Abstract
When the goal is the production of biodiesel, it is beneficial to have some knowledge of the chemical analyses necessary for the determination of free fatty acids and the so-called acid number along with other kind of analyses required to assess the iodine number, the saponification of fats and oils. The biodiesel’s main characteristics and properties are described here together with the properties of the main biodiesel sources. Some microbial-based sources of biodiesel are also reported since this will be a new trend of the future production of biodiesel. The chapter continues with some comparisons between biodiesel and different fuels, and a more detailed description of the enzymatic process and kinetic modeling with the introduction of the Ping Pong Bi Bi mechanism.
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References
Adewale, P., Dumont, M.-J., & Ngadi, M. (2015). Enzyme-catalyzed synthesis and kinetics of ultrasonic-assisted methanolysis of waste choice white grease for fatty acid methyl ester production [WWW Document]. https://doi.org/10.1021/acs.energyfuels.5b00849.
Aldrich Chemical Company, Inc. (1990). Aldrich catalogue handbook of fine chemicals. Aldrich Chemical Company, Inc.
Andrews, L. W. (1903). Titrations with potassium iodate. Journal of the American Chemical Society, 25, 756–761. https://doi.org/10.1021/ja02009a012.
Aricetti, J. A., & Tubino, M. (2012). A green and simple visual method for the determination of the acid-number of biodiesel. Fuel, 95, 659–661. https://doi.org/10.1016/j.fuel.2011.10.058.
Baig, A., & Ng, F. T. T. (2011). Determination of acid number of biodiesel and biodiesel blends. Journal of the American Oil Chemists Society, 88, 243–253. https://doi.org/10.1007/s11746-010-1667-x.
Blin, J., Brunschwig, C., Chapuis, A., Changotade, O., Sidibe, S. S., Noumi, E. S., et al. (2013). Characteristics of vegetable oils for use as fuel in stationary diesel engines—Towards specifications for a standard in West Africa. Renewable and Sustainable Energy Reviews, 22, 580–597. https://doi.org/10.1016/j.rser.2013.02.018.
Cetinkaya, M., & Karaosmanoglu, F. (2004). Optimisation of base-catalysed transesterification reaction of used cooking oil. Energy & Fuels, 18, 1888–1895.
Date, A. W. (2012). Analytic combustion with thermodynamics, chemical kinetics and mass transfer. Cambridge: Cambridge University Press. https://doi.org/10.1017/CBO9780511976759.
Dean, J. A. (1985). Lange’s handbook of chemistry (13th ed.). McGraw-Hill.
Drapcho, C. M., Nghiem, J., & Walker, T. (2008a). Biofuels engineering process technology. McGraw-Hill Education.
Drapcho, C. M., Nghim, N. P., & Walker, T. (2008b). Biofuels, bioproducts and biorefining. McGraw-Hill.
El Rassy, H., Perrard, A., & Pierre, A. C. (2004). Application of lipase encapsulated in silica aerogels to a transesterification reaction in hydrophobic and hydrophilic solvents: Bi-Bi Ping-Pong kinetics. Journal of Molecular Catalysis. B, Enzymatic, 30, 137–150. https://doi.org/10.1016/j.molcatb.2004.03.013.
Encinar, J. M., González, J. F., & Rodríguez-Reinares, A. (2005). Biodiesel from used frying oil. Variables affecting the yields and characteristics of the biodiesel. Industrial and Engineering Chemistry Research, 44, 5491–5499. https://doi.org/10.1021/ie040214f.
Georgogianni, K. G., Kontominas, M. G., Tegou, E., Avlonitis, D., & Vergis, V. (2007). Biodiesel production: Reaction and process parameters of alkali-catalysed transesterification of waste frying-oils. Energy & Fuels, 21, 3023–3027.
Giakoumis, E. G. (2018). Analysis of 22 vegetable oils’ physico-chemical properties and fatty acid composition on a statistical basis, and correlation with the degree of unsaturation. Renewable Energy, 126, 403–419. https://doi.org/10.1016/j.renene.2018.03.057.
Lin, C.-Y., & Lin, Y.-W. (2012). Fuel characteristics of biodiesel produced from a high-acid oil from soybean soapstock by supercritical-methanol transesterification. Energies, 5, 2370–2380. https://doi.org/10.3390/en5072370.
Lotero, E., Liu, Y., Lopez, D. E., Suwannakarn, K., Bruce, D. A., & Goodwin, J. G. (2005). Synthesis of biodiesel via acid catalysis. Industrial and Engineering Chemistry Research, 44, 5353–5363.
Mollenhauer, K., & Tschöke, H. (2010). Handbook of diesel engines. Berlin: Springer.
Morrison, R. T., & Boyd, R. N. (1992). Organic chemistry (6th ed.). Prentice Hall.
Orsavova, J., Misurcova, L., Vavra Ambrozova, J., Vicha, R., & Mlcek, J. (2015). Fatty acids composition of vegetable oils and its contribution to dietary energy intake and dependence of cardiovascular mortality on dietary intake of fatty acids. International Journal of Molecular Sciences, 16, 12871–12890. https://doi.org/10.3390/ijms160612871.
Park, L. K.-E., Liu, J., Yiacoumi, S., Borole, A. P., & Tsouris, C. (2017). Contribution of acidic components to the total acid number (TAN) of bio-oil. Fuel, 200, 171–181. https://doi.org/10.1016/j.fuel.2017.03.022.
Patel, N. K., & Shah, S. N. (2015). Biodiesel from plant oils, Chap. 11. In S. Ahuja (Ed.), Food, energy, and water (pp. 277–307). Boston: Elsevier. https://doi.org/10.1016/B978-0-12-800211-7.00011-9.
Phan, A. N., & Phan, T. M. (2008). Biodiesel production from waste cooking oils. Fuel, 87, 3490–3496. https://doi.org/10.1016/j.fuel.2008.07.008.
Rand, S. (2010). Significance of tests for petroleum products (8th ed.). United States: American Society for Testing and Materials, ASTM.
Satyanarayana, K., & Rao, P. G. (1992). Improved equation to estimate flash points of organic compounds. Journal of Hazardous Materials, 32, 81–85. https://doi.org/10.1016/0304-3894(92)85106-B.
Weiss, G. (1980). Hazardous chemicals data book. Park Ridge, HJ: Noyes Data Corporation.
Yasuda, M. (1931). The determination of the iodine number of lipids. Journal of Biological Chemistry, 94, 401–409.
Zumdahl, S. S., & Zumdahl, S. A. (2014). Chemistry (9th ed.). Brooks Cole Cengage Learning.
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De Blasio, C. (2019). Some Chemical Analyses in Biodiesel Production and Biofuel Characteristics. In: Fundamentals of Biofuels Engineering and Technology. Green Energy and Technology. Springer, Cham. https://doi.org/10.1007/978-3-030-11599-9_19
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