsburg State University, Pittsburg, KS, USA

    Ram K. Gupta

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Dahiya, Y., Agarwal, S., Kumar, M., Sarkar, D., Jain, A. (2024). Pseudocapacitive Materials for Metal-Sulfur Batteries. In: Gupta, R.K. (eds) Pseudocapacitors. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-031-45430-1_18

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