Summary
Regional studies of Devonian and Mississippian carbonate sequences in Montana and Idaho illustrate the ability of meteoric water to alter early near-surface dolomite. Early precursor dolomites in these rocks formed in various near-surface settings, such as evaporitic tidal flats, shallow subsurface reflux environments, and subtidal marine environments on broad carbonate platforms that extended across the study area. The best preserved early dolomites, or their remnants, typically are nonstoichiometric, isotopically heavy, and trace element enriched. The early dolomites also generally predate compaction or early calcite cements and exhibit zoned to irregular cathodoluminescence (CL) patterns.
However, many of these early dolomites apparently were altered by meteoric fluids in shallow subsurface environments (0 to 300 m burial depth). Petrographic techniques (transmitted light, CL, and backscattered electron imaging) may define the alteration microfabrics, which include extensive dissolution porosity (both intracrystalline and intercrystalline), “dedolomitization,” and blotchy to homogeneous CL. Highly altered dolomites occur closest to recharge surfaces, typically are the most stoichiometric, and have the most negative δ 18O values. Another geochemical trend, which may indicate near-surface alteration of dolomites by meteoric waters, is the development of depleted cerium contents (“negative Ce anomaly”). The negative Ce anomaly may develop because Ce4+ is preferentially scavenged and incorporated into authigenic Fe-Mn oxyhydroxides in oxidizing near-surface diagenetic environments and, therefore, is not available for incorporation into the meteoric dolomite.
Retention of fabrics and geochemical signatures that are closest to those of the precursor dolomite are more common in downflow regions, far from recharge surfaces. In downflow portions of paleoaquifers, groundwaters most likely were saturated with respect to dolomite because of extensive dolomite dissolution updip. Early, pore-filling calcite cements in downflow regions also may seal off porosity, thus preventing reaction of precursor dolomites with later meteoric waters.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Back, W. and B.B. Hanshaw, 1970. Comparison of chemical hydrology of the carbonate peninsulas of Florida and Yucatan. Journal of Hydrology, v. 10, p. 330–368.
Back, W., B.B. Hanshaw, L.N. Plummer, P.H. Rahn, C.T. Rightmire, and M. Rubin, 1983. Process and rate of dedolomitization: Mass transfer and 14C dating in a regional carbonate aquifer. Geological Society of America Bulletin, v. 94, p. 1415–1429.
Banner, J.L. and G.N. Hanson, 1990. Calculation of simultaneous isotopic and trace element variations during water-rock interaction with applications to carbonate diagenesis. Geochimica et Cosmochimica Acta, v. 54, p. 3123–3137.
Banner, J.L., G.N. Hanson, and W.J. Meyers, 1988a. Water-rock interaction history of regionally extensive dolomites of the Burlington-Keokuk Formation (Mississippian): isotopic evidence. In: Shukla, V. and P.A. Baker (eds.), Sedimentology and Geochemistry of Dolostones. Society of Economic Paleontologists and Mineralogists Special Publication, v. 43, p. 97–113.
Banner, J.L., G.N. Hanson, and W.J. Meyers, 1988b. Rare earth element and Nd isotopic variations in regionally extensive dolomites from the Burlington-Keokuk Formation (Mississippian): implications for REE mobility during carbonate diagenesis. Journal of Sedimentary Petrology, v. 58, p. 415–432.
Bridges, L.W.D., 1982. Rocky Mountain Laramide-Tertiary subsurface solution vs. Paleozoic karst in Mississippian carbonates. Thirty-third Annual Field Conference, Wyoming Geological Association Guidebook, p. 251–264.
DeBaar, H.J.W., M.P. Bacon, and P.G. Brewer, 1983. Rare earth distributions with a positive Ce anomaly in the Western North Atlantic Ocean. Nature, v. 301, p. 324–327.
DeBaar, H.J.W., M.P. Bacon, P.G. Brewer, and K.W. Bruland, 1985. Rare earth elements in the Pacific and Atlantic Oceans. Geochimica et Cosmochimica Acta, v. 49, p. 1943–1959.
Deike, R.G., 1990. Dolomite dissolution rates and possible Holocene dedolomitization of water-bearing units in the Edwards aquifer, South-central Texas. Journal of Hydrology, v. 112, p. 335–373.
Dorobek, S.L. and R.H. Filby, 1988. Origin of dolomites in a platform margin biostrome, Jefferson Formation (Frasnian), Central Idaho: Evidence from REE patterns, stable isotopes, and petrography. Bulletin of Canadian Petroleum Geology, v. 36, p. 202–215.
Dorobek, S.L., S.K. Reid, and T.M. Smith, 1988. Early carbonate cements in the Mission Canyon Formation (Lower Mississippian), central and southwestern Montana. Annual Midyear Meeting, Society of Economic Paleontologists and Mineralogists, Programs with Abstracts, v. V, p. 15.
Dorobek, S.L., S.K. Reid, and M. Elrick, 1991. Foreland response to episodic Antler convergence events, Devonian-Mississippian stratigraphy of Montana and Idaho: effects of horizontal and vertical loads. In: Cooper, J.D. and C.H. Stevens (eds.), Paleozoic Paleogeography of the Western United States II: Pacific Section Society of Economic Paleontologists and Mineralogists, v. 67, p. 487–508.
Dover, J.H., 1980. Status of the Antler orogeny in central Idaho-Clarification and constraints from the Pioneer Mountains. In: Fouch, T.D. and E.R. Magathan (eds.), Paleozoic Paleogeography of the West-Central United States. Society of Economic Paleontologists and Mineralogists, Rocky Mountain Section, Rocky Mountains Paleogeography Symposium, v. 1, p. 371–386.
Dunham, R.J., 1969. Early vadose silt in Townsend mound (reef), New Mexico. In: Friedman, G.M. (ed.), Depositional Environments in Carbonate Rocks. Society of Economic Paleontologists and Mineralogists Special Publication, v. 14, p. 139–181.
Elderfield, H. and M.J. Greaves, 1982. The rare earth elements in seawater. Nature, v. 296, p. 214–219.
Elderfield, H., C.J. Hawkesworth, M.J. Greaves, and S.E. Calvert, 1981. Rare earth element geochemistry of oceanic ferromanganese nodules and associated sediments. Geochimica et Cosmochimica Acta, v. 45, p. 513–528.
Fanning, K.A., R.H. Byrne, J.A. Breland II, P.R. Betzer, W.S. Moore, R.J. Elsinger, and T.E. Pyle, 1981. Geothermal springs of the west Florida continental shelf: evidence for dolomitization and radionuclide enrichment. Earth and Planetary Science Letters, v. 52, p. 345–354.
Fleet, A.J., 1984. Aqueous and sedimentary geochemistry of the rare earth elements. In: Henderson, P. (ed.), Rare Earth Element Geochemistry. Elsevier, New York, p. 343–373.
Gao, G., 1990. Geochemical and isotopic constraints on the diagenetic history of a massive stratal, late Cambrian (Royer) dolomite, Lower Arbuckle Group, Slick Hills, SW Oklahoma, USA. Geochimica et Cosmochimica Acta, v. 54, p. 1979–1989.
Gonzales, L.A. and K.C. Lohmann, 1988. Controls on mineralogy and composition of spelean carbonates: Carlsbad Caverns, New Mexico. In: James, N.P. and P.W. Choquette (eds.), Paleokarst. Springer-Verlag, New York, p. 81–101.
Gregg, J.M. and D.F. Sibley, 1984. Epigenetic dolomitization and the origin of xenotopic dolomite texture. Journal of Sedimentary Petrology, v. 54, p. 908–931.
Gutschick, R.C., C.A. Sandberg, and W.J. Sando, 1980. Mississippian shelf margin and carbonate platform from Montana to Nevada. In: Fouch, T.D. and E.R. Magathan (eds.), Paleozoic Paleogeography of the West-Central United States. Society of Economic Paleontologists and Mineralogists, Rocky Mountain Section, West-central United States Paleogeography Symposium, v. 1, p. 111–128.
Hardie, L.A., 1987. Dolomitization: A critical view of some current views. Journal of Sedimentary Petrology, v. 57, p. 166–183.
Harris, A.G., 1979. Conodont color alteration, an organo-mineral metamorphic index, and its application to Appalachian Basin geology. In: Scholle, P.A. and P.R. Schluger (eds.), Aspects of Diagenesis. Society of Economic Paleontologists and Mineralogists Special Publication, v. 26, p. 3–16.
Heckel, P.H., 1983. Diagenetic model for carbonate rocks in Midcontinent Pennsylvanian eustatic cyclothems. Journal of Sedimentary Petrology, v. 53, p. 733–760.
Henderson, P., 1984. General geochemical properties and abundances of the rare earth elements. In: Henderson, P. (ed.), Rare Earth Element Geochemistry. Elsevier, New York, p. 1–32.
Holail, H., K.C. Lohmann, and I. Sanderson, 1988. Dolomitization and dedolomitization of Upper Cretaceous carbonates: Bahariya Oasis, Egypt. In: Shukla, V. and P.A. Baker (eds.), Sedimentology and Geochemistry of Dolostones. Society of Economic Paleontologists and Mineralogists Special Publication, v. 43, p. 191–207.
Isaacson, P.E. and S.L. Dorobek, 1988. Regional significance and interpretation of a coral-stromatoporoid carbonate buildup succession, Jefferson Formation (Upper Devonian), east-central Idaho. In: McMillan, N.J., A.F. Embry, and D.J. Glass (eds.), Devonian of the World. Canadian Society of Petroleum Geologists Memoir 14, Volume II, p. 581–589.
Johnson, J.C., G. Klapper, and C.A. Sandberg, 1985. Devonian eustatic fluctuations in Euramerica. Geological Society of America Bulletin, v. 96, p. 567–587.
Kerans, C., N.F. Hurley, and P.E. Playford, 1986. Marine diagenesis in Devonian reef complexes of the Canning Basin, Western Australia. In: Schroeder, J.H. and B.H. Purser (eds.), Reef Diagenesis. Springer-Verlag, New York, p. 357–380.
Kohout, F.A., 1967. Ground-water flow and the geothermal regime of the Floridian Plateau. Transactions Gulf Coast Association of Geological Societies, v. 17, p. 339–354.
Land, L.S., 1980. The isotopic and trace element geochemistry of dolomite: The state of the art. In: Zenger, D.H., J.B. Dunham, and R.L. Ethington (eds.), Concepts and Models of Dolomitization. Society of Economic Paleontologists and Mineralogists Special Publication, v. 28, p. 87–110.
Land, L.S., 1985. The origin of massive dolomite. Journal of Geological Education, v. 33, p. 112–125.
Land, L.S., 1989. Dolomitization and dolomite recrystallization, Hope Gate Formation, north Jamaica: reassessment of mixing-zone dolomite. Geological Society of America Abstracts with Programs, v. 21, p. A220 - A221.
Langmuir, D., 1971. The geochemistry of some carbonate ground waters in central Pennsylvania. Geochimica et Cosmochimica Acta, v. 35, p. 1023–1045.
Lohmann, K.C., 1988. Geochemical patterns of meteoric diagenetic systems and their application to studies of paleokarst. In: James, N.P. and P.W. Choquette (eds.), Paleokarst. Springer-Verlag, New York, p. 58–80.
Machel, H.-G., 1985. Cathodoluminescence in calcite and dolomite and its chemical interpretation. Geoscience Canada, v. 12, p. 139–147.
Machel, H.-G., 1986. Early lithification, dolomitization, and anhydritization of Upper Devonian Nisku buildups, subsurface of Alberta, Canada. In: Schroeder, J.H. and B.H. Purser (eds.), Reef Diagenesis. Springer-Verlag, New York, p. 336–356.
Marsaglia, K.M. and G.deV. Klein, 1983. The paleogeography of Paleozoic and Mesozoic storm depositional systems. Journal of Geology, v. 91, p. 117–142.
Mazzullo, S.J., 1981. Facies and burial diagenesis of a carbonate reservoir: Chapman deep (Atoka) field, Delaware basin, Texas. American Association of Petroleum Geologists Bulletin, v. 65, p. 850–865.
Meyers, W.J., 1988. Paleokarstic features on Mississippian limestones, New Mexico. In: James, N.P. and P.W. Choquette (eds.), Paleokarst. Springer-Verlag, New York, p. 306–328.
Meyers, W.J. and K.C. Lohmann, 1985. Isotope geochemistry of regionally extensive calcite cement zones and marine components in Mississippian limestones, New Mexico. In: Schneidermann, N. and P.M. Harris (eds.), Carbonate Cements. Society of Economic Paleontologists and Mineralogists Special Publication, v. 36, p. 223–239.
Middleton, G.V., 1961. Evaporite solution breccias from the Mississippian of southwest Montana. Journal of Sedimentary Petrology, v. 31, p. 189–195.
Moore, C.H., A. Chowdhury, and L. Chan, 1988. Upper Jurassic Smackover platform dolomitization, northwestern Gulf of Mexico: a tale of two waters. In: Shukla, V. and P.A. Baker (eds.), Sedimentology and Geochemistry of Dolostones. Society of Economic Paleontologists and Mineralogists Special Publication, v. 43, p. 175–189.
Mudge, M.R., 1972. Pre-Quaternary rocks in the Sun River Canyon area, northwestern Montana. U.S. Geological Survey Professional Paper 663-A, 142 p.
Nichols, K.M., 1980. Depositional and diagenetic history of porous dolomitized grainstones at the top of the Madison Group, Disturbed Belt, Montana. In: Fouch, T.D. and E.R. Magathan (eds.), Paleozoic Paleogeography of the West-Central United States. Society of Economic Paleontologists and Mineralogists, Rocky Mountain Section, Rocky Mountain Paleogeography Symposium, v. 1, p. 163–173.
Nichols, K.M., 1984. Stratigraphy of the upper part of the Madison Group, Sawtooth Range, northwestern Montana. In: McBane, J.D. and P.B. Garrison (eds.), Montana Geological Society, 1984 Field Conference, p. 127–140.
Nichols, K.M., 1986. Regional significance of lithologic correlation of Mississippian rocks at Pentagon Mountain and the Sawtooth Range, northwestern Montana. U.S. Geological Survey Open File Report 86–84, 1 sheet.
Peterson, J.A., 1981. General stratigraphy and paleostructure of the western Montana Overthrust Belt. Montana Geological Society Field Conference, Southwest Montana, p. 5–35.
Pierson, B.J., 1981. The control of cathodoluminescence in dolomite by iron and manganese. Sedimentology, v. 28, p. 601–610.
Piper, D.Z., 1974. Rare earth elements in the sedimentary cycle: A summary. Chemical Geology, v. 14, p. 285–304.
Popp, B.N., T.F. Anderson, and P.A. Sandberg, 1986. Brachiopods as indicators of original isotopic compositions of some Paleozoic limestones. Geological Society of America Bulletin, v. 97, p. 1262–1269.
Reeder, R.J. and J.L. Prosky, 1986. Compositional sector zoning in dolomite. Journal of Sedimentary Petrology, v. 56, p. 237–247.
Reid, S.K. and S.L. Dorobek, 1989. Application of sequence stratigraphy in the Mississippian Mission Canyon Formation and stratigraphie equivalents, southwestern Montana and east-central Idaho. In: French, D.E. and R.F. Grabb (eds.), 1989 Field Conference Guidebook. Montana Centennial Edition, Geologic Resources of Montana, v. 1, p. 47–53.
Reid, S.K. and S.L. Dorobek, 1991. Controls on development of third-and fourth-order depositional sequences in the Lower Mississippian Mission Canyon Formation and stratigraphie equivalents, Idaho and Montana. In: Cooper, J.D. and C.H. Stevens (eds.), Paleozoic Paleogeography of the Western United States II: Pacific Section Society of Economic Paleontologists and Mineralogists, v. 67, p. 527–542.
Roberts, A.E., 1966. Stratigraphy of Madison Group near Livingston, Montana, and discussion of karst and solution-breccia features. U.S. Geological Survey Professional Paper 526-B, 23 p.
Ross, C.P., 1937. Geology and ore deposits of the Bayhorse region, Custer County, Idaho. U.S. Geological Survey Bulletin 877, 161 p.
Ruppel, E.T. and D.A. Lopez, 1984. The thrust belt in southwest Montana and east-central Idaho. U.S. Geological Survey Professional Paper 1278, 41 p.
Sandberg, C.A., R.C. Gutschick, J.G. Johnson, F.G. Poole, and W.J. Sando, 1983. Middle Devonian to Late Mississippian geologic history of the Overthrust Belt region, western United States. In: Powers, R.B. (ed.), Geologic Studies of the Cordilleran Thrust Belt, Rocky Mountain Association of Geologists, v. 2, p. 691–719.
Sando, W.J., 1974. Ancient solution phenomena in the Madison Limestone (Mississippian) of north-central Wyoming. Geological Society of America Bulletin, v. 2, p. 133–141.
Sando, W.J., 1976. Mississippian history of the northern Rocky Mountains Region: United States Geological Survey Journal of Research, v. 4, p. 317–338.
Sando, W.J., 1988. Madison Limestone (Mississippian) paleokarst: A geologic synthesis. In: James, N.P. and P.W. Choquette (eds.), Paleokarst. Springer-Verlag, New York, p. 256–277.
Sando, W.J., C.A. Sandberg, and W.J. Perry, Jr., 1985. Revision of Mississippian Stratigraphy, Northern Tendoy Mountains, southwest Montana. In: Sando, W.J. (ed.), Mississippian and Pennsylvanian Stratigraphy in Southwest Montana and Adjacent Idaho. United States Geological Survey Bulletin 1657, p. Al-A10.
Shaw, H.F. and G.J. Wasserburg, 1985. Sm-Nd in marine carbonates and phosphates: Implications for Nd isotopes in seawater and crustal ages. Geochimica et Cosmochimica Acta, v. 49, p. 503–518.
Sibley, D.F. and J.M. Gregg, 1987. Classification of dolomite rock textures. Journal of Sedimentary Petrology, v. 57, p. 967–975.
Simms, M., 1984. Dolomitization by groundwater-flow systems in carbonate platforms. Transactions Gulf Coast Association of Geological Societies, v. 34, p. 411–420.
Skipp, B., W.J. Sando, and W.E. Hall, 1979. The Mississippian and Pennsylvanian (Carboniferous) Systems in the United States—Idaho. United States Geological Survey Professional Paper 1110-AA, 42 p.
Smith, T.M. and S.L. Dorobek, 1989. Dolomitization of the Devonian Jefferson Formation in south-central Montana. Mountain Geologist, v. 26, p. 81–96.
Smith, T.M. and S.L. Dorobek, 1990. Meteoric calcite cements from the Mission Canyon Formation, Montana. Geological Society of America Abstracts with Programs, v. 22, p. A335.
Sperber, C.M., B.H. Wilkinson, and D.R. Peacor, 1984. Rock composition, dolomite stoichiometry, and rock/water reactions in dolomitic carbonate rocks. Journal of Geology, v. 92, p. 609–622.
Stanley, S.M., 1989. Earth and Life Through Time, Second Edition. W.H. Freeman and Co., New York, 689 p.
Ward, W.B. and R.J. Reeder, 1990. The use of growth microfabrics and TEM in understanding replacement processes in carbonates. Carbonate Microfabrics Symposium and Workshop, Texas A0026M University, College Station, TX, Abstracts Volume 31.
Whitsitt, P.M., 1989. Shallow meteoric alteration and burial diagenesis of massive dolomite in the Castle Reef Formation, northwest Montana. Unpublished M.S. thesis, Texas A0026M University, College Station, TX, 61 p.
Wright, J., R.S. Seymour, and H.F. Shaw, 1984. REE and Nd isotopes in conodont apatite: Variations with geological age and depositional environment. Geological Society of America Special Paper 196, p. 325–340.
Wright, J., 1985. Rare earth element distributions in Recent and fossil apatite: Implications for paleoceanography and stratigraphy. Unpublished Ph.D. Dissertation, University of Oregon, Eugene, 259 p.
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1993 Springer-Verlag New York, Inc.
About this chapter
Cite this chapter
Dorobek, S.L., Smith, T.M., Whitsitt, P.M. (1993). Microfabrics and Geochemistry of Meteorically Altered Dolomite in Devonian and Mississippian Carbonates, Montana and Idaho. In: Rezak, R., Lavoie, D.L. (eds) Carbonate Microfabrics. Frontiers in Sedimentary Geology. Springer, New York, NY. https://doi.org/10.1007/978-1-4684-9421-1_16
Download citation
DOI: https://doi.org/10.1007/978-1-4684-9421-1_16
Publisher Name: Springer, New York, NY
Print ISBN: 978-1-4684-9423-5
Online ISBN: 978-1-4684-9421-1
eBook Packages: Springer Book Archive