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Clay-Based Nanocomposites: Potential Materials for Water Treatment Applications

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Advanced Research in Nanosciences for Water Technology

Part of the book series: Nanotechnology in the Life Sciences ((NALIS))

Abstract

Water treatment with its current level of pollution and increased complexity of pollutants has become a major concern and grand challenge for ensuring sustainability of water nowadays. Nanoclays and their composites have played an increasingly important role in dealing with these multifaceted pollution perspectives. These clay minerals exist in various types having basic structure of aluminosilicates but vary in their properties like cation-exchange capacity, swelling tendency, surface area, and chemical and mechanical strengths that directly or indirectly impact their adsorption capacity. This chapter reviews and summarizes the recent technological advancements circling around the nanoclays, nano-organoclays, and their nanocomposites focusing on the mechanistic ways that affect the adsorption of pollutants from the aqueous media. The modifications implied to these nanoclays have extended their applications by enhancing their properties resulting in strong ability to sorb organic, inorganic, and even biological impurities in potable as well as wastewater.

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References

  • Abbas A, Sallam AS, Usman AR, Al-Wabel MI (2017) Organoclay-based nanoparticles from montmorillonite and natural clay deposits: synthesis characteristics and application for MTBE removal. Appl Clay Sci 142:21–29

    Article  CAS  Google Scholar 

  • Acisli O, Khataee A, Karaca S, Sheydaei M (2016) Modification of nanosized natural montmorillonite for ultrasound-enhanced adsorption of Acid Red 17. Ultrason Sonochem 31:116–121

    Article  CAS  PubMed  Google Scholar 

  • Amil Usmani M, Khan I, Bhat AH, Pillai RS, Ahmad N, Mohamad Haafiz KM, Oves M (2017) Current trend in the application of nanoparticles for waste water treatment and purification: a review. Curr Org Synth 14(2):206–226

    Article  CAS  Google Scholar 

  • Bagchi B, Kar S, Dey SK, Bhandary S, Roy D, Mukhopadhyay TK, Nandy P (2013) In situ synthesis and antibacterial activity of copper nanoparticle loaded natural montmorillonite clay based on contact inhibition and ion release. Colloids Surf B Biointerfaces 108:358–365

    Article  CAS  PubMed  Google Scholar 

  • Ballav N, Choi HJ, Mishra SB, Maity A (2014) Polypyrrole-coated halloysite nanotube clay nanocomposite: synthesis characterization and Cr (VI) adsorption behaviour. Appl Clay Sci 102:60–70

    Article  CAS  Google Scholar 

  • Belessi V, Lambropoulou D, Konstantinou I, Katsoulidis A, Pomonis P, Petridis D, Albanis T (2007) Structure and photocatalytic performance of TiO2/clay nanocomposites for the degradation of dimethachlor. Appl Catal B 73(3–4):292–299

    Article  CAS  Google Scholar 

  • Bergaya F, Lagaly G (2013) Handbook of clay science. Elsevier Science, Amsterdam; Oxford

    Google Scholar 

  • Bergaya F, Jaber M, Lambert JF (2012) Clays and clay minerals as layered nanofillers for (bio) polymers. In: Averous L, Pollet E (eds) Environmental silicate nano-biocomposites. Springer, London, pp 41–75

    Chapter  Google Scholar 

  • Bhattacharyya KG, Gupta SS (2008) Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite: a review. Adv Colloid Interf Sci 140(2):114–131

    Article  CAS  Google Scholar 

  • Bhattacharyya R, Ray SK (2015) Removal of Congo red and methyl violet from water using nano clay filled composite hydrogels of poly acrylic acid and polyethylene glycol. Chem Eng J 260:269–283

    Article  CAS  Google Scholar 

  • Bleiman N, Mishael YG (2010) Selenium removal from drinking water by adsorption to chitosan–clay composites and oxides: batch and columns tests. J Hazard Mater 183(1–3):590–595

    Article  CAS  PubMed  Google Scholar 

  • Bouna L, Rhouta B, Amjoud M, Maury F, Lafont MC, Jada A, Daoudi L (2011) Synthesis characterization and photocatalytic activity of TiO2 supported natural palygorskite microfibers. Appl Clay Sci 52(3):301–311

    Article  CAS  Google Scholar 

  • Bruna J, Peñaloza A, Guarda A, Rodríguez F, Galotto M (2012) Development of MtCu2+/LDPE nanocomposites with antimicrobial activity for potential use in food packaging. Appl Clay Sci 58:79–87

    Article  CAS  Google Scholar 

  • Bulut Y, Karaer H (2015) Adsorption of methylene blue from aqueous solution by crosslinked chitosan/bentonite composite. J Dispers Sci Technol 36(1):61–67

    Article  CAS  Google Scholar 

  • Cadena F, Rizvi R, Peters RW (1990) Feasibility studies for the removal of heavy metals from solution using tailored bentonite. Paper presented at the Hazardous and industrial wastes. Proceedings of the mid-Atlantic industrial waste conference, Drexel University

    Google Scholar 

  • Celis R, Adelino M, Hermosin M, Cornejo J (2012) Montmorillonite–chitosan bionanocomposites as adsorbents of the herbicide clopyralid in aqueous solution and soil/water suspensions. J Hazard Mater 209:67–76

    Article  PubMed  CAS  Google Scholar 

  • Chang MY, Juang RS (2004) Adsorption of tannic acid humic acid and dyes from water using the composite of chitosan and activated clay. J Colloid Interface Sci 278(1):18–25

    Article  CAS  PubMed  Google Scholar 

  • Chen W, Liu HC (2014) Adsorption of sulfate in aqueous solutions by organo-nano-clay: adsorption equilibrium and kinetic studies. J Cent South Univ 21(5):1974–1981

    Article  CAS  Google Scholar 

  • Chen H, Zhao J (2009) Adsorption study for removal of Congo red anionic dye using organo-attapulgite. Adsorption 15(4):381–389

    Article  CAS  Google Scholar 

  • Chen Q, Wu P, Dang Z, Zhu N, Li P, Wu J, Wang X (2010) Iron pillared vermiculite as a heterogeneous photo-Fenton catalyst for photocatalytic degradation of azo dye reactive brilliant orange X-GN. Separ Purif Technol 71(3):315–323

    Article  CAS  Google Scholar 

  • Chen D, Chen J, Luan X, Ji H, Xia Z (2011a) Characterization of anion–cationic surfactants modified montmorillonite and its application for the removal of methyl orange. Chem Eng J 171(3):1150–1158

    Article  CAS  Google Scholar 

  • Chen LF, Liang HW, Lu Y, Cui CH, Yu SH (2011b) Synthesis of an attapulgite clay@carbon nanocomposite adsorbent by a hydrothermal carbonization process and their application in the removal of toxic metal ions from water. Langmuir 27(14):8998–9004

    Article  CAS  PubMed  Google Scholar 

  • Chen J, Hong X, Xie Q, Li D, Zhang Q (2014) Sepiolite fiber oriented-polypyrrole nanofibers for efficient chromium (VI) removal from aqueous solution. J Chem Eng Data 59(7):2275–2282

    Article  CAS  Google Scholar 

  • Chen J, Hong X, Xie Q, Tian M, Li K, Zhang Q (2015) Exfoliated polypyrrole/montmorillonite nanocomposite with flake-like structure for Cr (VI) removal from aqueous solution. Res Chem Intermed 41(12):9655–9671

    Article  CAS  Google Scholar 

  • Chen J, Yan L-g, Yu H-q, Li S, Qin L-l, Liu G, Du B (2016a) Efficient removal of phosphate by facile prepared magnetic diatomite and illite clay from aqueous solution. Chem Eng J 287:162–172

    Article  CAS  Google Scholar 

  • Chen L, Zhou CH, Fiore S, Tong DS, Zhang H, Li C, Yu WH (2016b) Functional magnetic nanoparticle/clay mineral nanocomposites: preparation magnetism and versatile applications. Appl Clay Sci 127:143–163

    Article  CAS  Google Scholar 

  • De Paiva LB, Morales AR, Díaz FRV (2008) Organoclays: properties preparation and applications. Appl Clay Sci 42(1–2):8–24

    Article  CAS  Google Scholar 

  • Ding X, An T, Li G, Zhang S, Chen J, Yuan J, Fu J (2008) Preparation and characterization of hydrophobic TiO2 pillared clay: the effect of acid hydrolysis catalyst and doped Pt amount on photocatalytic activity. J Colloid Interface Sci 320(2):501–507

    Article  CAS  PubMed  Google Scholar 

  • Dou B, Dupont V, Pan W, Chen B (2011) Removal of aqueous toxic Hg (II) by synthesized TiO2 nanoparticles and TiO2/montmorillonite. Chem Eng J 166(2):631–638

    Article  CAS  Google Scholar 

  • Duan J, Liu R, Chen T, Zhang B, Liu J (2012) Halloysite nanotube-Fe3O4 composite for removal of methyl violet from aqueous solutions. Desalination 293:46–52

    Article  CAS  Google Scholar 

  • Edition F (2011) Guidelines for drinking-water quality. WHO Chron 38(4):104–108

    Google Scholar 

  • Encyclopaedia Britannica (1998) In: McHenry R (ed) Encyclopaedia Britannica. Encyclopaedia Britannica, Inc.

    Google Scholar 

  • Eren E, Afsin B, Onal Y (2009) Removal of lead ions by acid activated and manganese oxide-coated bentonite. J Hazard Mater 161(2–3):677–685

    Article  CAS  PubMed  Google Scholar 

  • Feng J, Hu X, Yue PL, Zhu HY, Lu GQ (2003) Degradation of azo-dye orange II by a photoassisted Fenton reaction using a novel composite of iron oxide and silicate nanoparticles as a catalyst. Ind Eng Chem Res 42(10):2058–2066

    Article  CAS  Google Scholar 

  • Feng J, Wong RS, Hu X, Yue PL (2004) Discoloration and mineralization of Orange II by using Fe3+-doped TiO2 and bentonite clay-based Fe nanocatalysts. Catal Today 98(3):441–446

    Article  CAS  Google Scholar 

  • Gámiz B, Hermosín M, Cornejo J, Celis R (2015) Hexadimethrine-montmorillonite nanocomposite: characterization and application as a pesticide adsorbent. Appl Surf Sci 332:606–613

    Article  CAS  Google Scholar 

  • Ganigar R, Rytwo G, Gonen Y, Radian A, Mishael YG (2010) Polymer–clay nanocomposites for the removal of trichlorophenol and trinitrophenol from water. Appl Clay Sci 49(3):311–316

    Article  CAS  Google Scholar 

  • Gao Z, Peng X, Zhang H, Luan Z, Fan B (2009) Montmorillonite–Cu (II)/Fe (III) oxides magnetic material for removal of cyanobacterial Microcystis aeruginosa and its regeneration. Desalination 247(1–3):337–345

    Article  CAS  Google Scholar 

  • Girase B, Depan D, Shah J, Xu W, Misra R (2011) Silver–clay nanohybrid structure for effective and diffusion-controlled antimicrobial activity. Mater Sci Eng C 31(8):1759–1766

    Article  CAS  Google Scholar 

  • Grim RE (1962) Clay mineralogy: the clay mineral composition of soils and clays is providing an understanding of their properties. Science 135(3507):890–898

    Article  CAS  PubMed  Google Scholar 

  • Grim R, Guven N (1978) Bentonite: geology, clay mineralogy properties and users. Elsevier Science Publishing, New York

    Google Scholar 

  • Hassani A, Khataee A, Karaca S, Karaca M, KıranÅŸan M (2015a) Adsorption of two cationic textile dyes from water with modified nanoclay: a comparative study by using central composite design. J Environ Chem Eng 3(4):2738–2749

    Article  CAS  Google Scholar 

  • Hassani A, Khataee A, Karaca S, Shirzad-Siboni M (2015b) Surfactant-modified montmorillonite as a nanosized adsorbent for removal of an insecticide: kinetic and isotherm studies. Environ Technol 36(24):3125–3135

    Article  CAS  PubMed  Google Scholar 

  • Hassani A, Soltani RDC, KıranÅŸan M, Karaca S, Karaca C, Khataee A (2016) Ultrasound-assisted adsorption of textile dyes using modified nanoclay: central composite design optimization. Korean J Chem Eng 33(1):178–188

    Article  CAS  Google Scholar 

  • Hong SI, Rhim JW (2008) Antimicrobial activity of organically modified nano-clays. J Nanosci Nanotechnol 8(11):5818–5824

    Article  CAS  PubMed  Google Scholar 

  • Hundáková M, Valášková M, Samlíková M, Pazdziora E (2014) Vermiculite with Ag and Cu used as an antibacterial nanofiller in polyethylene/vermikulit S Ag A Cu Použitý Jako Antibakteriální Nanoplnivo V Polyethylenu. GeoSci Eng 60(3):28–36

    Article  Google Scholar 

  • Ismadji S, Soetaredjo FE, Ayucitra A (2015) Clay materials for environmental remediation. Springer International Publishing, Cham

    Book  Google Scholar 

  • Jiang JQ, Cooper C (2003) Preparation of modified clay adsorbents for the removal of humic acid. Environ Eng Sci 20(6):581–586

    Article  CAS  Google Scholar 

  • Kaplan M, Kasgoz H (2011) Hydrogel nanocomposite sorbents for removal of basic dyes. Polym Bull 67(7):1153–1168

    Article  CAS  Google Scholar 

  • Kasama T, Watanabe Y, Yamada H, Murakami T (2004) Sorption of phosphates on Al-pillared smectites and mica at acidic to neutral pH. Appl Clay Sci 25(3–4):167–177

    Article  CAS  Google Scholar 

  • KaÅŸgöz H, Durmus A (2008) Dye removal by a novel hydrogel-clay nanocomposite with enhanced swelling properties. Polym Adv Technol 19(7):838–845

    Article  CAS  Google Scholar 

  • KaÅŸgöz H, DurmuÅŸ A, KaÅŸgöz A (2008) Enhanced swelling and adsorption properties of AAm-AMPSNa/clay hydrogel nanocomposites for heavy metal ion removal. Polym Adv Technol 19(3):213–220

    Article  CAS  Google Scholar 

  • Khalaf A, Yehia A, Temraz MM (2016) A short review on hybrid clay/rubber nanocomposites. KGK KAUT Gummi Kunst 69(6):22–32

    CAS  Google Scholar 

  • Khataee A, Sheydaei M, Hassani A, Taseidifar M, Karaca S (2015) Sonocatalytic removal of an organic dye using TiO2/Montmorillonite nanocomposite. Ultrason Sonochem 22:404–411

    Article  CAS  PubMed  Google Scholar 

  • Kiani G, Dostali M, Rostami A, Khataee AR (2011) Adsorption studies on the removal of Malachite Green from aqueous solutions onto halloysite nanotubes. Appl Clay Sci 54(1):34–39

    CAS  Google Scholar 

  • Kohay H, Izbitski A, Mishael YG (2015) Developing polycation-clay sorbents for efficient filtration of diclofenac: effect of dissolved organic matter and comparison to activated carbon. Environ Sci Technol 49(15):9280–9288

    Article  CAS  PubMed  Google Scholar 

  • Kryuchkova M, Danilushkina A, Lvov Y, Fakhrullin R (2016) Evaluation of toxicity of nanoclays and graphene oxide in vivo: a Paramecium caudatum study. Environ Sci Nano 3(2):442–452

    Article  CAS  Google Scholar 

  • Küçükselek Ç (2007) Investigation of applicability of clay minerals in wastewater treatment. Graduate School of Natural and Applied Sciences. Dokul Eylül University. pp 9–26

    Google Scholar 

  • Kumar ASK, Kalidhasan S, Rajesh V, Rajesh N (2011) Application of cellulose-clay composite biosorbent toward the effective adsorption and removal of chromium from industrial wastewater. Ind Eng Chem Res 51(1):58–69

    Article  CAS  Google Scholar 

  • Lee SM, Tiwari D (2012) Organo and inorgano-organo-modified clays in the remediation of aqueous solutions: an overview. Appl Clay Sci 59:84–102

    Article  CAS  Google Scholar 

  • Li P, Kim NH, Yoo GH, Lee JH (2009) Poly (acrylamide/laponite) nanocomposite hydrogels: swelling and cationic dye adsorption properties. J Appl Polym Sci 111(4):1786–1798

    Article  CAS  Google Scholar 

  • Li R, Wang JJ, Zhou B, Awasthi MK, Ali A, Zhang Z, Mahar A (2016) Enhancing phosphate adsorption by Mg/Al layered double hydroxide functionalized biochar with different Mg/Al ratios. Sci Total Environ 559:121–129

    Article  CAS  PubMed  Google Scholar 

  • Lim GO, Jang SA, Song KB (2010) Physical and antimicrobial properties of Gelidium corneum/nano-clay composite film containing grapefruit seed extract or thymol. J Food Eng 98(4):415–420

    Article  CAS  Google Scholar 

  • Liu L, Wan Y, Xie Y, Zhai R, Zhang B, Liu J (2012) The removal of dye from aqueous solution using alginate-halloysite nanotube beads. Chem Eng J 187:210–216

    Article  CAS  Google Scholar 

  • Ma J, Zou J, Li L, Yao C, Kong Y, Cui B, Li D (2014) Nanocomposite of attapulgite–Ag3PO4 for Orange II photodegradation. Appl Catal B 144:36–40

    Article  CAS  Google Scholar 

  • Mahdavinia GR, Asgari A (2013) Synthesis of kappa-carrageenan-g-poly (acrylamide)/sepiolite nanocomposite hydrogels and adsorption of cationic dye. Polym Bull 70(8):2451–2470

    Article  CAS  Google Scholar 

  • Meng N, Zhou NL, Zhang SQ, Shen J (2009) Synthesis and antimicrobial activities of polymer/montmorillonite–chlorhexidine acetate nanocomposite films. Appl Clay Sci 42(3–4):667–670

    Article  CAS  Google Scholar 

  • Meshram S, Limaye R, Ghodke S, Nigam S, Sonawane S, Chikate R (2011) Continuous flow photocatalytic reactor using ZnO–bentonite nanocomposite for degradation of phenol. Chem Eng J 172(2–3):1008–1015

    Article  CAS  Google Scholar 

  • Mishra A, Mehta A, Sharma M, Basu S (2017) Enhanced heterogeneous photodegradation of VOC and dye using microwave synthesized TiO2/clay nanocomposites: a comparison study of different type of clays. J Alloys Compd 694:574–580

    Article  CAS  Google Scholar 

  • Mokhtar M (2017) Application of synthetic layered sodium silicate magadiite nanosheets for environmental remediation of methylene blue dye in water. Materials 10(7):760

    Article  PubMed Central  CAS  Google Scholar 

  • Motshekga SC, Ray SS, Onyango MS, Momba MN (2013) Microwave-assisted synthesis characterization and antibacterial activity of Ag/ZnO nanoparticles supported bentonite clay. J Hazard Mater 262:439–446

    Article  CAS  PubMed  Google Scholar 

  • Moussout H, Ahlafi H, Aazza M, El Akili C (2018) Performances of local chitosan and its nanocomposite 5% Bentonite/Chitosan in the removal of chromium ions (Cr (VI)) from wastewater. Int J Biol Macromol 108:1063–1073

    Article  CAS  PubMed  Google Scholar 

  • Na P, Jia X, Yuan B, Li Y, Na J, Chen Y, Wang L (2010) Arsenic adsorption on Ti-pillared montmorillonite. J Chem Technol Biotechnol 85(5):708–714

    Article  CAS  Google Scholar 

  • Narayanan DP, Gopalakrishnan A, Yaakob Z, Sugunan S, Narayanan BN (2017) A facile synthesis of clay—graphene oxide nanocomposite catalysts for solvent free multicomponent Biginelli reaction. Arab J Chem. https://doi.org/10.1016/j.arabjc.2017.04.011

  • Nazir MS, Kassim MH, Mohapatra L, Gilani MA, Raza MR, Majeed K (2016) Characteristic properties of nanoclays and characterization of nanoparticulates and nanocomposites. In: Nanoclay reinforced polymer composites. Springer, Singapore, pp 35–55

    Chapter  Google Scholar 

  • Nikkhah AA, Zilouei H, Asadinezhad A, Keshavarz A (2015) Removal of oil from water using polyurethane foam modified with nanoclay. Chem Eng J 262:278–285

    Article  CAS  Google Scholar 

  • Olad A, Azhar FF, Shargh M, Jharfi S (2014) Application of response surface methodology for modeling of reactive dye removal from solution using starch-montmorillonite/polyaniline nanocomposite. Polym Eng Sci 54(7):1595–1607

    Article  CAS  Google Scholar 

  • Pandey S, Mishra SB (2011) Organic–inorganic hybrid of chitosan/organoclay bionanocomposites for hexavalent chromium uptake. J Colloid Interface Sci 361(2):509–520

    Article  CAS  PubMed  Google Scholar 

  • Patel HA, Somani RS, Bajaj HC, Jasra RV (2006) Nanoclays for polymer nanocomposites paints inks greases and cosmetics formulations drug delivery vehicle and waste water treatment. Bull Mater Sci 29(2):133–145

    Article  CAS  Google Scholar 

  • Peng Q, Liu M, Zheng J, Zhou C (2015) Adsorption of dyes in aqueous solutions by chitosan–halloysite nanotubes composite hydrogel beads. Microporous Mesoporous Mater 201:190–201

    Article  CAS  Google Scholar 

  • Petrik L, Missengue R, Fatoba O, Tuffin M, Sachs J (2012) Silver/zeolite nano composite-based clay filters for water disinfection. Water Research Commission WRC report (KV 297/12) ISSN 1790670070

    Google Scholar 

  • Piri S, Zanjani ZA, Piri F, Zamani A, Yaftian M, Davari M (2016) Potential of polyaniline modified clay nanocomposite as a selective decontamination adsorbent for Pb (II) ions from contaminated waters; kinetics and thermodynamic study. J Environ Health Sci Eng 14(1):20

    Article  PubMed  PubMed Central  CAS  Google Scholar 

  • Pourabolghasem H, Ghorbanpour M, Shayegh R (2016) Antibacterial activity of copper-doped montmorillonite nanocomposites prepared by alkaline ion exchange method. J Phys Sci 27(2):1–8

    Article  Google Scholar 

  • Rafati L, Ehrampoush M, Rafati A, Mokhtari M, Mahvi A (2018) Removal of ibuprofen from aqueous solution by functionalized strong nano-clay composite adsorbent: kinetic and equilibrium isotherm studies. Int J Environ Sci Technol 15(3):513–524

    Article  CAS  Google Scholar 

  • Rafiei H, Shirvani M, Ogunseitan O (2016) Removal of lead from aqueous solutions by a poly (acrylic acid)/bentonite nanocomposite. Appl Water Sci 6(4):331–338

    Article  CAS  Google Scholar 

  • Ramesh A, Hasegawa H, Maki T, Ueda K (2007) Adsorption of inorganic and organic arsenic from aqueous solutions by polymeric Al/Fe modified montmorillonite. Sep Purif Technol 56(1):90–100

    Article  CAS  Google Scholar 

  • Ratanarat K, Nithitanakul M, Martin D, Magaraphan R (2003) Polymer-layer silicate nanocomposites: linear PEO and highly branched dendrimer for organic wastewater treatment. Rev Adv Mater Sci 5(3):187–192

    CAS  Google Scholar 

  • Rhim JW, Hong SI, Park HM, Ng PK (2006) Preparation and characterization of chitosan-based nanocomposite films with antimicrobial activity. J Agric Food Chem 54(16):5814–5822

    Article  CAS  PubMed  Google Scholar 

  • Rhim JW, Lee SB, Hong SI (2011) Preparation and characterization of agar/clay nanocomposite films: the effect of clay type. J Food Sci 76(3):21–28

    Article  CAS  Google Scholar 

  • Rivera-Jimenez SM, Lehner MM, Cabrera-Lafaurie WA, Hernández-Maldonado AJ (2011) Removal of naproxen salicylic acid clofibric acid and carbamazepine by water phase adsorption onto inorganic–organic-intercalated bentonites modified with transition metal cations. Environ Eng Sci 28(3):171–182

    Article  CAS  Google Scholar 

  • Setshedi KZ, Bhaumik M, Songwane S, Onyango MS, Maity A (2013) Exfoliated polypyrrole-organically modified montmorillonite clay nanocomposite as a potential adsorbent for Cr (VI) removal. Chem Eng J 222:186–197

    Article  CAS  Google Scholar 

  • Shabeer TA, Saha A, Gajbhiye V, Gupta S, Manjaiah K, Varghese E (2014) Simultaneous removal of multiple pesticides from water: effect of organically modified clays as coagulant aid and adsorbent in coagulation–flocculation process. Environ Technol 35(20):2619–2627

    Article  CAS  PubMed  Google Scholar 

  • Sharafi MM, Bazgir S, Tamizifar M, Nemati A (2010) Adsorption of petroleum hydrocarbons on organoclay

    Google Scholar 

  • Shirsath S, Hage A, Zhou M, Sonawane S, Ashokkumar M (2011) Ultrasound assisted preparation of nanoclay Bentonite-FeCo nanocomposite hybrid hydrogel: a potential responsive sorbent for removal of organic pollutant from water. Desalination 281:429–437

    Article  CAS  Google Scholar 

  • Shirzad-Siboni M, Khataee A, Hassani A, Karaca S (2015) Preparation characterization and application of a CTAB-modified nanoclay for the adsorption of an herbicide from aqueous solutions: kinetic and equilibrium studies. C R Chim 18(2):204–214

    Article  CAS  Google Scholar 

  • Shokri E, Yegani R, Pourabbas B, Kazemian N (2016) Preparation and characterization of polysulfone/organoclay adsorptive nanocomposite membrane for arsenic removal from contaminated water. Appl Clay Sci 132:611–620

    Article  CAS  Google Scholar 

  • Shu Z, Zhang Y, Yang Q, Yang H (2017) Halloysite nanotubes supported Ag and ZnO nanoparticles with synergistically enhanced antibacterial activity. Nanoscale Res Lett 12(1):135

    Article  PubMed  PubMed Central  CAS  Google Scholar 

  • Sohrabnezhad S, Moghaddam MM, Salavatiyan T (2014) Synthesis and characterization of CuO–montmorillonite nanocomposite by thermal decomposition method and antibacterial activity of nanocomposite. Spectrochim Acta Part A Mol Biomol Spectrosc 125:73–78

    Article  CAS  Google Scholar 

  • Sonawane S, Chaudhari P, Ghodke S, Ambade S, Gulig S, Mirikar A, Bane A (2008) Combined effect of ultrasound and nanoclay on adsorption of phenol. Ultrason Sonochem 15(6):1033–1037

    Article  CAS  PubMed  Google Scholar 

  • Sonawane S, Chaudhari P, Ghodke S, Phadtare S, Meshram S (2009) Ultrasound assisted adsorption of basic dye onto organically modified bentonite (nanoclay). J Sci Ind Res 68:162–167

    CAS  Google Scholar 

  • Sothornvit R, Rhim JW, Hong SI (2009) Effect of nano-clay type on the physical and antimicrobial properties of whey protein isolate/clay composite films. J Food Eng 91(3):468–473

    Article  CAS  Google Scholar 

  • Srinivasan R (2011) Advances in application of natural clay and its composites in removal of biological organic and inorganic contaminants from drinking water. Adv Mater Sci Eng 2011:872531

    Article  Google Scholar 

  • Taleb MFA, Hegazy DE, Ismail SA (2012) Radiation synthesis characterization and dye adsorption of alginate–organophilic montmorillonite nanocomposite. Carbohyd Polym 87(3):2263–2269

    Article  CAS  Google Scholar 

  • UÄŸurlu M, KaraoÄŸlu M (2011) TiO2 supported on sepiolite: preparation structural and thermal characterization and catalytic behaviour in photocatalytic treatment of phenol and lignin from olive mill wastewater. Chem Eng J 166(3):859–867

    Article  CAS  Google Scholar 

  • Ul-Islam M, Khan T, Khattak WA, Park JK (2013) Bacterial cellulose-MMTs nanoreinforced composite films: novel wound dressing material with antibacterial properties. Cellulose 20(2):589–596

    Article  CAS  Google Scholar 

  • Unuabonah EI, Taubert A (2014) Clay–polymer nanocomposites (CPNs): adsorbents of the future for water treatment. Appl Clay Sci 99:83–92

    Article  CAS  Google Scholar 

  • Unuabonah E, Olu-Owolabi B, Adebowale K, Yang L (2008) Removal of lead and cadmium ions from aqueous solution by polyvinyl alcohol-modified kaolinite clay: a novel nano-clay adsorbent. Adsor Sci Technol 26(6):383–405

    Article  CAS  Google Scholar 

  • Urbano BF, Rivas BL, Martinez F, Alexandratos SD (2012) Water-insoluble polymer–clay nanocomposite ion exchange resin based on N-methyl-d-glucamine ligand groups for arsenic removal. React Funct Polym 72(9):642–649

    Article  CAS  Google Scholar 

  • Wang L, Wang A (2007) Adsorption characteristics of Congo Red onto the chitosan/montmorillonite nanocomposite. J Hazard Mater 147(3):979–985

    Article  CAS  PubMed  Google Scholar 

  • Wang L, Zhang J, Wang A (2008a) Removal of methylene blue from aqueous solution using chitosan-g-poly (acrylic acid)/montmorillonite superadsorbent nanocomposite. Colloid Surf A Physicochem Eng Asp 322(1–3):47–53

    Article  CAS  Google Scholar 

  • Wang X, Du Y, Yang J, Tang Y, Luo J (2008b) Preparation characterization and antimicrobial activity of quaternized chitosan/organic montmorillonite nanocomposites. J Biomed Mater Res Part A 84(2):384–390

    Article  CAS  Google Scholar 

  • Wang MC, Lin JJ, Tseng HJ, Hsu SH (2011) Characterization antimicrobial activities and biocompatibility of organically modified clays and their nanocomposites with polyurethane. ACS Appl Mater Interfaces 4(1):338–350

    Article  PubMed  CAS  Google Scholar 

  • Wang X, Yang L, Zhang J, Wang C, Li Q (2014) Preparation and characterization of chitosan–poly (vinyl alcohol)/bentonite nanocomposites for adsorption of Hg (II) ions. Chem Eng J 251:404–412

    Article  CAS  Google Scholar 

  • Wang Z, Wang C, Wang P, Qian J, Hou J, Ao Y, Wu B (2015) The performance of chitosan/montmorillonite nanocomposite during the flocculation and floc storage processes of Microcystis aeruginosa cells. Environ Sci Poll Res 22(14):11148–11161

    Article  CAS  Google Scholar 

  • Xi Y, Mallavarapu M, Naidu R (2010) Preparation characterization of surfactants modified clay minerals and nitrate adsorption. Appl Clay Sci 48(1–2):92–96

    Article  CAS  Google Scholar 

  • Xie Y, Qian D, Wu D, Ma X (2011) Magnetic halloysite nanotubes/iron oxide composites for the adsorption of dyes. Chem Eng J 168(2):959–963

    Article  CAS  Google Scholar 

  • Yahyaei B, Azizian S, Mohammadzadeh A, Pajohi-Alamoti M (2014) Preparation of clay/alumina and clay/alumina/Ag nanoparticle composites for chemical and bacterial treatment of waste water. Chem Eng J 247:16–24

    Article  CAS  Google Scholar 

  • Yan L, Xu Y, Yu H, Xin X, Wei Q, Du B (2010) Adsorption of phosphate from aqueous solution by hydroxy-aluminum hydroxy-iron and hydroxy-iron–aluminum pillared bentonites. J Hazard Mater 179(1–3):244–250

    Article  CAS  PubMed  Google Scholar 

  • Yang Y, Han S, Fan Q, Ugbolue SC (2005) Nanoclay and modified nanoclay as sorbents for anionic cationic and nonionic dyes. Text Res J 75(8):622–627

    Article  CAS  Google Scholar 

  • Yao C, Xu Y, Kong Y, Liu W, Wang W, Wang Z, Ji J (2012) Polypyrrole/palygorskite nanocomposite: a new chromate collector. Appl Clay Sci 67:32–35

    Article  CAS  Google Scholar 

  • Yin J, Deng C, Yu Z, Wang X (2018) Effective removal of lead ions from aqueous solution using nano illite/smectite clay: isotherm kinetic and thermodynamic modeling of adsorption. Water 10(2):210

    Article  Google Scholar 

  • Yuan G, Wu L (2007) Allophane nanoclay for the removal of phosphorus in water and wastewater. Sci Technol Adv Mater 8(1–2):60–62

    Article  CAS  Google Scholar 

  • Yuan P, Fan M, Yang D, He H, Liu D, Yuan A, Chen T (2009) Montmorillonite-supported magnetite nanoparticles for the removal of hexavalent chromium [Cr (VI)] from aqueous solutions. J Hazard Mater 166(2–3):821–829

    Article  CAS  PubMed  Google Scholar 

  • Yuan P, Liu D, Fan M, Yang D, Zhu R, Ge F, He H (2010) Removal of hexavalent chromium [Cr (VI)] from aqueous solutions by the diatomite-supported/unsupported magnetite nanoparticles. J Hazard Mater 173(1–3):614–621

    Article  CAS  PubMed  Google Scholar 

  • Yuan L, Huang D, Guo W, Yang Q, Yu J (2011) TiO2/montmorillonite nanocomposite for removal of organic pollutant. Appl Clay Sci 53(2):272–278

    Article  CAS  Google Scholar 

  • Zhang J, Zhang Y, Chen Y, Du L, Zhang B, Zhang H, … Wang K (2012) Preparation and characterization of novel polyethersulfone hybrid ultrafiltration membranes bending with modified halloysite nanotubes loaded with silver nanoparticles. Industrial & engineering chemistry research, 51(7):3081–3090

    Article  CAS  Google Scholar 

  • Zang L, Qiu J, Yang C, Sakai E (2016) Preparation and application of conducting polymer/Ag/clay composite nanoparticles formed by in situ UV-induced dispersion polymerization. Sci Rep 6:204–211

    Google Scholar 

  • Zhou Q, Gao Q, Luo W, Yan C, Ji Z, Duan P (2015) One-step synthesis of amino-functionalized attapulgite clay nanoparticles adsorbent by hydrothermal carbonization of chitosan for removal of methylene blue from wastewater. Colloid Surf A Physicochem Eng Asp 470:248–257

    Article  CAS  Google Scholar 

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Fareed, F., Ibrar, M., Ayub, Y., Nazir, R., Tahir, L. (2019). Clay-Based Nanocomposites: Potential Materials for Water Treatment Applications. In: Prasad, R., Karchiyappan, T. (eds) Advanced Research in Nanosciences for Water Technology. Nanotechnology in the Life Sciences. Springer, Cham. https://doi.org/10.1007/978-3-030-02381-2_10

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