Abstract
In photovoltaic generations of a solar cell, thin-film dye-sensitized solar cells have a significant role in clean energy production due to low-cost, easy fabrication process, and maximum efficiencies even in low-intensity radiations from the sun in a cloudy environment. The charge transportation mechanism, electron diffusion and movement, charge collection efficiency, charge recombination reactions, and the electron path length influence the DSSC performance. All these factors are linked with the photoanode material. Porosity, surface area, composition, and architecture are the key parameters which should be considered for the material selection of DSSC photoanode. This chapter comprises three parts. In the first section, a brief introduction to photovoltaic technologies, working mechanism of DSSC, and structure of DSSC will be discussed in detail. The role of metal oxide semiconductor materials in DSSCs and their types will be discussed in second part. Finally, the morphology, modification of semiconductor materials, and their effect on the photovoltaic properties of light-harvesting devices will be discussed in detail in the last part.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Etxebarria, I., Ajuria, J. & Pacios, R. Polymer:fullerene solar cells: materials, processing issues, and cell layouts to reach power conversion efficiency over 10%, a review. J. Photonics Energy5, 057214 (2015).
Hagfeldt, A., Boschloo, G., Sun, L., Kloo, L. & Pettersson, H. Dye-Sensitized Solar Cells. Chem. Rev.110, 6595–6663 (2010).
O’Regan, B. & Grätzel, M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature353, 737–740 (1991).
Iwata, S., Shibakawa, S. ichiro, Imawaka, N. & Yoshino, K. Stability of the current characteristics of dye-sensitized solar cells in the second quadrant of the current–voltage characteristics. Energy Reports4, 8–12 (2018).
Akman, E. Enhanced photovoltaic performance and stability of dye-sensitized solar cells by utilizing manganese-doped ZnO photoanode with europium compact layer. J. Mol. Liq.317, 114223 (2020).
Ou, J. Z. et al. Erratum: Elevated temperature anodized Nb 2O 5-A photoanode material with exceptionally large photoconversion efficiencies (ACS Nano (2012) 6 (4045–4053) DOI: https://doi.org/10.1021/nn300408p). ACS Nano6, 5737 (2012).
Nazeeruddin, M. K., Liska, P., Moser, J., Vlachopoulos, N. & Grätzel, M. Conversion of Light into Electricity with Trinuclear Ruthenium Complexes Adsorbed on Textured TiO2 Films. Helv. Chim. Acta73, 1788–1803 (1990).
Shin, Y.-J., Lee, J.-H., Park, J.-H. & Park, N.-G. Enhanced Photovoltaic Properties of SiO 2 -treated ZnO Nanocrystalline Electrode for Dye-sensitized Solar Cell. Chem. Lett.36, 1506–1507 (2007).
Horiuchi, H. et al. Electron injection efficiency from excited N3 into nanocrystalline ZnO films: Effect of (N3-Zn2+) aggregate formation. J. Phys. Chem. B107, 2570–2574 (2003).
Keis, K., Lindgren, J., Lindquist, S. E. & Hagfeldt, A. Studies of the adsorption process of Ru complexes in nanoporous ZnO electrodes. Langmuir16, 4688–4694 (2000).
Parks, G. A. The Isoelectric Points of Solid Oxides, Solid Hydroxides, and Aqueous Hydroxo Complex Systems. Chem. Rev.65, 177–198 (1965).
Shin, Y. J., Lee, J. H., Park, J. H. & Park, N. G. Enhanced photovoltaic properties of SiO2-treated ZnO nanocrystalline electrode for dye-sensitized solar cell. Chem. Lett.36, 1506–1507 (2007).
Law, M. et al. ZnO-Al2O3 and ZnO-TiO2 core-shell nanowire dye-sensitized solar cells. J. Phys. Chem. B110, 22652–22663 (2006).
Greene, L. E., Law, M., Yuhas, B. D. & Yang, P. ZnO - TiO2 Core - Shell nanorod/P3HT solar cells. J. Phys. Chem. C111, 18451–18456 (2007).
Memarian, N. et al. Hierarchically assembled ZnO nanocrystallites for high-efficiency dye-sensitized solar cells. Angew. Chemie - Int. Ed.50, 12321–12325 (2011).
Akhtar, M. S. A Facile Synthesis of ZnO Nanoparticles and Its Application as Photoanode for Dye Sensitized Solar Cells. Sci. Adv. Mater.7, 1137–1142 (2015).
Akhtar, M. S., Khan, M. A., Jeon, M. S. & Yang, O. B. Controlled synthesis of various ZnO nanostructured materials by capping agents-assisted hydrothermal method for dye-sensitized solar cells. Electrochim. Acta53, 7869–7874 (2008).
Ameen, S., Akhtar, M. S., Seo, H. K., Kim, Y. S. & Shin, H. S. Influence of Sn doping on ZnO nanostructures from nanoparticles to spindle shape and their photoelectrochemical properties for dye sensitized solar cells. Chem. Eng. J.187, 351–356 (2012).
Jiang, C. Y., Sun, X. W., Lo, G. Q., Kwong, D. L. & Wang, J. X. Improved dye-sensitized solar cells with a ZnO-nanoflower photoanode. Appl. Phys. Lett.90, 3–6 (2007).
Mou, J., Zhang, W., Fan, J., Deng, H. & Chen, W. Facile synthesis of ZnO nanobullets/nanoflakes and their applications to dye-sensitized solar cells. J. Alloys Compd.509, 961–965 (2011).
Lee, C. P. et al. Synthesis of hexagonal ZnO clubs with opposite faces of unequal dimensions for the photoanode of dye-sensitized solar cells. Phys. Chem. Chem. Phys.13, 20999–21008 (2011).
Wang, Y., Cui, X., Zhang, Y., Gao, X. & Sun, Y. Preparation of Cauliflower-like ZnO Films by Chemical Bath Deposition: Photovoltaic Performance and Equivalent Circuit of Dye-sensitized Solar Cells. J. Mater. Sci. Technol.29, 123–127 (2013).
Li, Z. et al. Fabrication of hierarchically assembled microspheres consisting of nanoporous ZnO nanosheets for high-efficiency dye-sensitized solar cells. J. Mater. Chem.22, 14341–14345 (2012).
McCune, M., Zhang, W. & Deng, Y. High efficiency dye-sensitized solar cells based on three-dimensional multilayered ZnO nanowire arrays with ‘caterpillar-like’ structure. Nano Lett.12, 3656–3662 (2012).
Ameen, S., Shaheer Akhtar, M. & Shin, H. S. Growth and characterization of nanospikes decorated ZnO sheets and their solar cell application. Chem. Eng. J.195–196, 307–313 (2012).
Wang, J. X. et al. Synthesis of hierarchical porous ZNO disklike nanostructures for improved photovoltaic properties of Dye-Sensitized solar cells. J. Phys. Chem. C114, 13157–13161 (2010).
Kalyanasundaram, K. & Grätzel, M. Applications of functionalized transition metal complexes in photonic and optoelectronic devices. Coord. Chem. Rev.177, 347–414 (1998).
O’Regan, B., Grätzel, M. A. Low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature354, 56–58 (1991).
Barbé, C. J. et al. Nanocrystalline Titanium Oxide Electrodes for Photovoltaic Applications. J. Am. Ceram. Soc.80, 3157–3171 (2005).
Fillinger, A. The Adsorption Behavior of a Ruthenium-Based Sensitizing Dye to Nanocrystalline TiO[sub 2] Coverage Effects on the External and Internal Sensitization Quantum Yields. J. Electrochem. Soc.146, 4559 (1999).
Chai, S., Lau, T., Dayou, J., Sipaut, S. & Mansa, R. F. Development in Photoanode Materials for High Efficiency Dye Sensitized Solar Cells. vol. 4 (2014).
Valencia, S., Marín, J. M. & Restrepo, G. Study of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal Treatment. Open Mater. Sci. J.4, 9–14 (2010).
Chou, T. P., Zhang, Q., Russo, B., Fryxell, G. E. & Cao, G. Titania particle size effect on the overall performance of dye-sensitized solar cells. J. Phys. Chem. C111, 6296–6302 (2007).
Bagheri, S., Mohd Hir, Z. A., Yousefi, A. T. & Abdul Hamid, S. B. Progress on mesoporous titanium dioxide: Synthesis, modification and applications. Microporous Mesoporous Mater.218, 206–222 (2015).
Muniz, E. C. et al. Synthesis and characterization of mesoporous TiO2 nanostructured films prepared by a modified sol-gel method for application in dye solar cells. Ceram. Int.37, 1017–1024 (2011).
Alwin, S., Shajan, X. S., Karuppasamy, K. & Warrier, K. G. K. Microwave assisted synthesis of high surface area TiO2 aerogels: A competent photoanode material for quasi-solid dye-sensitized solar cells. Mater. Chem. Phys.196, 37–44 (2017).
Hochbaum, A. I. & Yang, P. Semiconductor nanowires for energy conversion. Chem. Rev.110, 527–546 (2010).
Chen, Y. et al. Effect of mesoporous TiO2 bead diameter in working electrodes on the efficiency of dye-sensitized solar cells. ChemSusChem4, 1498–1503 (2011).
Kao, M. C., Chen, H. Z., Young, S. L., Kung, C. Y. & Lin, C. C. The effects of the thickness of TiO2 films on the performance of dye-sensitized solar cells. Thin Solid Films517, 5096–5099 (2009).
Dissanayake, L. & Thotawatthage, C. A. The effect of TiO2 photo anode film thickness on photovoltaic properties of dye-sensitized solar cells The effect of TiO 2 photoanode film thickness on photovoltaic properties of dye-sensitized solar cells. (2016) doi:https://doi.org/10.4038/cjs.v45i1.7362.
Park, Y. C. et al. Size-tunable mesoporous spherical TiO2 as a scattering overlayer in high-performance dye-sensitized solar cells. J. Mater. Chem.21, 9582–9586 (2011).
Sun, X. et al. Mixed P25 nanoparticles and large rutile particles as a top scattering layer to enhance performance of nanocrystalline TiO 2 based dye-sensitized solar cells. Appl. Surf. Sci.337, 188–194 (2015).
Miao, Q., Wu, L., Cui, J., Huang, M. & Ma, T. A New Type of Dye-Sensitized Solar Cell with a Multilayered Photoanode Prepared by a Film-Transfer Technique. Adv. Mater.23, 2764–2768 (2011).
Koo, H. J. et al. Nano-embossed hollow spherical TiO2 as bifunctional material for high-efficiency dye-sensitized solar cells. Adv. Mater.20, 195–199 (2008).
Huang, F., Chen, D., Zhang, X. L., Caruso, R. A. & Cheng, Y. B. Dual-function scattering layer of submicrometer-sized mesoporous TiO 2 beads for high-efficiency dyesensitized solar cells. Adv. Funct. Mater.20, 1301–1305 (2010).
Wu, W. Q., Xu, Y. F., Rao, H. S., Su, C. Y. & Kuang, D. Bin. A double layered TiO2 photoanode consisting of hierarchical flowers and nanoparticles for high-efficiency dye-sensitized solar cells. Nanoscale5, 4362–4369 (2013).
Dong, Z. et al. Quintuple-shelled Sno2 hollow microspheres with superior light scattering for high-performance dye-sensitized solar cells. Adv. Mater.26, 905–909 (2014).
Yan, K., Qiu, Y., Chen, W., Zhang, M. & Yang, S. A double layered photoanode made of highly crystalline TiO2 nanooctahedra and agglutinated mesoporous TiO2 microspheres for high efficiency dye sensitized solar cells. Energy Environ. Sci.4, 2168–2176 (2011).
Gao, Z. et al. Application of hierarchical TiO2 spheres as scattering layer for enhanced photovoltaic performance in dye sensitized solar cell. CrystEngComm15, 3351–3358 (2013).
Wu, W. Q., Xu, Y. F., Rao, H. S., Su, C. Y. & Kuang, D. Bin. Multistack integration of three-dimensional hyperbranched anatase titania architectures for high-efficiency dye-sensitized solar cells. J. Am. Chem. Soc.136, 6437–6445 (2014).
Yang, L. & Leung, W. W. F. Application of a bilayer TiO2 nanofiber photoanode for optimization of dye-sensitized solar cells. Adv. Mater.23, 4559–4562 (2011).
Wang, G., Zhu, X. & Yu, J. Bilayer hollow/spindle-like anatase TiO2 photoanode for high efficiency dye-sensitized solar cells. J. Power Sources278, 344–351 (2015).
Asahi, R., Morikawa, T., Ohwaki, T., Aoki, K. & Taga, Y. Visible-light photocatalysis in nitrogen-doped titanium oxides. Science (80-. ).293, 269–271 (2001).
Mrowetz, M., Balcerski, W., Colussi, A. J. & Hoffmann, M. R. Oxidative power of nitrogen-doped TiO 2 photocatalysts under visible illumination. J. Phys. Chem. B108, 17269–17273 (2004).
Hoye, R. L. Z., Musselman, K. P. & Macmanus-Driscoll, J. L. Research update: Doping ZnO and TiO2 for solar cells. APL Mater.1, (2013).
Duan, Y. et al. Sn-doped TiO 2 photoanode for dye-sensitized solar cells. J. Phys. Chem. C116, 8888–8893 (2012).
Ko, K. H., Lee, Y. C. & Jung, Y. J. Enhanced efficiency of dye-sensitized TiO2 solar cells (DSSC) by doping of metal ions. J. Colloid Interface Sci.283, 482–487 (2005).
Zhang, J. C. et al. N, S-doped TiO2 anode effect on performance of dye-sensitized solar cells. J. Phys. Chem. Solids72, 1239–1244 (2011).
Berglund, S. P., Hoang, S., Minter, R. L., Fullon, R. R. & Mullins, C. B. Investigation of 35 elements as single metal oxides, mixed metal oxides, or dopants for titanium dioxide for dye-sensitized solar cells. J. Phys. Chem. C117, 25248–25258 (2013).
Ma, T., Akiyama, M., Abe, E. & Imai, I. High-efficiency dye-sensitized solar cell based on a nitrogen-doped nanostructured titania electrode. Nano Lett.5, 2543–2547 (2005).
Tian, H. et al. Retarded charge recombination in dye-sensitized nitrogen-doped tio 2 solar cells. J. Phys. Chem. C114, 1627–1632 (2010).
Fu, H., Zhang, L., Zhang, S., Zhu, Y. & Zhao, J. Electron spin resonance spin-trapping detection of radical intermediates in N-doped TiO2-assisted photodegradation of 4-chlorophenol. J. Phys. Chem. B110, 3061–3065 (2006).
Etacheri, V., Seery, M. K., Hinder, S. J. & Pillai, S. C. Highly visible light active TiO2-xNx heterojunction photocatalysts. Chem. Mater.22, 3843–3853 (2010).
Guo, W., Shen, Y., Boschloo, G., Hagfeldt, A. & Ma, T. Influence of nitrogen dopants on N-doped TiO2 electrodes and their applications in dye-sensitized solar cells. Electrochim. Acta56, 4611–4617 (2011).
Nah, Y.-C., Paramasivam, I. & Schmuki, P. Doped TiO2 and TiO2 Nanotubes: Synthesis and Applications. ChemPhysChem11, 2698–2713 (2010).
Yang, M. et al. Nb doping of TiO2 nanotubes for an enhanced efficiency of dye-sensitized solar cells. Chem. Commun.47, 2032–2034 (2011).
Low, F. W. & Lai, C. W. Recent developments of graphene-TiO2 composite nanomaterials as efficient photoelectrodes in dye-sensitized solar cells: A review. Renew. Sustain. Energy Rev.82, 103–125 (2018).
Batmunkh, M., Biggs, M. J. & Shapter, J. G. Carbonaceous Dye-Sensitized Solar Cell Photoelectrodes. Adv. Sci.2, 1400025 (2015).
Ting, C. C. & Chao, W. S. Efficiency improvement of the DSSCs by building the carbon black as bridge in photoelectrode. Appl. Energy87, 2500–2505 (2010).
Kang, S. H., Kim, J. Y., Kim, Y. K. & Sung, Y. E. Effects of the incorporation of carbon powder into nanostructured TiO2 film for dye-sensitized solar cell. J. Photochem. Photobiol. A Chem.186, 234–241 (2007).
Kim, D. Y. et al.The photovoltaic efficiencies on dye sensitized solar cells assembled with nanoporous carbon/tio 2 composites. J. Ind. Eng. Chem.18, 1–5 (2012).
Yang, G. et al. Light scattering enhanced photoanodes for dye-sensitized solar cells prepared by carbon spheres/TiO2 nanoparticle composites. Curr. Appl. Phys.11, 376–381 (2011).
Jang, Y. J., Jang, Y. H. & Kim, D. H. Carbohydrate-Derived Carbon Sheaths on TiO 2 Nanoparticle Photoanodes for Efficiency Enhancement in Dye-Sensitized Solar Cells. Part. Part. Syst. Charact.30, 1030–1033 (2013).
Nissfolk, J., Fredin, K., Hagfeldt, A. & Boschloo, G. Recombination and transport processes in dye-sensitized solar cells investigated under working conditions. J. Phys. Chem. B110, 17715–17718 (2006).
Cai, J. et al. Enhanced conversion efficiency of dye-sensitized solar cells using a CNT-incorporated TiO2 slurry-based photoanode. AIP Adv.5, 027118 (2015).
Liu, Y., Zhang, J., Cheng, Y. & Jiang, S. P. Effect of Carbon Nanotubes on Direct Electron Transfer and Electrocatalytic Activity of Immobilized Glucose Oxidase. ACS Omega3, 667–676 (2018).
Peng, H., Sun, X., Weng, W. & Fang, X. Electronic Polymer Composite. in Polymer Materials for Energy and Electronic Applications 107–149 (Elsevier, 2017). doi:https://doi.org/10.1016/b978-0-12-811091-1.00004-5.
Benetti, D. et al. Functionalized multi-wall carbon nanotubes/TiO2 composites as efficient photoanodes for dye sensitized solar cells. J. Mater. Chem. C4, 3555–3562 (2016).
Anusorn Kongkanand, Rebeca Martínez Domínguez, and & Kamat*, P. V. Single Wall Carbon Nanotube Scaffolds for Photoelectrochemical Solar Cells. Capture and Transport of Photogenerated Electrons. (2007) doi:https://doi.org/10.1021/NL0627238.
Kim, S. G. et al. Nb-doped TiO2 nanoparticles for organic dye-sensitized solar cells. RSC Adv.3, 16380 (2013).
Archana, P. S., Gupta, A., Yusoff, M. M. & Jose, R. Tungsten doped titanium dioxide nanowires for high efficiency dye-sensitized solar cells. Phys. Chem. Chem. Phys.16, 7448–7454 (2014).
Wu, J. et al. Enhancement of the Photovoltaic Performance of Dye-Sensitized Solar Cells by Doping Y0.78Yb0.20Er0.02F3 in the Photoanode. Adv. Energy Mater.2, 78–81 (2012).
Zhang, J., Peng, W., Chen, Z., Chen, H. & Han, L. Effect of cerium doping in the TiO 2 photoanode on the electron transport of dye-sensitized solar cells. J. Phys. Chem. C116, 19182–19190 (2012).
Kim, C., Kim, K. S., Kim, H. Y. & Han, Y. S. Modification of a TiO2 photoanode by using Cr-doped TiO 2 with an influence on the photovoltaic efficiency of a dye-sensitized solar cell. J. Mater. Chem.18, 5809–5814 (2008).
Xie, Y. et al. Improved performance of dye-sensitized solar cells by trace amount Cr-doped TiO2 photoelectrodes. J. Power Sources224, 168–173 (2013).
Yang, S. et al. Improved efficiency of dye-sensitized solar cells applied with F-doped TiO2 electrodes. J. Fluor. Chem.150, 78–84 (2013).
Mahmoud, M. S. et al. Demonstrated photons to electron activity of S-doped TiO2 nanofibers as photoanode in the DSSC. Mater. Lett.225, 77–81 (2018).
Sun, Q. et al. Sulfur-doped TiO 2 nanocrystalline photoanodes for dye-sensitized solar cells. in Journal of Renewable and Sustainable Energy vol. 4 023104 (American Institute of PhysicsAIP, 2012).
Wang, M. et al. Improved photovoltaic performance of dye-sensitized solar cells by Sb-doped TiO 2 photoanode. Electrochim. Acta77, 54–59 (2012).
Sakthivel, T., Kumar, K. A., Senthilselvan, J. & Jagannathan, K. Effect of Ni dopant in TiO2 matrix on its interfacial charge transportation and efficiency of DSSCs. J. Mater. Sci. Mater. Electron.29, 2228–2235 (2018).
Zhu, G., Wang, H., Zhang, Q. & Zhang, L. Enhanced photovoltaic performance of dye-sensitized solar cells based on NaYF4:Yb3+, Er3+-incorporated nanocrystalline TiO2 electrodes. J. Colloid Interface Sci.451, 15–20 (2015).
Qin, Y. et al. Performance improvement of dye-sensitized solar cell by introducing Sm3 +/Y3 + co-doped TiO2 film as an efficient blocking layer. Thin Solid Films631, 141–146 (2017).
Guai, G. H., Li, Y., Ng, C. M., Li, C. M. & Chan-Park, M. B. TiO2 Composing with Pristine, Metallic or Semiconducting Single-Walled Carbon Nanotubes: Which Gives the Best Performance for a Dye-Sensitized Solar Cell. ChemPhysChem13, 2566–2572 (2012).
Munkhbayar, B. et al. Influence of dry and wet ball milling on dispersion characteristics of the multi-walled carbon nanotubes in aqueous solution with and without surfactant. Powder Technol.234, 132–140 (2013).
Dang, X. et al. Virus-templated self-assembled single-walled carbon nanotubes for highly efficient electron collection in photovoltaic devices. Nat. Nanotechnol.6, 377–384 (2011).
Balandin, A. A. et al. Superior Thermal Conductivity of Single-Layer Graphene. Nano Lett.8, 902–907 (2008).
Geim, A. K. & Novoselov, K. S. The rise of graphene. Nat. Mater.6, 183–191 (2007).
Sun, Y., Wu, Q. & Shi, G. Graphene based new energy materials. Energy Environ. Sci.4, 1113 (2011).
Geim, A. K. Graphene: status and prospects. Science324, 1530–4 (2009).
Bonaccorso, F., Sun, Z., Hasan, T. & Ferrari, A. C. Graphene photonics and optoelectronics. Nat. Photonics4, 611–622 (2010).
Sacco, A. et al. Investigation of transport and recombination properties in graphene/titanium dioxide nanocomposite for dye-sensitized solar cell photoanodes. Electrochim. Acta131, 154–159 (2014).
Song, J. et al. Enhancement of Photogenerated Electron Transport in Dye-Sensitized Solar Cells with Introduction of a Reduced Graphene Oxide-TiO2 Junction. Chem. - A Eur. J.17, 10832–10837 (2011).
Tang, Y. B. et al. Incorporation of graphenes in nanostructured TiO2 films via molecular grafting for dye-sensitized solar cell application. ACS Nano4, 3482–3488 (2010).
Batmunkh, M., Dadkhah, M., Shearer, C. J., Biggs, M. J. & Shapter, J. G. Incorporation of graphene into SnO 2 photoanodes for dye-sensitized solar cells. Appl. Surf. Sci.387, 690–697 (2016).
Fan, J., Liu, S. & Yu, J. Enhanced photovoltaic performance of dye-sensitized solar cells based on TiO 2 nanosheets/graphene composite films. J. Mater. Chem.22, 17027–17036 (2012).
Yang, N., Zhai, J., Wang, D., Chen, Y. & Jiang, L. Two-Dimensional Graphene Bridges Enhanced Photoinduced Charge Transport in Dye-Sensitized Solar Cells. ACS Nano4, 887–894 (2010).
Chen, T., Hu, W., Song, J., Guai, G. H. & Li, C. M. Interface Functionalization of Photoelectrodes with Graphene for High Performance Dye-Sensitized Solar Cells. Adv. Funct. Mater.22, 5245–5250 (2012).
Guo, W. et al. Rectangular bunched rutile TiO 2 nanorod arrays grown on carbon fiber for dye-sensitized solar cells. J. Am. Chem. Soc.134, 4437–4441 (2012).
Macdonald, T. J. et al. A TiO 2 Nanofiber-Carbon Nanotube-Composite Photoanode for Improved Efficiency in Dye-Sensitized Solar Cells. ChemSusChem8, 3396–3400 (2015).
Yen, M. Y. et al. Preparation of graphene/multi-walled carbon nanotube hybrid and its use as photoanodes of dye-sensitized solar cells. Carbon N. Y.49, 3597–3606 (2011).
Kilic, B. et al. Preparation of Carbon Nanotube/TiO2 Mesoporous Hybrid Photoanode with Iron Pyrite (FeS2) Thin Films Counter Electrodes for Dye-Sensitized Solar Cell. Sci. Rep.6, 27052 (2016).
Golobostanfard, M. R. & Abdizadeh, H. Influence of carbon nanotube wall thickness on performance of dye sensitized solar cell with hierarchical porous photoanode. Microporous Mesoporous Mater.191, 74–81 (2014).
Yang, L. & Leung, W. W. F. Electrospun TiO2 nanorods with carbon nanotubes for efficient electron collection in dye-sensitized solar cells. Adv. Mater.25, 1792–1795 (2013).
Massihi, N., Mohammadi, M. R., Bakhshayesh, A. M. & Abdi-Jalebi, M. Controlling electron injection and electron transport of dye-sensitized solar cells aided by incorporating CNTs into a Cr-doped TiO2 photoanode. Electrochim. Acta111, 921–929 (2013).
Golobostanfard, M. R. & Abdizadeh, H. Hierarchical porous titania/carbon nanotube nanocomposite photoanode synthesized by controlled phase separation for dye sensitized solar cell. Sol. Energy Mater. Sol. Cells120, 295–302 (2014).
Anjidani, M., Milani Moghaddam, H. & Ojani, R. Binder-free MWCNT/TiO2 multilayer nanocomposite as an efficient thin interfacial layer for photoanode of dye sensitized solar cell. Mater. Sci. Semicond. Process.71, 20–28 (2017).
Chan, Y. F., Wang, C. C., Chen, B. H. & Chen, C. Y. Dye-sensitized TiO2 solar cells based on nanocomposite photoanode containing plasma-modified multi-walled carbon nanotubes. Prog. Photovoltaics Res. Appl.21, 47–57 (2013).
Tang, B. & Hu, G. Two kinds of graphene-based composites for photoanode applying in dye-sensitized solar cell. J. Power Sources220, 95–102 (2012).
Zhang, H. et al. Effects of TiO2 film thickness on photovoltaic properties of dye-sensitized solar cell and its enhanced performance by graphene combination. Mater. Res. Bull.49, 126–131 (2014).
Tsai, C. H., Fei, P. H. & Wu, W. C. Enhancing the efficiency and charge transport characteristics of dye-sensitized solar cells by adding graphene nanosheets to TiO2 working electrodes. Electrochim. Acta165, 356–364 (2015).
Wang, P., He, F., Wang, J., Yu, H. & Zhao, L. Graphene oxide nanosheets as an effective template for the synthesis of porous TiO 2 film in dye-sensitized solar cells. in Applied Surface Science vol. 358 175–180 (Elsevier B.V., 2015).
Zhu, M., Li, X., Liu, W. & Cui, Y. An investigation on the photoelectrochemical properties of dye-sensitized solar cells based on graphene-TiO2 composite photoanodes. J. Power Sources262, 349–355 (2014).
He, Z. et al. Nanostructure control of graphene-composited TiO 2 by a one-step solvothermal approach for high performance dye-sensitized solar cells. Nanoscale3, 4613–4616 (2011).
Chen, L. et al. Enhanced photovoltaic performance of a dye-sensitized solar cell using graphene-TiO2 photoanode prepared by a novel in situ simultaneous reduction-hydrolysis technique. Nanoscale5, 3481–3485 (2013).
Choi, H., Chen, W. T. & Kamat, P. V. Know thy nano neighbor. Plasmonic versus electron charging effects of metal nanoparticles in dye-sensitized solar cells. ACS Nano6, 4418–4427 (2012).
Qi, J., Dang, X., Hammond, P. T. & Belcher, A. M. Highly efficient plasmon-enhanced dye-sensitized solar cells through metal@oxide core-shell nanostructure. ACS Nano5, 7108–7116 (2011).
Jeong, N. C., Prasittichai, C. & Hupp, J. T. Photocurrent enhancement by surface plasmon resonance of silver nanoparticles in highly porous dye-sensitized solar cells. Langmuir27, 14609–14614 (2011).
Xu, J. et al. G-C3N4 modified TiO2 nanosheets with enhanced photoelectric conversion efficiency in dye-sensitized solar cells. J. Power Sources274, 77–84 (2015).
Bella, F., Griffini, G., Gerosa, M., Turri, S. & Bongiovanni, R. Performance and stability improvements for dye-sensitized solar cells in the presence of luminescent coatings. J. Power Sources283, 195–203 (2015).
Griffini, G. et al. Multifunctional Luminescent Down-Shifting Fluoropolymer Coatings: A Straightforward Strategy to Improve the UV-Light Harvesting Ability and Long-Term Outdoor Stability of Organic Dye-Sensitized Solar Cells. Adv. Energy Mater.5, 1401312 (2015).
Yuan, S., Tang, Q., He, B., Men, L. & Chen, H. Transmission enhanced photoanodes for efficient dye-sensitized solar cells. Electrochim. Acta125, 646–651 (2014).
Gondal, M. A., Ilyas, A. M. & Baig, U. Facile synthesis of silicon carbide-titanium dioxide semiconducting nanocomposite using pulsed laser ablation technique and its performance in photovoltaic dye sensitized solar cell and photocatalytic water purification. Appl. Surf. Sci.378, 8–14 (2016).
Kim, J. T., Lee, S. H. & Han, Y. S. Enhanced power conversion efficiency of dye-sensitized solar cells with Li 2 SiO 3 -modified photoelectrode. Appl. Surf. Sci.333, 134–140 (2015).
Sabet, M., Salavati-Niasari, M. & Amiri, O. Using different chemical methods for deposition of CdS on TiO2 surface and investigation of their influences on the dye-sensitized solar cell performance. Electrochim. Acta117, 504–520 (2014).
Wang, Z. et al. Titanium dioxide/calcium fluoride nanocrystallite for efficient dye-sensitized solar cell. A strategy of enhancing light harvest. J. Power Sources275, 175–180 (2015).
Kane, S. N., Mishra, A. & Dutta, A. K. Electrospinning Titanium Dioxide (TiO2) nanofiber for dye sensitized solar cells based on Bryophyta as a sensitizer. J. Phys. Conf. Ser.755, 3–10 (2016).
Yang, X., Zhao, L., Lv, K., Dong, B. & Wang, S. Enhanced efficiency for dye-sensitized solar cells with ZrO 2 as a barrier layer on TiO 2 nanofibers. Appl. Surf. Sci.469, 821–828 (2019).
Cao, Y., Dong, Y. J., Feng, H. L., Chen, H. Y. & Kuang, D. Bin. Electrospun TiO2 nanofiber based hierarchical photoanode for efficient dye-sensitized solar cells. Electrochim. Acta189, 259–264 (2016).
Joshi, P. et al. Composite of TiO2 nanofibers and nanoparticles for dye-sensitized solar cells with significantly improved efficiency. Energy Environ. Sci.3, 1507–1510 (2010).
Chuangchote, S., Sagawa, T. & Yoshikawa, S. Efficient dye-sensitized solar cells using electrospun Ti O2 nanofibers as a light harvesting layer. Appl. Phys. Lett.93, 2012–2015 (2008).
Jung, W. H., Kwak, N. S., Hwang, T. S. & Yi, K. B. Preparation of highly porous TiO 2 nanofibers for dye-sensitized solar cells (DSSCs) by electro-spinning. Appl. Surf. Sci.261, 343–352 (2012).
Lin, Y. P., Chen, Y. Y., Lee, Y. C. & Chen-Yang, Y. W. Effect of wormhole-like mesoporous anatase TiO 2 nanofiber prepared by electrospinning with ionic liquid on dye-sensitized solar cells. J. Phys. Chem. C116, 13003–13012 (2012).
Mesoporous titania–vertical nanorod films with interfacial engineering for high performance dye-sensitized solar cells - IOPscience.
Zukalová, M. et al. Nanofibrous TiO2 improving performance of mesoporous TiO 2 electrode in dye-sensitized solar cell. J. Nanoparticle Res.15, 1–8 (2013).
Wang, J. et al. Improved morphology and photovoltaic performance in TiO2 nanorod arrays based dye sensitized solar cells by using a seed layer. J. Alloys Compd.551, 82–87 (2013).
Huang, Q., Zhou, G., Fang, L., Hu, L. & Wang, Z. S. TiO2 nanorod arrays grown from a mixed acid medium for efficient dye-sensitized solar cells. Energy Environ. Sci.4, 2145–2151 (2011).
Zhang, Z., Hu, Y., Qin, F. & Ding, Y. DC sputtering assisted nano-branched core-shell TiO 2 /ZnO electrodes for application in dye-sensitized solar cells. Appl. Surf. Sci.376, 10–15 (2016).
Sriharan, N., Ganesan, N. M., Kang, M., Kungumadevi, L. & Senthil, T. S. Improved photoelectrical performance of single crystalline rutile TiO2 nanorod arrays incorporating α-alumina for high efficiency dye-sensitized solar cells. Mater. Lett.237, 204–208 (2019).
Lv, M. et al. Optimized porous rutile TiO2 nanorod arrays for enhancing the efficiency of dye-sensitized solar cells. Energy Environ. Sci.6, 1615–1622 (2013).
Zha, C. et al. Double-sided brush-shaped TiO2 nanostructure assemblies with highly ordered nanowires for dye-sensitized solar cells. ACS Appl. Mater. Interfaces6, 122–129 (2014).
Motonari Adachi, * et al. Highly Efficient Dye-Sensitized Solar Cells with a Titania Thin-Film Electrode Composed of a Network Structure of Single-Crystal-like TiO2 Nanowires Made by the “Oriented Attachment” Mechanism. (2004) doi:https://doi.org/10.1021/JA048068S.
Wang, W. et al. Effects of low pressure plasma treatments on DSSCs based on rutile TiO 2 array photoanodes. Appl. Surf. Sci.324, 143–151 (2015).
Wu, W. Q., Xu, Y. F., Su, C. Y. & Kuang, D. Bin. Ultra-long anatase TiO2 nanowire arrays with multi-layered configuration on FTO glass for high-efficiency dye-sensitized solar cells. Energy Environ. Sci.7, 644–649 (2014).
Wu, W. Q. et al. Hierarchical oriented anatase TiO2 nanostructure arrays on flexible substrate for efficient dye-sensitized solar cells. Sci. Rep.3, 1–7 (2013).
Sun, P. et al. Rutile TiO2 nanowire array infiltrated with anatase nanoparticles as photoanode for dye-sensitized solar cells: Enhanced cell performance via the rutile-anatase heterojunction. J. Mater. Chem. A1, 3309–3314 (2013).
Sun, P. et al. Bilayer TiO2 photoanode consisting of a nanowire-nanoparticle bottom layer and a spherical voids scattering layer for dye-sensitized solar cells. New J. Chem.39, 4845–4851 (2015).
Mor, G. K., Varghese, O. K., Paulose, M., Shankar, K. & Grimes, C. A. A review on highly ordered, vertically oriented TiO2 nanotube arrays: Fabrication, material properties, and solar energy applications. Solar Energy Materials and Solar Cells vol. 90 2011–2075 (2006).
Zhou, Q., Fang, Z., Li, J. & Wang, M. Applications of TiO2 nanotube arrays in environmental and energy fields: A review. Microporous and Mesoporous Materials vol. 202 22–35 (2015).
Flores, I. C. et al. Dye-sensitized solar cells based on TiO2 nanotubes and a solid-state electrolyte. J. Photochem. Photobiol. A Chem.189, 153–160 (2007).
Park, H. et al. Fabrication of dye-sensitized solar cells by transplanting highly ordered TiO2 nanotube arrays. in Solar Energy Materials and Solar Cells vol. 95 184–189 (North-Holland, 2011).
Roy, P., Kim, D., Lee, K., Spiecker, E. & Schmuki, P. TiO2 nanotubes and their application in dye-sensitized solar cells. Nanoscale2, 45–59 (2010).
Kim, D., Ghicov, A. & Schmuki, P. TiO2 Nanotube arrays: Elimination of disordered top layers (“nanograss”) for improved photoconversion efficiency in dye-sensitized solar cells. Electrochem. commun.10, 1835–1838 (2008).
Zhu, K., Neale, N. R., Miedaner, A. & Frank, A. J. Enhanced charge-collection efficiencies and light scattering in dye-sensitized solar cells using oriented TiO2 nanotubes arrays. Nano Lett.7, 69–74 (2007).
Jennings, J. R., Ghicov, A., Peter, L. M., Schmuki, P. & Walker, A. B. Dye-sensitized solar cells based on oriented TiO2 nanotube arrays: Transport, trapping, and transfer of electrons. J. Am. Chem. Soc.130, 13364–13372 (2008).
Liu, Z. & Misra, M. Dye-sensitized photovoltaic wires using highly ordered TiO2 nanotube arrays. ACS Nano4, 2196–2200 (2010).
Kuo, C. G., Yang, C. F., Hwang, L. R. & Huang, J. S. Effects of titanium oxide nanotube arrays with different lengths on the characteristics of dye-sensitized solar cells. Int. J. Photoenergy2013, (2013).
Chen, W. C., Yeh, M. H., Lin, L. Y., Vittal, R. & Ho, K. C. Double-Wall TiO2 Nanotubes for Dye-Sensitized Solar Cells: A Study of Growth Mechanism. ACS Sustain. Chem. Eng.6, 3907–3915 (2018).
Lee, C. H., Kim, K. H., Jang, K. U., Park, S. J. & Choi, H. W. Synthesis of TiO 2 Nanotube by Hydrothermal Method and Application for Dye-Sensitized Solar Cell. Mol. Cryst. Liq. Cryst.539, 125/[465]-132/[472] (2011).
Yu, J., Fan, J. & Lv, K. Anatase TiO2 nanosheets with exposed (001) facets: Improved photoelectric conversion efficiency in dye-sensitized solar cells. Nanoscale2, 2144–2149 (2010).
Zhu, H. et al. Growth of TiO 2 nanosheet-array thin films by quick chemical bath deposition for dye-sensitized solar cells. Appl. Phys. A Mater. Sci. Process.105, 769–774 (2011).
Lee, C. S., Kim, J. K., Lim, J. Y. & Kim, J. H. One-step process for the synthesis and deposition of anatase, two-dimensional, disk-shaped TiO2 for dye-sensitized solar cells. ACS Appl. Mater. Interfaces6, 20842–20850 (2014).
Shanmugam, M., Jacobs-Gedrim, R., Durcan, C. & Yu, B. 2D layered insulator hexagonal boron nitride enabled surface passivation in dye sensitized solar cells. Nanoscale5, 11275–11282 (2013).
Lin, J. et al. A Bi-layer TiO2 photoanode for highly durable, flexible dye-sensitized solar cells. J. Mater. Chem. A3, 4679–4686 (2015).
Deepak, T. G. et al. Cabbage leaf-shaped two-dimensional TiO2 mesostructures for efficient dye-sensitized solar cells. RSC Adv.4, 27084–27090 (2014).
Chen, B. et al. Graphene Oxide-Assisted Synthesis of Microsized Ultrathin Single-Crystalline Anatase TiO2 Nanosheets and Their Application in Dye-Sensitized Solar Cells. ACS Appl. Mater. Interfaces8, 2495–2504 (2016).
Li, X., Yu, J. & Jaroniec, M. Hierarchical photocatalysts. Chemical Society Reviews vol. 45 2603–2636 (2016).
Chen, H. Y., Kuang, D. Bin & Su, C. Y. Hierarchically micro/nanostructured photoanode materials for dye-sensitized solar cells. Journal of Materials Chemistry vol. 22 15475–15489 (2012).
Zhang, Q. & Cao, G. Hierarchically structured photoelectrodes for dye-sensitized solar cells. J. Mater. Chem.21, 6769–6774 (2011).
Sanjay, P., Deepa, K., Madhavan, J. & Senthil, S. Performance of TiO2 based dye-sensitized solar cells fabricated with dye extracted from leaves of Peltophorum pterocarpum and Acalypha amentacea as sensitizer. Mater. Lett.219, 158–162 (2018).
Bahramian, A. High conversion efficiency of dye-sensitized solar cells based on coral-like TiO2 nanostructured films: Synthesis and physical characterization. Ind. Eng. Chem. Res.52, 14837–14846 (2013).
Mali, S. S., Betty, C. A., Bhosale, P. N., Patil, P. S. & Hong, C. K. From nanocorals to nanorods to nanoflowers nanoarchitecture for efficient dye-sensitized solar cells at relatively low film thickness: All Hydrothermal Process. Sci. Rep.4, 2–9 (2014).
Su, C. et al. Preparation and characterization of pure rutile TiO2 nanoparticles for photocatalytic study and thin films for dye-sensitized solar cells. J. Nanomater.2011, (2011).
Fang, F., Kennedy, J., Manikandan, E., Futter, J. & Markwitz, A. Morphology and characterization of TiO 2 nanoparticles synthesized by arc discharge. Chem. Phys. Lett.521, 86–90 (2012).
Liu, L., Yu, X. M., Zhang, B., Meng, S. X. & Feng, Y. Q. Synthesis of nano-TiO2 assisted by diethylene glycol for use in high efficiency dye-sensitized solar cells. Chinese Chem. Lett.28, 765–770 (2017).
Hussian, H. A. R. A., Hassan, M. A. M. & Agool, I. R. Synthesis of titanium dioxide (TiO2) nanofiber and nanotube using different chemical method. Optik (Stuttg).127, 2996–2999 (2016).
Guo, H. et al. Facile synthesis of chrysanthemum flowers-like TiO2 hierarchical microstructures assembled by nanotube for high performance dye-sensitized solar cells. Org. Electron.55, 97–105 (2018).
Luan, X., Guan, D. & Wang, Y. Facile synthesis and morphology control of bamboo-type TiO 2 nanotube arrays for high-efficiency dye-sensitized solar cells. J. Phys. Chem. C116, 14257–14263 (2012).
Mojaddami, M., Mohammadi, M. R. & Madaah Hosseini, H. R. Improved Efficiency of Dye-Sensitized Solar Cells Based on a Single Layer Deposition of Skein-Like TiO 2 Nanotubes . J. Am. Ceram. Soc.97, 2873–2879 (2014).
Roh, D. K., Chi, W. S., Jeon, H., Kim, S. J. & Kim, J. H. High efficiency Solid-state Dye-sensitized solar cells assembled with hierarchical anatase pine Tree-like TiO2 nanotubes. Adv. Funct. Mater.24, 379–386 (2014).
Fan, K., Zhang, W., Peng, T., Chen, J. & Yang, F. Application of TiO2 fusiform nanorods for dye-sensitized solar cells with significantly improved efficiency. J. Phys. Chem. C115, 17213–17219 (2011).
Liu, Y. Y. et al. One-step hydrothermal fabrication of three dimensional anatase hierarchical hyacinth-like TiO2 arrays for dye-sensitized solar cells. Thin Solid Films683, 42–48 (2019).
Tański, T. et al. Study of dye sensitized solar cells photoelectrodes consisting of nanostructures. Appl. Surf. Sci.491, 807–813 (2019).
Wu, W. Q. et al. Morphology-controlled cactus-like branched anatase TiO2 arrays with high light-harvesting efficiency for dye-sensitized solar cells. J. Power Sources260, 6–11 (2014).
Wei, Z., Yao, Y., Huang, T. & Yu, A. Solvothermal growth of well-aligned TiO2 nanowire arrays for dye-sensitized solar cell: Dependence of morphology and vertical orientation upon substrate pretreatment. Int. J. Electrochem. Sci.6, 1871–1879 (2011).
Li, H. et al. Ultralong Rutile TiO2 Nanowire Arrays for Highly Efficient Dye-Sensitized Solar Cells. ACS Appl. Mater. Interfaces8, 13384–13391 (2016).
Li, Y. et al. Au nanoparticle-decorated urchin-like TiO2 hierarchical microspheres for high performance dye-sensitized solar cells. Electrochim. Acta293, 230–239 (2019).
Marandi, M. & Bayat, S. Facile fabrication of hyper-branched TiO2 hollow spheres for high efficiency dye-sensitized solar cells. Sol. Energy174, 888–896 (2018).
Liu, Y. et al. Synthesis of “lotus root”-like mesoporous titanium dioxide and its effects on UV response to aconitine release. J. Alloys Compd.777, 285–293 (2019).
Hu, B. & Liu, B. Dye-sensitized solar cells fabricated by the TiO 2 nanostructural materials synthesized by electrospray and hydrothermal post-treatment. Appl. Surf. Sci.358, 412–417 (2015).
Pan, H., Qian, J., Cui, Y., Xie, H. & Zhou, X. Hollow anatase TiO2 porous microspheres with V-shaped channels and exposed (101) facets: Anisotropic etching and photovoltaic properties. J. Mater. Chem.22, 6002–6009 (2012).
Chen, Y. Z., Wu, R. J., Lin, L. Y. & Chang, W. C. Novel synthesis of popcorn-like TiO2 light scatterers using a facile solution method for efficient dye-sensitized solar cells. J. Power Sources413, 384–390 (2019).
Zhang, J., He, X., Zhu, M., Guo, Y. & Li, X. The preparation of hierarchical rutile TiO2 microspheres constructed with branched nanorods for efficient dye-sensitized solar cells. J. Alloys Compd.747, 729–737 (2018).
Xu, L. et al. Hierarchical submicroflowers assembled from ultrathin anatase TiO2 nanosheets as light scattering centers in TiO2 photoanodes for dye-sensitized solar cells. J. Alloys Compd.776, 1002–1008 (2019).
Ma, C. et al. Monodisperse TiO 2 microspheres assembled by porous spindles for high performance dye-sensitized solar cells. Colloids Surfaces A Physicochem. Eng. Asp.538, 94–99 (2018).
Li, Z. Q. et al. Mesoporous TiO2 Yolk-Shell Microspheres for Dye-sensitized Solar Cells with a High Efficiency Exceeding 11%. Sci. Rep.5, 1–8 (2015).
Beall, C., Piipari, K., Al-qassab, H. & Smith, M. A. Alkali-Corrosion Synthesis and Excellent DSSC Performance of a Novel Jujube-like Hierarchical TiO2 Microspheres. Biochem. J. 0–14 (2010).
Zhao, T. et al. Monodisperse mesoporous TiO2 microspheres for dye sensitized solar cells. Nano Energy26, 16–25 (2016).
Li, Z. Q. et al. Fine Tuning of Nanocrystal and Pore Sizes of TiO 2 Submicrospheres toward High Performance Dye-Sensitized Solar Cells. ACS Appl. Mater. Interfaces7, 22277–22283 (2015).
Hwang, S. H., Yun, J. & Jang, J. Multi-shell porous TiO2 hollow nanoparticles for enhanced light harvesting in dye-sensitized solar cells. Adv. Funct. Mater.24, 7619–7626 (2014).
Jiang, J., Gu, F., Shao, W. & Li, C. Fabrication of spherical multi-hollow TiO 2 nanostructures for photoanode film with enhanced light-scattering performance. Ind. Eng. Chem. Res.51, 2838–2845 (2012).
Lin, C. M. et al. Multi-step hydrothermally synthesized TiO 2 nanoforests and its application to dye-sensitized solar cells. Mater. Chem. Phys.135, 723–727 (2012).
Ma, J., Ren, W., Zhao, J. & Yang, H. Growth of TiO2nanoflowers photoanode for dye-sensitized solar cells. J. Alloys Compd.692, 1004–1009 (2017).
Javed, H. M. A. et al. Investigation on the surface modification of TiO2 nanohexagon arrays based photoanode with SnO2 nanoparticles for highly-efficient dye-sensitized solar cells. Mater. Res. Bull.109, 21–28 (2019).
Umale, S., Sudhakar, V., Sontakke, S. M., Krishnamoorthy, K. & Pandit, A. B. Improved efficiency of DSSC using combustion synthesized TiO2. Mater. Res. Bull.109, 222–226 (2019).
Amoli, V. et al. Tailored Synthesis of Porous TiO2 Nanocubes and Nanoparallelepipeds with Exposed {111} Facets and Mesoscopic Void Space: A Superior Candidate for Efficient Dye-Sensitized Solar Cells. ACS Appl. Mater. Interfaces7, 26022–26035 (2015).
Chae, J. & Kang, M. Cubic titanium dioxide photoanode for dye-sensitized solar cells. J. Power Sources196, 4143–4151 (2011).
Shuang, Y., Hou, Y., Zhang, B. & Yang, H. G. Impurity-free synthesis of cube-like single-crystal anatase TiO2 for high performance dye-sensitized solar cell. Ind. Eng. Chem. Res.52, 4098–4102 (2013).
Li, Z. Q. et al. Solvothermal Synthesis of Hierarchical TiO2 Microstructures with High Crystallinity and Superior Light Scattering for High-Performance Dye-Sensitized Solar Cells. ACS Appl. Mater. Interfaces9, 32026–32033 (2017).
Qiu, Y., Chen, W. & Yang, S. Double-Layered Photoanodes from Variable-Size Anatase TiO2 Nanospindles: A Candidate for High-Efficiency Dye-Sensitized Solar Cells. Angew. Chemie122, 3757–3761 (2010).
He, X., Li, X. & Zhu, M. The application of hollow box TiO2 as scattering centers in dye-sensitized solar cells. J. Power Sources333, 10–16 (2016).
Jeyaraman, A. R. et al. Enhanced solar to electrical energy conversion of titania nanoparticles and nanotubes-based combined photoanodes for dye-sensitized solar cells. Mater. Lett.243, 180–182 (2019).
Marandi, M., Bayat, S. & Naeimi Sani Sabet, M. Hydrothermal growth of a composite TiO2 hollow spheres/TiO2 nanorods powder and its application in high performance dye-sensitized solar cells. J. Electroanal. Chem.833, 143–150 (2019).
Kim, J. S. et al. Facile Preparation of TiO2 Nanobranch/Nanoparticle Hybrid Architecture with Enhanced Light Harvesting Properties for Dye-Sensitized Solar Cells. J. Nanomater.2015, (2015).
Wang, Y., Yang, W. & Shi, W. Preparation and characterization of anatase TiO2 nanosheets-based microspheres for dye-sensitized solar cells. Ind. Eng. Chem. Res.50, 11982–11987 (2011).
Acknowledgements
The authors acknowledge the support provided by PPE Department, UET Lahore.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2022 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this chapter
Cite this chapter
Sufyan, M., Mehmood, U., Yasmeen, S., Gill, Y.Q., Sadiq, M., Ali, M. (2022). Metal-Oxide Semiconductor Nanomaterials as Alternative to Carbon Allotropes for Third-Generation Thin-Film Dye-Sensitized Solar Cells. In: Sahoo, S., Tiwari, S.K., Das, A.K. (eds) Defect Engineering of Carbon Nanostructures. Advances in Material Research and Technology. Springer, Cham. https://doi.org/10.1007/978-3-030-94375-2_9
Download citation
DOI: https://doi.org/10.1007/978-3-030-94375-2_9
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-94374-5
Online ISBN: 978-3-030-94375-2
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)