Abstract
With the advent of industrialization and globalization, the consumption of energy sources has reached a pinnacle from where the great minds have apprehension about sustainability. The focus has been shifted from fossil fuels to sustainable and cost-effective alternative energy sources to meet the requirement of the future generation. These energy sources include bioenergy in the form of biofuel, biodiesel, bioethanol, and biogas usually produced from the various organic biomasses. There are various steps involving the production of bioenergy from biomass and few of them hinder their commercialization. Nanotechnology offers a meaningful solution to the conventional bioprocesses used for the bioenergy production by changing the characteristics of the feed materials and biocatalysts. Nanoparticles manifest many unique characteristics like small size, large surface area, chemical stability, uniformity, and the ability of dispersion, and their electronic, magnetic, optical, physical, and chemical properties outclass them with their counterpart technologies. This chapter discusses an overview of the advantages of different types of nanoparticles used at various steps in the bioenergy production.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Abbaraju RR, Dasgupta N, Virkar AV (2008) Composite Nafion membranes containing nanosize TiO2∕ SnO2 for proton exchange membrane fuel cells. J Electrochem Soc 155(12):B1307–B1313
Abd-Elsalam K, Mohamed AA, Prasad R (2019) Magnetic Nanostructures: Environmental and Agricultural Applications. Springer International Publishing (ISBN 978-3-030-16438-6) https://www.springer.com/gp/book/9783030164386
Alzate CC, Toro OS (2006) Energy consumption analysis of integrated flowsheets for production of fuel ethanol from lignocellulosic biomass. Energy 31(13):2447–2459
Ambuchi JJ, Zhang Z, Shan L, Liang D, Zhang P, Feng Y (2017) Response of anaerobic granular sludge to iron oxide nanoparticles and multi-wall carbon nanotubes during beet sugar industrial wastewater treatment. Water Res 117:87–94
An J, Jeon H, Lee J, Chang IS (2011) Bifunctional silver nanoparticle cathode in microbial fuel cells for microbial growth inhibition with comparable oxygen reduction reaction activity. Environ Sci Technol 45(12):5441–5446
Ansari SA, Husain Q (2012) Potential applications of enzymes immobilized on/in nano materials: a review. Biotechnol Adv 30(3):512–523
Baskar G, Kumar RN, Melvin XH, Aiswarya R, Soumya S (2016) Sesbania aculeate biomass hydrolysis using magnetic nanobiocomposite of cellulase for bioethanol production. Renew Energ 98:23–28
Bowles LK, Ellefson WL (1985) Effects of butanol on Clostridium acetobutylicum. Appl Environ Microbiol 50(5):1165–1170
BP’s Statistical Review of World Energy (2017) https://www.bp.com/content/dam/bp-country/de_ch/PDF/bp-statistical-review-of-world-energy-2017-full-report.pdf
Budarin V, Shuttleworth PS, Lanigan B, Clark JH (2013) Nanocatalysts for biofuels. In: Polshettiwar V, Asefa T (eds) Nanocatalysis synthesis and applications. Wiley, Hoboken, pp 595–614
Casals E, Barrena R, GarcÃa A, González E, Delgado L, Busquets-Fité M, Font X, Arbiol J, Glatzel P, Kvashnina K, Sánchez A (2014) Programmed iron oxide nanoparticles disintegration in anaerobic digesters boosts biogas production. Small 10(14):2801–2808
Chang RH, Jang J, Wu KC (2011) Cellulase immobilized mesoporous silica nanocatalysts for efficient cellulose-to-glucose conversion. Green Chem 13(10):2844–2850
Chen G, Guo CY, Qiao H, Ye M, Qiu X, Yue C (2013) Well-dispersed sulfated zirconia nanoparticles as high-efficiency catalysts for the synthesis of bis (indolyl) methanes and biodiesel. Catal Commun 41:70–74
Chen B, Li F, Huang Z, Yuan G (2017) Carbon-coated Cu-Co bimetallic nanoparticles as selective and recyclable catalysts for production of biofuel 2,5-dimethylfuran. Appl Catal B 200:192–199
Cherian E, Dharmendirakumar M, Baskar G (2015) Immobilization of cellulase onto MnO2 nanoparticles for bioethanol production by enhanced hydrolysis of agricultural waste. Chinese J Catal 36(8):1223–1229
Cipolatti EP, Silva MJ, Klein M, Feddern V, Feltes MM, Oliveira JV, Ninow JL, de Oliveira D (2014) Current status and trends in enzymatic nanoimmobilization. J Mol Catal B Enzym 99:56–67
Colvin VL (2003) The potential environmental impact of engineered nanomaterials. Nat Biotechnol 21(10):1166–1170
Damartzis T, Zabaniotou A (2011) Thermochemical conversion of biomass to second generation biofuels through integrated process design – a review. Renew Sust Energ Rev 15(1):366–378
Dehkordi AM, Ghasemi M (2012) Transesterification of waste cooking oil to biodiesel using Ca and Zr mixed oxides as heterogeneous base catalysts. Fuel Process Technol 97:45–51
Di Serio M, Tesser R, Pengmei L, Santacesaria E (2007) Heterogeneous catalysts for biodiesel production. Energy Fuel 22(1):207–217
Donoso-Bravo A, Mairet F (2012) Determining the limiting reaction in anaerobic digestion processes. How has this been tackled? J Chem Technol Biotechnol 87(10):1375–1378
Elreedy A, Ibrahim E, Hassan N, El-Dissouky A, Fujii M, Yoshimura C, Tawfik A (2017) Nickel-graphene nanocomposite as a novel supplement for enhancement of biohydrogen production from industrial wastewater containing mono-ethylene glycol. Energy Convers Manage 140:133–144
Fan Y, Sharbrough E, Liu H (2008) Quantification of the internal resistance distribution of microbial fuel cells. Environ Sci Technol 42(21):8101–8107
Fang Z, Zhang F, Zeng HY, Guo F (2011) Production of glucose by hydrolysis of cellulose at 423 K in the presence of activated hydrotalcite nanoparticles. Bioresour Technol 102(17):8017–8021
Galbe M, Sassner P, Wingren A, Zacchi G (2007) Process engineering economics of bioethanol production. Adv Biochem Eng Biotechnol 108:303–327
GarcÃa A, Delgado L, Torà JA, Casals E, González E, Puntes V, Font X, Carrera J, Sánchez A (2012) Effect of cerium dioxide, titanium dioxide, silver, and gold nanoparticles on the activity of microbial communities intended in wastewater treatment. J Hazard Mater 199:64–72
Ghasemi M, Daud WR, Rahimnejad M, Rezayi M, Fatemi A, Jafari Y, Somalu MR, Manzour A (2013a) Copper-phthalocyanine and nickel nanoparticles as novel cathode catalysts in microbial fuel cells. Int J Hydrogen Energy 38(22):9533–9540
Ghasemi M, Ismail M, Kamarudin SK, Saeedfar K, Daud WR, Hassan SH, Heng LY, Alam J, Oh SE (2013b) Carbon nanotube as an alternative cathode support and catalyst for microbial fuel cells. Appl Energy 102:1050–1056
Goh WJ, Makam VS, Hu J, Kang L, Zheng M, Yoong SL, Udalagama CN, Pastorin G (2012) Iron oxide filled magnetic carbon nanotube–enzyme conjugates for recycling of amyloglucosidase: toward useful applications in biofuel production process. Langmuir 28(49):16864–16873
Gupta J, Agarwal M (2016) Preparation and characterization of CaO nanoparticle for biodiesel production. AIP Conf Proc. https://doi.org/10.1063/1.4945186
Gurunathan B, Ravi A (2015) Process optimization and kinetics of biodiesel production from neem oil using copper doped zinc oxide heterogeneous nanocatalyst. Bioresour Technol 190:424–428
Hu S, Guan Y, Wang Y, Han H (2011) Nano-magnetic catalyst KF/CaO–Fe3O4 for biodiesel production. Appl Energy 88(8):2685–2690
Hussain M, Ahmad R, Liu Y, Liu B, He M, He N (2017) Applications of nanomaterials and biological materials in bioenergy. J Nanosci Nanotechnol 17(12):8654–8666
Hussein AK (2015) Applications of nanotechnology in renewable energies – a comprehensive overview and understanding. Renew Sust Energ Rev 42:460–476
Hutchings G (2013) Nanocatalysis: synthesis and applications. John Wiley and Sons, Weinheim
Ingram LO (1989) Ethanol tolerance in bacteria. Crit Rev Biotechnol 9(4):305–319
Ivanova V, Petrova P, Hristov J (2011) Application in the ethanol fermentation of immobilized yeast cells in matrix of alginate/magnetic nanoparticles, on chitosan-magnetite microparticles and cellulose-coated magnetic nanoparticles. Int Rev Chem Eng 3:289–299
Jia Y, Hu Y, Zhu Y, Che L, Shen Q, Zhang J, Li X (2011) Oligoamines conjugated chitosan derivatives: synthesis, characterization, in vitro and in vivo biocompatibility evaluations. Carbohydr Polym 83(3):1153–1161
Khan MJ, Husain Q, Azam A (2012) Immobilization of porcine pancreatic α-amylase on magnetic Fe2O3 nanoparticles: applications to the hydrolysis of starch. Biotechnol Bioprocess Eng 17(2):377–384
Kim YK, Lee H (2016) Use of magnetic nanoparticles to enhance bioethanol production in syngas fermentation. Bioresour Technol 204:139–144
Kim YK, Park SE, Lee H, Yun JY (2014) Enhancement of bioethanol production in syngas fermentation with Clostridium ljungdahlii using nanoparticles. Bioresour Technol 159:446–450
Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS (1992) Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature 359(6397):710
Kumar Gupta S, Kumari S, Reddy K, Bux F (2013) Trends in biohydrogen production: major challenges and state-of-the-art developments. Environ Technol 34(13–14):1653–1670
Larsen SC (2007) Nanocrystalline zeolites and zeolite structures: synthesis, characterization, and applications. J Phys Chem C 111(50):18464–18474
Lee YC, Huh YS, Farooq W, Chung J, Han JI, Shin HJ, Jeong SH, Lee JS, Oh YK, Park JY (2013) Lipid extractions from docosahexaenoic acid (DHA)-rich and oleaginous Chlorella sp. biomasses by organic-nanoclays. Bioresour Technol 137:74–81
Lee AF, Bennett JA, Manayil JC, Wilson K (2014) Heterogeneous catalysis for sustainable biodiesel production via esterification and transesterification. Chem Soc Rev 43(22):7887–7916
Li M (2017) World Energy 2017-2050: Annual report. https://content.csbs.utah.edu/~mli/2017/World%20Energy%202017-2050.pdf
Lin YF, Chen JH, Hsu SH, Hsiao HC, Chung TW, Tung KL (2012) The synthesis of Lewis acid ZrO2 nanoparticles and their applications in phospholipid adsorption from Jatropha oil used for biofuel. J Colloid Interface Sci 368(1):660–662
Liu KK, Chen MF, Chen PY, Lee TJ, Cheng CL, Chang CC, Ho YP, Chao JI (2008) Alpha-bungarotoxin binding to target cell in a developing visual system by carboxylated nanodiamond. Nanotechnology 19(20):205102
Lu AH, Salabas EE, Schüth F (2007) Magnetic nanoparticles: synthesis, protection, functionalization, and application. Angew Chem Int Ed 46(8):1222–1244
Luna-del Risco M, Orupõld K, Dubourguier HC (2011) Particle-size effect of CuO and ZnO on biogas and methane production during anaerobic digestion. J Hazard Mater 189(1–2):603–608
Lupoi JS, Smith EA (2011) Evaluation of nanoparticle-immobilized cellulase for improved ethanol yield in simultaneous saccharification and fermentation reactions. Biotechnol Bioeng 108(12):2835–2843
Madsen M, Holm-Nielsen JB, Esbensen KH (2011) Monitoring of anaerobic digestion processes: a review perspective. Renew Sust Ener Rev 15(6):3141–3155
Malik P, Sangwan A (2012) Nanotechnology: a tool for improving efficiency of bio-energy. J Eng Appl Sci 1:37–49
Meher LC, Sagar DV, Naik SN (2006) Technical aspects of biodiesel production by transesterification – a review. Renew Sust Energ Rev 10(3):248–268
Mendes AA, Oliveira PC, Castro HF, Giordano RD (2011) Application of chitosan as support for immobilization of enzymes of industrial interest. QuÃm Nova 34(5):831–840
Mielby J, Abildstrøm JO, Wang F, Kasama T, Weidenthaler C, Kegnæs S (2014) Oxidation of bioethanol using Zeolite-encapsulated gold nanoparticles. Angew Chem Int Ed 126(46):12721–12724
Milledge JJ, Smith B, Dyer PW, Harvey P (2014) Macroalgae-derived biofuel: a review of methods of energy extraction from seaweed biomass. Energies 7(11):7194–7222
Misson M, Zhang H, Jin B (2015) Nanobiocatalyst advancements and bioprocessing applications. J R Soc Interface 12(102):20140891. https://doi.org/10.1098/rsif.2014.0891
Nicolas P, Lassalle V, Ferreira ML (2014) Development of a magnetic biocatalyst useful for the synthesis of ethyloleate. Bioprocess Biosyst Eng 37(3):585–591
Pathak PK, Raj J, Saxena G, Sharma US (2017) A review on production of biodiesel by transesterification using heterogeneous nanocatalyst. Int J Sci Res Dev 5(2):631–636
Pugh S, McKenna R, Moolick R, Nielsen DR (2011) Advances and opportunities at the interface between microbial bioenergy and nanotechnology. Can J Chem Eng 89(1):2–12
Rad AG, Abbasi H, Afzali MH (2011) Gold nanoparticles: synthesizing, characterizing and reviewing novel application in recent years. Phys Procedia 22:203–208
Raffi M, Hussain F, Bhatti TM, Akhter JI, Hameed A, Hasan MM (2008) Antibacterial characterization of silver nanoparticles against E. coli ATCC-15224. J Mater Sci Technol 24(2):192–196
Rahimnejad M, Ghasemi M, Najafpour GD, Ismail M, Mohammad AW, Ghoreyshi AA, Hassan SH (2012) Synthesis, characterization and application studies of self-made Fe3O4/PES nanocomposite membranes in microbial fuel cell. Electrochim Acta 85:700–706
Rai M, dos Santos JC, Soler MF, Marcelino PR, Brumano LP, Ingle AP, Gaikwad S, Gade A, da Silva SS (2016) Strategic role of nanotechnology for production of bioethanol and biodiesel. Nanotechnol Rev 5(2):231–250
Raita M, Arnthong J, Champreda V, Laosiripojana N (2015) Modification of magnetic nanoparticle lipase designs for biodiesel production from palm oil. Fuel Process Technol 134:189–197
Ram MS, Singh L, Suryanarayana MV, Alam SI (2000) Effect of iron, nickel and cobalt on bacterial activity and dynamics during anaerobic oxidation of organic matter. Water Air Soil Poll 117(1–4):305–312
Rao PP, Seenayya G (1994) Improvement of methanogenesis from cow dung and poultry litter waste digesters by addition of iron. World J Microbiol Biotechnol 10(2):211–214
Reis P, Witula T, Holmberg K (2008) Mesoporous materials as host for an entrapped enzyme. Micropor Mesopor Mat 110(2–3):355–362
Saini JK, Saini R, Tewari L (2015) Lignocellulosic agriculture wastes as biomass feedstocks for second-generation bioethanol production: concepts and recent developments. 3 Biotech 5(4):337–353
Santos FC, Paim LL, da Silva JL, Stradiotto NR (2016) Electrochemical determination of total reducing sugars from bioethanol production using glassy carbon electrode modified with graphene oxide containing copper nanoparticles. Fuel 163:112–121
Schrand AM, Hens SA, Shenderova OA (2009) Nanodiamond particles: properties and perspectives for bioapplications. Crit Rev Solid State Mater Sci 34(1–2):18–74
Schügerl K, Hubbuch J (2005) Integrated bioprocesses. Curr Opin Microbiol 8(3):294–300
Shah S, Venkatramanan V, Prasad R (2019) Microbial fuel cell: Sustainable green technology for bioelectricity generation and wastewater treatment. In: Sustainable Green Technologies for Environmental Management (eds. Shah S, Venkatramanan V, Prasad R), Springer Springer Nature Singapore Pte Ltd. 199–218
Shuttleworth PS, Parker HL, Hunt AJ, Budarin VL, Matharu AS, Clark JH (2014) Applications of nanoparticles in biomass conversion to chemicals and fuels. Green Chem 16(2):573–584
Sims RE, Mabee W, Saddler JN, Taylor M (2010) An overview of second generation biofuel technologies. Bioresour Technol 101(6):1570–1580
Souza KC, Mohallem ND, Sousa EM (2011) Magnetic nanocomposites: potential for applications in Biomedicine. QuÃm Nova 34(10):1692–1703
Srivastava N, Srivastava M, Mishra PK, Singh P, Ramteke PW (2015) Application of cellulases in biofuels industries: an overview. J Biofuel Bioenerg 1(1):55–63
Srivastava N, Srivastava M, Mishra PK, Ramteke PW (2016) Application of ZnO nanoparticles for improving the thermal and pH stability of crude cellulase obtained from Aspergillus fumigatus AA001. Front Microbiol 7:514. https://doi.org/10.3389/fmicb.2016.00514
Straathof AJ (2003) Auxiliary phase guidelines for microbial biotransformations of toxic substrate into toxic product. Biotechnol Prog 19(3):755–762
Su L, Shi X, Guo G, Zhao A, Zhao Y (2013) Stabilization of sewage sludge in the presence of nanoscale zero-valent iron (nZVI): abatement of odor and improvement of biogas production. J Mater Cycle Waste Manage 15(4):461–468
Tan C, Zhao S, Yang G, Hu S, Qin X (2015) Facile and surfactant-free synthesis of SnO2-graphene hybrids as high performance anode for lithium-ion batteries. Ionics 21(4):987–994
Taufiqurrahmi N, Mohamed AR, Bhatia S (2011) Production of biofuel from waste cooking palm oil using nanocrystalline zeolite as catalyst: process optimization studies. Bioresour Technol 102(22):10686–10694
Uygun DA, Öztürk N, Akgöl S, Denizli A (2012) Novel magnetic nanoparticles for the hydrolysis of starch with Bacillus licheniformis α-amylase. J Appl Polym Sci 123(5):2574–2581
Verma ML, Chaudhary R, Tsuzuki T, Barrow CJ, Puri M (2013) Immobilization of β-glucosidase on a magnetic nanoparticle improves thermostability: application in cellobiose hydrolysis. Bioresour Technol 135:2–6
Wang X, Dou P, Zhao P, Zhao C, Ding Y, Xu P (2009) Immobilization of lipases onto magnetic Fe3O4 nanoparticles for application in biodiesel production. Chem Sus Chem 2(10):947–950
Wang X, Liu X, Zhao C, Ding Y, Xu P (2011) Biodiesel production in packed-bed reactors using lipase–nanoparticle biocomposite. Bioresour Technol 102(10):6352–6355
Wang W, Martin JC, Fan X, Han A, Luo Z, Sun L (2012) Silica nanoparticles and frameworks from rice husk biomass. ACS Appl Mater Interfaces 4(2):977–981
Wen L, Wang Y, Lu D, Hu S, Han H (2010) Preparation of KF/CaO nanocatalyst and its application in biodiesel production from Chinese tallow seed oil. Fuel 89(9):2267–2271
Wen Z, Ci S, Mao S, Cui S, Lu G, Yu K, Luo S, He Z, Chen J (2013) TiO2 nanoparticles-decorated carbon nanotubes for significantly improved bioelectricity generation in microbial fuel cells. J Power Sources 234:100–106
Xie W, Ma N (2009) Immobilized lipase on Fe3O4 nanoparticles as biocatalyst for biodiesel production. Energ Fuel 23(3):1347–1353
Xie W, Ma N (2010) Enzymatic transesterification of soybean oil by using immobilized lipase on magnetic nano-particles. Biomass Bioenergy 34(6):890–896
Xu X, Li Y, Gong Y, Zhang P, Li H, Wang Y (2012) Synthesis of palladium nanoparticles supported on mesoporous N-doped carbon and their catalytic ability for biofuel upgrade. J Am Chem Soc 134(41):16987–16990
Yan Z, Wang M, Huang B, Liu R, Zhao J (2013) Graphene supported Pt-Co alloy nanoparticles as cathode catalyst for microbial fuel cells. Int J Electrochem Sci 8:149–158
Yang Y, Xu M, Wall JD, Hu Z (2012) Nanosilver impact on methanogenesis and biogas production from municipal solid waste. Waste Manag 32(5):816–825
Younes NR, Amara S, Mrad I, Ben-Slama I, Jeljeli M, Omri K, El Ghoul J, El Mir L, Rhouma KB, Abdelmelek H, Sakly M (2015) Subacute toxicity of titanium dioxide (TiO2) nanoparticles in male rats: emotional behavior and pathophysiological examination. Environ Sci Pollut Res 22(11):8728–8737
Yu CY, Huang LY, Kuan I, Lee SL (2013) Optimized production of biodiesel from waste cooking oil by lipase immobilized on magnetic nanoparticles. Int J Mol Sci 14(12):24074–24086
Yulianti CH, Ediati R, Hartanto D, Purbaningtias TE, Chisaki Y, Jalil AA, Ku CK, Prasetyoko D (2014) Synthesis of CaO-ZnO nanoparticles catalyst and its application in transesterification of refined palm oil. Bull Chem Reac Eng Cat 9(2):100–110
Zaidi AA, RuiZhe F, Shi Y, Khan SZ, Mushtaq K (2018) Nanoparticles augmentation on biogas yield from microalgal biomass anaerobic digestion. Int J Hydrogen Energy 18:1–12
Zhang J, Wang L, Ji Y, Chen F, Xiao FS (2018) Mesoporous zeolites for biofuel upgrading and glycerol conversion. Front Chem Sci Eng 26(1):132–144
Zhao S, Yin H, Du L, He L, Zhao K, Chang L, Yin G, Zhao H, Liu S, Tang Z (2014) Carbonized nanoscale metal–organic frameworks as high performance electrocatalyst for oxygen reduction reaction. ACS Nano 8(12):12660–12668
Zhao S, Li Y, Yin H, Liu Z, Luan E, Zhao F, Tang Z, Liu S (2015) Three-dimensional graphene/Pt nanoparticle composites as freestanding anode for enhancing performance of microbial fuel cells. Sci Adv 1(10):e1500372. https://doi.org/10.1126/sciadv.1500372
Zhou Q, Zhang H, Chang F, Li H, Pan H, Xue W, Hu DY, Yang S (2015) Nano La2O3 as a heterogeneous catalyst for biodiesel synthesis by transesterification of Jatropha curcas L. oil. J Ind Eng Chem 31:385–392
Zuliani A, Ivars F, Luque R (2018) Advances in nanocatalyst design for biofuel production. Chem Cat Chem 10(9):1968–1981
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Switzerland AG
About this chapter
Cite this chapter
Brar, A., Kumar, M., Vivekanand, V., Pareek, N. (2020). Nanoparticles and Their Role in Bioenergy Production. In: Thangadurai, D., Sangeetha, J., Prasad, R. (eds) Nanotechnology for Food, Agriculture, and Environment. Nanotechnology in the Life Sciences. Springer, Cham. https://doi.org/10.1007/978-3-030-31938-0_11
Download citation
DOI: https://doi.org/10.1007/978-3-030-31938-0_11
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-31937-3
Online ISBN: 978-3-030-31938-0
eBook Packages: Biomedical and Life SciencesBiomedical and Life Sciences (R0)