Abstract
Clay minerals and zeolites are the typical host-guest systems occurring in nature. Hydrate clathrates are deposited under extreme conditions such as those in the Arctic regions or deep seabed; melanophlogite is an exceptional clathrate mineral comprised of silica as the host and some organic molecules as the guest with the structure similar to that of the hydrate clathrate. These inclusion systems found in nature have the host structures built of the tetrahedral centers such as silicon or oxygen atoms and the bridging moieties such as -O- or O-H…O linkages. The structural features characteristic of the natural inclusion systems can be mimicked using cadmium cyanide systems.
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Iwamoto, T., Kitazawa, T., Nishikiori, Si., Kuroda, R. (1993). Mineralomimetic Inclusion Behavior of Cadmium Cyanide Systems. In: Bernier, P., Fischer, J.E., Roth, S., Solin, S.A. (eds) Chemical Physics of Intercalation II. NATO ASI Series, vol 305. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-2850-0_32
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DOI: https://doi.org/10.1007/978-1-4615-2850-0_32
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