Abstract
A new organo-mineral composite material has been synthesized by in situ immobilization of poly[(4-methacroyloxy-(4′-carboxy-2′-nitro)azobenzene] on the surface of saponite of Tashkivsky occurrence (Ukraine). According to the results of thermogravimetric analysis, it was found that the mass of immobilized polymer is 3.5%. The increase in the sorption capacity of the mineral after its modification by the selected polymer with respect to the ions Cu(II), Pb(II) and Fe(III) was recorded.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
Girin VM, Boyko II, Rudichenko VF (1995) The use of natural mineral saponite for water disinfection. Med Bus 5–6:177–179
Kulik MF, Zasuha TV, Lutyuk MB (2012) Saponite and aerosil in animal husbandry and medicine. Vinnitsa
Savchenko I, Yanovska E, Sternik D, Kychkiruk O, Ol’khovik L, Buriachenko I (2017) In situ immobilization on the silica gel surface and adsorption capacity of poly[N-(4-carboxyphenyl) methacrylamide] on toxic metal ions. Nanoscale Res Lett 12:313
Savchenko I, Yanovska E, Polonska Y, Sternik D, Kychkiruk O, Ol’khovik L (2019) In situ immobilization on the silica gel surface and adsorption capacity of polymer-based azobenzene on toxic metal ions. Appl Nanosci 9(5):657–664
Yanovska ES, Vretik LO, Nikolaeva OA, Polonska Y, Sternik D, Kichkiruk O (2017) Synthesis and adsorption properties of 4-vinylpyridine and styrene copolymer in situ immobilized on silica surface. Nanoscale Res Lett 12:217–222
Yanovska ES, Vretik LO, Nikolaeva OA, Kondratenko OO, Sternik D, Kichkiruk (2018)Synthesis and adsorption properties of 4-vinylpyridine, styrene and maleic anhydride copolymer in situ immobilized on silica surface. Mol Cryst Liq Cryst 672:104–114
Budnyak TM, Yanovskaya ES, Tortikh VA, Kichyruk OY (2010) Adsorption properties of natural minerals with in situ immobilized polyaniline with respect to the anionic forms Mo (VI), W (VI), Cr (VI), As (V), V (V) and P (V). Voprosy Khimii i Khimicheskoi Tekhnologii 5:43–47
Budnyak TM, Yanovskaya ES, Tortikh VA, Voznyuk VI (2011) The adsorption properties of the composite Sokyrnitsky clinoptilolite-polyaniline with respect to the anions of elements of groups V and VI of the periodic system DI Mendeleyev. Rep NAS Ukraine 3:141–145
Yanovska E, Savchenko I, Polonska Y, Ol’khovik L, Sternik D, Kychkiruk O (2017) Sorption properties for ions of toxic metals of Carpathian clinoptilolite (Ukraine), in situ modified by poly[N-carboxyphenyl)methacrylamide. New Mater Compd Appl 1:45–53
Yanovska E, Savchenko I, Polonska Y, Ol’khovik L, Sternik D, Kychkiruk O (2018) Sorption properties of toxic metal ions of saponite, in situ modified poly [N-(4-carboxyphenyl) methacrylamide]. Ukr Chem J 84:67–72
Sapurina I, Stejskal J (2008) The mechanism of the oxidative polymerization of aniline and the formation of supramolecular polyaniline structures. Pol Int 57:295–325
Davidenko N, Davidenko I, Savchenko I, Popenaka A (2008) Synthesis and electrooptical properties of metal-containing azopolymers. The influence of steric factors on the electro-optical effect in polycomplexes of azobenzene. Mol Cryst Liq Cryst 485:254–262
Savchenko I, Yanovska E, Polonska Y, Ol’khovik L, Sternik D, Kychkiruk O (2018) In situ immobilization on the silica gel surface and adsorption capacity of poly[4-methacroyloxy-(4′-carboxy-2′-nitro)-azobenzene] on toxic metals ions. Mol Cryst Liq Cryst 671:164–174
Polonska Y, Yanovska E, Savchenko I, Ol’khovik L, Sternik D, Kychkiruk O (2018) Adsorption capacity to toxic metals ions of azocontaining polymers, in situ immobilized on the silica gel surface. Mol Cryst Liq Cryst 673:39–47
Smith AL (1982) Applied IR spectroscopy. World, Moscow
Tarasevich BN (2012) IR spectra of the basic classes of organic compounds. Reference materials. Moscow: MSU them. M.V. Lomonosov
Parfitt GD, Rochester CH (1986) Adsorption from solution at the solid liquid interface M. Mir, 488
Skopenko VV, Savranskij LI (2004) Coordination chemistry. Kyiv, Lybid
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Switzerland AG
About this paper
Cite this paper
Savchenko, I.A., Yanovska, E., Polonska, Y., Ol’khovik, L., Sternik, D., Kychkyruk, O. (2020). The Sorption Properties of Ukrainian Saponite Clay In Situ Modified of Poly[4-Methacroyloxy-(4′-Carboxy-2′-Nitro)-Azobenzene] to Toxic Metals Ions. In: Fesenko, O., Yatsenko, L. (eds) Nanooptics and Photonics, Nanochemistry and Nanobiotechnology, and Their Applications . Springer Proceedings in Physics, vol 247. Springer, Cham. https://doi.org/10.1007/978-3-030-52268-1_5
Download citation
DOI: https://doi.org/10.1007/978-3-030-52268-1_5
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-52267-4
Online ISBN: 978-3-030-52268-1
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)