Abstract
The enormous experimental and theoretical effort on high-temperature copper-oxide-based superconductors began with the La-Ba-Cu-O system [1], shifted to the Y-Ba-Cu-O system [2], and recently has focused on the Bi-Ca-Sr-Cu-O [3] and Tl-Ca-Ba-Cu-O [4] systems. Tl-Ca-Ba-Cu-O ceramics have zero resistance and Meissner effect up to 125 K [5,6], and exhibit at least five structurally distinct superconducting phases.[7–10] Two common phases, Tl2Ca2Ba2Cu3Ox (Tl-2223 with a c-axis of 35.9 Å) and Tl2CaBa2Cu2Oy (T1-2122, c = 29.3 Å), contain double T1-O planes sandwiched by Ba-O sheets and blocks of double (T1-2122) or triple (T1-2223) Cu-O planes separated by intermediate Ca layers.
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Venturini, E.L., Kwak, J.F., Ginley, D.S., Morosin, B., Baughman, R.J. (1989). Magnetization, Flux Creep and Transport in Tl-Ca-Ba-Cu-O Thin Films. In: McConnell, R.D., Wolf, S.A. (eds) Science and Technology of Thin Film Superconductors. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-5658-5_47
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DOI: https://doi.org/10.1007/978-1-4684-5658-5_47
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