Abstract
Structural, electronic, dynamic and chemical characteristics of materials depend primarily on the state (phase) and degree (size) of aggregation. Small clusters often exhibit unique physical and chemical phenomena, of both fundamental and technological significance, and provide the opportunity for exploration of the transition from molecular to condensed matter systems. Particularly, investigations of the correlations between physical properties and degree of aggregation allow elucidation of the development of collective phenomena responsible for phase transformations1,2 (such as nucleation, melting, and structural transitions), studies of the excitation dynamics and the kinetics of reactive processes3,4 (such as fragmentation) and of the energetics and dynamics of electron attachment,5,6 solvation phenomena7 and physical processes induced by electron attachment.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
J. Jellinek, T. L. Beck and R. S. Berry, J. Chem. Phys. 84, 2783 (1983) and references therein.
J. Luo, U. Landman and J. Jortner, these proceedings.
D. Scharf, J. Jortner and U. Landman, Chem. Phys. Letts. 126, 495 (1986).
J. Jortner, Ber. Bunsenges. Physik. Chem. 88, 188 (1984).
U. Landman, D. Scharf, and J. Jortner, Phys. Rev. Letts. 54, 1860 (1985).
T. D. Mark and A. W. Castleman Jr. in Adv. Atomic and Mol. Phys. (D. R. Bates and B. Bederson, Eds.), Vol. 20 (1984).
See papers in J. Phys. Chem. 88 (1984).
F. F. Abraham, J. Vac. Sci. Technol. B2, 534 (1984).
U. Landman et al., Mat. Res. Soc. Symp. Proc. Vol. 63, 273 (1985).
See papers in Ber. Bunsenges. Physik. Chem. 88, 188 (1984).
H. Haberland, Surf. Sci. 156, 305 (1985);
J. J. Saenz, J. M. Soler and N. Garcia, Surf. Sci. 156, 121 (1985).
J. W. Brady and J. D. Doll, J. Chem. Phys. 73, 2767 (1980).
J. Jortner, E. E. Koch and N. Schwentner in: Photo-Physics and Photochemistry in the Vacuum UV, S. P. McGlynn et al., Eds., (Reidel, Dordrecht, 1985), p. 515.
W. D. Kristensen, E. J. Jensen and M. J. Cotterill, J. Chem. Phys. 60, 4161 (1974).
I. Messing, B. Raz and J. Jortner, J. Chem. Phys. 66, 2239 (1977).
A. E. Sherwood and J. M. Prasunitz, J. Chem. Phys. 41, 429 (1964).
K. T. Gillen, R. P. Saxon, D. C. Lorentz, G. E. Ice and R. E. Olson, J. Chem. Phys. 64, 1925 (1975).
D. Scharf, U. Landman and J. Jortner (to be published).
T. P. Martin, Phys. Rep. 95, 167 (1983).
F. G. Fumi and M. P. Tosi, J. Phys. Chem. Solids 25, 31, 45 (1964).
R. W. Shaw, Phys. Rev. 174, 769 (1968); see also QUPID Studies of e- +Na+ and (NaCl)- in D. Scharf, J. Jortner and U. Landman (Chem. Phys. Letts. 1986, in press).
M. Parrinello and A. Rahman, J. Chem. Phys. 80, 860 (1984).
D. Chandler and P. G. Wolynes, J. Chem. Phys. 79, 4078 (1981).
B. De Raedt, H. Sprik and H. L. Klein, J. Chem. Phys. 80, 5719 (1984).
D. Chandler, J. Phys. Chem. 88, 3400 (1984).
R. P. Feynman and A. R. Hibbs, Quantum Mechanics and Path Integrals (McGraw-Hill, New York, 1965).
M. F. Herman, E. J. Bruskin and B. J. Berne, J. Chem. Phys. 76, 5150 (1982).
A. L. Nichols, D. Chandler, V. Singh and D. M. Richardson, J. Chem. Phys. 81, 5109 (1984).
B. J. Berne and D. Thirumalai, in Ann. Rev. Phys. Chem. (to appear, 1986).
J. R. Fox and H. C. Anderson, J. Phys. Chem. 88, 4019 (1984).
U. Landman, R. N. Barnett, C. L. Cleveland and P. Norlander, in “Tunneling”, Eds. J. Jortner and B. Pullman (Reidel, 1986).
J. Phys. Chem. 88, 3699–3914 (1984); Electrons in Fluids, J. Jortner and P. N. Kestner, Eds. (Springer, N. Y., 1973).
H. Haberland, H. G. Schindler and D. R. Worsnop, Ber. Bunsenges, Chem. 88, 270 (1984);
H. Haberland, H. G. Schindler and D. R. Worsnop, J. Phys. Chem. 88, 3903 (1984);
H. Haberland, H. G. Schindler and D. R. Worsnop, J. Chem. Phys. 81, 3742 (1984).
J. V. Coe, D. R. Worsnop and K. H. Bowen (J. Chem. Phys., 1986).
B. K. Rao and N. R. Kestner, J. Chem. Phys. 80, 1587 (1984) and references therein.
M. Sprik, R. W. Impey and M. L. Klein, J. Chem. Phys. 83, 5802 (1985).
C.D. Jonah, C. Romero and A. Rahman, Chem. Phys. Lett. 123, 209 (1986).
A. Wallquist, D. Thirumalai and B. J. Berne, J. Chem. Phys. 85, 1583 (1986).
J. R. Reimers, R. O. Watts and M. L. Klein, Chem. Phys. 64, 95 (1982).
J. R. Reimers and R. D. Watts, Chem. Phys. 85, 83 (1984). This paper as well as the description of the potential in ref. 39 (Eq. 13 and Table 1) contain several ambiguities and typographical errors. When corrected we reproduce their results.
J. N. Bardsley, case studies in Atomic Physics 4, 299 (1974);
G. G. Kleiman and U. Landman, Phys. Rev. B8, 5484 (1973).
C. W. Kerr and M. Karplus in Water, F. Franks, ed., (Plenum, N. Y., 1972), p. 21;
M. W. Ribarsky, W. D. Luedtke and U. Landman, Phys. Rev. B32, 1430 (1985).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1987 Plenum Press, New York
About this chapter
Cite this chapter
Landman, U., Barnett, R.N., Cleveland, C.L., Scharf, D., Jortner, J. (1987). Electron Localization and Excitation Dynamics in Small Clusters. In: Jena, P., Rao, B.K., Khanna, S.N. (eds) Physics and Chemistry of Small Clusters. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0357-3_26
Download citation
DOI: https://doi.org/10.1007/978-1-4757-0357-3_26
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4757-0359-7
Online ISBN: 978-1-4757-0357-3
eBook Packages: Springer Book Archive