Abstract
The clathrate compounds of the title three-dimensional metal complex hosts have been prepared with various aliphatic, alicyclic, and aromatic guest molecules. The typical structure has been demonstrated for a cyclohexane clathrate (N-methyl-1,3-diaminopropane)cadmium(II) tetracyanonickelate(II)-cyclohexane(2/1) by X-ray single crystal analysis. The powder X-ray diffraction data were assigned for the other clathrates to the tetragonal systems isostructural to the cyclohexane clathrate in which the box-like cavity with the approximate dimensions of 7 × 7 × 5 Å3 accommodates the guest molecule.
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Nishikiori, S., Takahashi-Ebisudani, Y. & Iwamoto, T. Novel series of clathrate compounds of the three-dimensional metal complex hosts (N-methyl-1,3-diaminopropane)cadmium(II) tetracyanonickelate(II), (N, N-Dimethyl-1,3-diaminopropane)cadmium(II) Tetracyanonickelate(II), and (2-Hydroxyethylmethylamine) cadmium(II) Tetracyanonickelate(II). J Incl Phenom Macrocycl Chem 9, 101–112 (1990). https://doi.org/10.1007/BF01041254
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DOI: https://doi.org/10.1007/BF01041254