Skip to main content

Production and Analysis of Chlorine Dioxide

Reference chapter: 10

  • Chapter
Environmental Chemistry

Abstract

After performing this experiment, the student shall be able to:

  • Produce a relatively uncommon, environmentally friendly, oxidizing and disinfecting gas.

  • Visualize an application of Frost diagrams.

  • Perform a disproportionation reaction.

  • Produce the same substance by different paths (i.e., oxidation, reduction and disproportionation).

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature References

  • ERCO Worldwide. http://clo2.com/index.html

    Google Scholar 

  • Esposito, A.P.; Stedl, T.; Jonsson, H.; Reid, P. J.; Peterson, K. A. “Absorption and Resonance Raman Study of the 2B1(X) − 2A2(A) Transition of Chlorine Dioxide in the Gas Phase,” J. Phys. Chem. A, 1999, 103, 1748–1757.

    Article  CAS  Google Scholar 

  • Green, T. J.; Islam, M.; Canosa-Mas, C.; Marston, G.; Wayne, R. P. “Higher Oxides of Chlorine: Absorption Cross-sections of C12O6 and Cl2O4, the Decomposition of Cl2O6, and the Reactions of 0ClO with O and O3,” J. Photochem. Photobiol. A: Chemistry 2004, 162, 353–370.

    Article  CAS  Google Scholar 

  • Ibanez, J. G.; Navarro-Monsivais, C.; Terrazas-Moreno, S.; Mena-Brito, R.; Pedraza-Segura, L. Mattson, B.; Anderson, M. P.; Fujita, J.; Hoette, T. “Microscale Environmental Chemistry, Part 5. Production of ClO2, an Environmentally-Friendly Oxidizer and Disinfectant,” Chem. Educ. 2006, 11, 174–177.

    CAS  Google Scholar 

  • McKetta, J. Inorganic Chemicals Handbook. Vol. 2, “Chlorine Dioxide”; Marcel Dekker: New York, 1993. pp. 779–810.

    Google Scholar 

  • Oikawa, K.; Hayashi, Y. “Method for Preparing Stabilized Aqueous Chlorine Dioxide Solution,” U.S. Patent 5,165,910 (Nov. 24, 1992).

    Google Scholar 

  • Paddon, C. A.; Atobe, M.; Fuchigami, T.; He, P.; Watts, P.; Haswell, S. J.; Pritchard, G. J.; Bull, S. D.; Marken, F. “Towards Paired and Coupled Electrode Reactions for Clean Organic Microreactor Electrosyntheses,” J. Appl. Electrochem. 2006, 36, 617–634.

    Article  CAS  Google Scholar 

  • Rajeshwar, K.; Ibanez, J.G. Environmental Electrochemistry: Fundamentals and Applications in Pollution Abatement: Academic Press: San Diego, 1997. Chapter 7.

    Google Scholar 

  • Roozdar, H. “Method and Compositions for the Production of Chlorine Dioxide,” U.S. Patent 5,651,996. (Jul. 29, 1997).

    Google Scholar 

  • Rosenblatt, A.; Rosenblatt, D. H.; Feldman, D.; Knapp, J. E.; Battisti, D.; Morsi, B. “Method and Apparatus for Chlorine Dioxide Manufacture,” U.S. Patent 5,234,678 (Aug. 10, 1993).

    Google Scholar 

  • Sokol, J. C. “Process for Continuously Producing Chlorine Dioxide,” U.S. Patent 5,380,517 (Jan. 10, 1995).

    Google Scholar 

  • Svenson, D. R.; Kadla, J. F; Chang, H-M.; Jameel, H. “Effect of pH on the Inorganic Species Involved in a Chlorine Dioxide Reaction System,” Ind. Eng. Chem. Res. 2002, 41, 5927–5933.

    Article  CAS  Google Scholar 

  • Yin, G.; Ni, Y. “Mechanism of the ClO2 Generation from the H2O2-HClO3 Reaction,” Can. J. Chem. Eng. 2000, 78, 827–833.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 2008 Springer Science+Business Media, LLC

About this chapter

Cite this chapter

Ibanez, J.G., Hernandez-Esparza, M., Doria-Serrano, C., Fregoso-Infante, A., Singh, M.M. (2008). Production and Analysis of Chlorine Dioxide. In: Environmental Chemistry. Springer, New York, NY. https://doi.org/10.1007/978-0-387-49493-7_19

Download citation

Publish with us

Policies and ethics