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Abstract

Electrically conductive adhesives are being used in electronic packaging for several decades. A brief review of the dynamic development of conductive adhesives under the influence of the miniaturization, the adaptation of environmental friendly manufacturing processes is presented.

With respect to the importance of isotropically conductive adhesives (ICA), a new contact model to analyze the principle influences of e.g., particle size, particle geometry, and filler content on the percolation threshold is introduced. With this model the arrangement of the particles within a contact is calculated by considering different types of forces (elastic, friction, adhesion, and inertia). Taking into account the electrical properties of the filler particles, the electrical contact behavior including its changes due to aging is investigated.

Finally, typical applications of isotropically conductive adhesives are presented. One example shows how the thermal requirements for attaching a GaAs heterojunction power transistor can be fulfilled using an adhesive with an extremely high filler content (thermal conductivity: >60 W/mK). In another case it is demonstrated how extreme thermomechanical requirements resulting from a thermal expansion mismatch of parts of a sealed IR sensor housing can be corresponded using an adhesive with a comparatively low glass transition temperature. A further example shows a packaging concept of a miniaturized, biocompatible multichip module. For mounting both, narrowly spaced SMDs and bare chips, an isotropically conductive adhesive has been applied.

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References

  1. R.L. Henry, Improvements in commutator brushes, British Patent #246.972, 1926.

    Google Scholar 

  2. H. Schuhmann, Conductive varnish, U.S. Patent #1,913,214, June 6, 1933.

    Google Scholar 

  3. H. Bienfait and W.L. Carolus van Zwet, Electrical conductor and method of making the same, U.S. Patent #2,018,343, Oct. 22, 1935.

    Google Scholar 

  4. H.J. Loftis, Molded electrically conductive body, U.S. Patent #2,361,220, Oct. 24, 1944.

    Google Scholar 

  5. N.H. Collings and R.J. Heaphy Beverton, Electrically conductive adhesive, U.S. Patent #2,444,034, June 29, 1948.

    Google Scholar 

  6. H. Wolfson and G. Elliott, Electrically conducting cements containing epoxy resins and silver, U.S. Patent #2,774,747, Dec. 18, 1956.

    Google Scholar 

  7. C. Mitchel and H. Berg, Use of conductive epoxies for die-attach, Int. Symp. Microelectron, 1976.

    Google Scholar 

  8. D. Gerber and W. Scheel, Kleben elektronischer Baugruppen, in W. Scheel, Ed., Baugruppentechnologie der Elektronik, Verlag Technik Berlin, Eugen G. Leuze Verlag, Saulgau, 1997, pp. 393–394.

    Google Scholar 

  9. H. Shirakawa, Nobel lecture: The discovery of polyacetylene film—the dawning of an era of conducting polymers, Reviews of Modern Physics, 73(July), pp. 713–718 (2001).

    Article  Google Scholar 

  10. P.M. Raj, J. Liu, and P. Öhlckers, Fundamentals of packaging materials and processes, in R.R. Tummala, Ed., Microsystems Packaging, McGraw-Hill, 2001, p. 739.

    Google Scholar 

  11. I. Watanabe and K. Takemura, Anisotropic conductive adhesive films for flip-chip interconnection, in J. Liu, Ed., Conductive Adhesives for Electronics Packaging, Electrochemical Publications Ltd., ISBN 0 901150 37 1, 1999, pp. 256–271.

    Google Scholar 

  12. A. Aghzout, Über die Leitfähigkeit von elektrisch anisotropen Klebern und deren Anwendungen in der Mikroelektronik, Dissertation thesis, Vienna University of Technology, June, 2002.

    Google Scholar 

  13. K.-i. Shinotani, J. Malmodin, and R. Trankell, Fundamentals of microsystems design for environment, in R.R. Tummala, Ed., Microsystems Packaging, McGraw-Hill, 2001, p. 859.

    Google Scholar 

  14. G. Hanreich, K.-J. Wolter, and J. Nicolics, Rework of flip-chip polpulated PCBS by laser desoldering, in H. Hauser, Ed., Sensors & Packaging, ÖVE-Schriftenreihe, Nr. 35, 2003, pp. 283–289.

    Google Scholar 

  15. L.M. Yu and W.C. Qing, Solder joints design attribute to no solder bridge for fine pitch device, Fifth International Conference on Electronic Packaging Technology, ICEPT2003, Shanghai, China, 28–30 Oct., 2003, pp. 70–75.

    Google Scholar 

  16. S. Kang, R.S. Rai, and S. Purushothaman, Development of high conductivity lead (Pb)-free conductive adhesives, IEEE Transactions on Components Packaging, and Manufacturing Technologies, 21(4), pp. 18–22 (1998).

    Article  Google Scholar 

  17. J.S. Hwang, Fine pitch soldering and solder paste, in J.H. Lau, Ed., Handbook of Fine Pitch Surface Mount Technology, Van Nostrand Reinhold, New York, 1993, pp. 81–133.

    Google Scholar 

  18. Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003 on the Restriction of the Use of Certain Hazardous Substances in Electrical and Electronic Equipment, Official Journal of the European Union L37, 13.02.2003, pp. 19–23.

    Google Scholar 

  19. R. Dudek, H. Berek, T. Fritsch, and B. Michel, Reliability investigations on conductive adhesive joints with emphasis on the mechanics of the conduction mechanism, IEEE Transactions on Components and Packaging Technologies, 3(3), pp. 462–469 (2000).

    Article  Google Scholar 

  20. C.P. Wong and D. Lu, Recent advances in electrically conductive adhesives for electronics applications, 4th International Conf. on Adhesive Joining and Coating Technology in Electronics Manufacturing, Proceedings, 2000, pp. 121–128.

    Google Scholar 

  21. S. Ganesan and M. Pecht, Lead-free electronics—2004 Edition, CALCE EPSC Press, ISBN 0-9707174-7-4, 2004.

    Google Scholar 

  22. J.H. Lau, C.P. Wong, N.-C. Lee, and R.S.W. Lee, Electronics Manufacturing—with Lead-Free, Halogen-Free, and Conductive-Adhesive Materials, McGraw-Hill, ISBN 0071386246, July 2002.

    Google Scholar 

  23. J.E. Morris, F. Anderssohn, S. Kudtarkar, and E. Loos, Reliability studies of an isotropic electrically conductive adhesive, 1st Int. IEEE Conference on Polymers and Adhesives in Microelectronics and Photonics, October 21–24, Potsdam, Germany, 2001, pp. 61–69.

    Google Scholar 

  24. D. Lu and C.P. Wong, Development of conductive adhesives for solder replacement, IEEE Transactions on Components and Packaging Technologies, 23(4), pp. 620–626 (2000).

    Article  MathSciNet  Google Scholar 

  25. D. Lu, C.P. Wong, and Q.K. Tong, Mechanisms underlying the unstable joint resistance of conductive adhesives, IEEE Transactions on Components, Packaging, and Manufacturing Technology, Part C, 22(3), pp. 228–232 (1999).

    Google Scholar 

  26. M. Zwolinski, J. Hickman, H. Rubin, Y. Zaks, S. McCarthy, T. Hanlon, P. Arrowsmith, A. Chaudhuri, R. Hermansen, S. Lau, and D. Napp, Electrically conductive adhesives for surface mount solder replacement, IEEE Transactions on Components, Packaging, and Manufacturing Technology, Part C, 19(4), pp. 251–256 (1996).

    Article  Google Scholar 

  27. E. Stanley, J.S. Andrade, S. Havlin, H.A. Makse, and B. Suki, Percolation Phenomena: a broad-brush introduction with some recent applications to porous media, liquid water, and city growth, Physica A: Statistical and Theoretical Physics, 266(1-4), pp. 5–16 (1999).

    Google Scholar 

  28. A. Bunde, Percolation in composites, Journal of Electroceramics, 5(2), pp. 81–92 (2000).

    Article  Google Scholar 

  29. J.E. Morris, Conduction mechanisms and microstructure development in isotropic, electrically conductive adhesives, in J. Liu, Ed., Conductive Adhesives for Electronics Packaging, Electrochemical Publications Ltd., ISBN 0 901150 37 1, 1999, pp. 37–77.

    Google Scholar 

  30. M. Mündlein, J. Nicolics, and G. Hanreich, Accelerated curing of isotropically conductive adhesivemns by vapor phase heating, Third International IEEE Conference on Polymers and Adhesives in Microelectronics and Photonics (Polytronic 2003), Montreaux, Switzerland, October 21–23, 2003, pp. 101–105.

    Google Scholar 

  31. L. Li and J.E. Morris, Electrical conduction models for isotropically conductive adhesive joints, IEEE Transactions on Components, Packaging, and Manufacturing Technology, Part A, 20(1), pp. 3–8 (1997).

    Article  Google Scholar 

  32. X.-G. Liang and X. Ji, Thermal conductance of randomly oriented composites of thin layers, International Journal of Heat and Mass Transfer, 43, pp. 3633–3640 (2000).

    Article  MATH  Google Scholar 

  33. E. Sancaktar and B. Lan, Modeling filler volume fraction and film thickness effects on conductive adhesive resistivity, 4th IEEE International Conference on Polymers and Adhesives in Microelectronics and Photonics (Polytronic 2004), Portland, USA, 12–15 Sept., 2004, pp. 38–49.

    Google Scholar 

  34. I. Balberg, C.H. Anderson, S. Alexander, and N. Wagner, Excluded volume and its relation to the onset of percolation, Physical Review B, 30(7), pp. 3933–3943 (1984).

    Article  Google Scholar 

  35. P.A. Cundall, A computer model for simulating progressive, large-scale movements in blocky rock systems, Proc. Symp. Int. Rock Mech. 2(8), Nancy, Vol. 2, 1971, pp. 129–136.

    Google Scholar 

  36. B. Su and J. Qu, A micromechanics model for electrical conduction in isotropically conductive adhesives during curing, Electronic Components and Technology 2004, Volume 2, 1–4 June 2004, pp. 1766–1771.

    Google Scholar 

  37. G.G.W. Mustoe, M. Nakagawa, X. Lin, and N. Iwamoto, Simulation of particle compaction for conductive adhesives using discrete element modeling, Electronic Components and Technology Conference 1999, 1–4 June, 1999, pp. 353–359.

    Google Scholar 

  38. A. Drory, I. Balberg, and B. Berkowitz, Application of the central-particle-potential approximation for percolation in interacting systems, Physical Review E, 52, pp. 4482–4494 (1995).

    Article  Google Scholar 

  39. B. Berkowitz, Percolation theory and network modeling applications in soil, Physics: Surveys in Geophysics, 19(1), pp. 23–72 (1998).

    Article  Google Scholar 

  40. S. Xu, D.A. Dillard, and J.G. Dillard, Environmental aging effects on the durability of electrically conductive adhesive joints, International Journal of Adhesion and Adhesives, 23(3), pp. 235–250 (2003).

    Google Scholar 

  41. E. Suganuma and M. Yamashita, High temperature degradation mechanism of conductive adhesive/Sn alloy interface, International Symposium on Advanced Packaging Materials: Processes, Properties and Interfaces, Proceedings, 2001, March 11–14, 2001, pp. 19–22.

    Google Scholar 

  42. H. Li, K.-S. Moon, Y. Li, L. Fan, J. Xu, and C.P. Wong, Reliability enhancement of electrically conductive adhesives in thermal shock environment, Electronic Components and Technology, ECTC 2004, Vol. 1, June 1–4, Las Vegas, USA, 2004, pp. 165–169.

    Google Scholar 

  43. F. Kriebel, Leitkleben—eine Alternative zum Löten in der Oberflächenmontagetechnik, VTE, (4)(Aug.), pp. 182–191 (1998).

    Google Scholar 

  44. H. Hauser, Kontaktwerkstoffe, Anhang D, in G. Fasching, Ed., Werkstoffe für die Elektrotechnik, Springer, 4th edition, 2005, pp. 517–520.

    Google Scholar 

  45. M. Mündlein, J. Nicolics, and J.E. Morris, Reliability investigations of isotropic conductive adhesives, 25th International Spring Seminar on Electronics Technology, ISSE 2002, Prague, Czech Republic, May 11–14, ISBN 0-7803-9824-6, 2002, pp. 329–333.

    Google Scholar 

  46. K. Gilleo, Evaluating polymer solders for lead-free assembly part I, Circuits Assembly, (January), pp. 50–56 (1994).

    Google Scholar 

  47. J.C. Jagt, P.J.M. Beris, and G.F.C.M. Lijten, Electrically conductive adhesives: a prospective alternative for SMD soldering? IEEE Transactions on Components, Packaging, and Manufacturing Technology, Part C, 18(2), pp. 292–298 (1995).

    Article  Google Scholar 

  48. D. Klosterman, L. Li, and J.E. Morris, Materials characterization, conduction development, and curing effects on reliability of isotropically conductive adhesives, IEEE Transactions on Components, Packaging, and Manufacturing Technology, Part A, 21(1), pp. 23–31 (1998).

    Article  Google Scholar 

  49. D. Lu, Q.K. Tong, and C.P. Wong, Conductivity mechanisms of isotropic conductive adhesives (ICAs), IEEE Transactions on Electronics Packaging Manufacturing, 22(3), pp. 223–227 (1999).

    Article  Google Scholar 

  50. J.C. Jagt, Reliability of electrically conductive adhesive joints for surface mount applications: a summary of the state of the art, IEEE Transactions on Components, Packaging, and Manufacturing Technology, Part A, 21(2), pp. 215–225 (1998).

    Article  Google Scholar 

  51. M.G. Perichaud, J.Y. Deletage, H. Fremont, Y. Danto, C. Faure, and M. Salagorty, Evaluation of conductive adhesives for industrial SMT assembles, 23rd IEEE/CPMT Electronics Manufacturing Technology Symposium, 1998, pp. 377–385.

    Google Scholar 

  52. R.C. Campbell, S.E. Smith, and R.L. Dietz, Measurements of adhesive bondline effective thermal conductivity and thermal resistance using the laser flash method, 15th Annual IEEE Semiconductor Thermal Measurement and Management Symposium, 9–11 March, 1999, pp. 83–97.

    Google Scholar 

  53. M. Mayer, J. Nicolics, G. Hanreich, and M. Mündlein, Thermal aspects of GaAs power FET attachment using isotropically conductive adhesive, 2nd Int. IEEE Conf. on Polymers and Adhesives in Microelectronics and Photonics, Polytronic 2002, Zalaegerszeg, Hungary, June 23–26, 2002, pp. 38–43.

    Google Scholar 

  54. http://www.npl.co.uk/ei/iag/leadfree/propertiespbf.html, Lead-Free Alloy Properties, National Physical Laboratory.

  55. D.W. Swanson and L.R. Enlow, Stress effects of epoxy adhesives on ceramic substrates and magnetics, Microelectronics Reliability, 41(4), pp. 499–510 (2001).

    Article  Google Scholar 

  56. J. Vanfleteren, A. Vervaet, and A.V. Calster, Highlights of the DACTEL project: development of adhesive chip technologies for dedicated electronic applications, Proc. of 23rd Int. Spring Seminar on Electronics Technology, ISSE 2000, Balatonfüred, HU, May 6–10, 2000, pp. 315–318.

    Google Scholar 

  57. M. Sumikawa, T. Sato, C. Yoshioka, and T. Nukii, Reliability of soldered joints in CSPs of various designs and mounting conditions, IEEE Transactions on Components and Packaging Technology, 24(2), pp. 293–299 (2001).

    Article  Google Scholar 

  58. R. Prasad, Adhesives and its applications, in G.R. Blackwell, Ed., The Electronic Packaging Handbook, CRC Press, IEEE Press, 2000, pp. 10-1–10-28.

    Google Scholar 

  59. M. Mündlein, G. Hanreich, and J. Nicolics, Application of an ICA for the production of a radiation sensor, Proc. of 3rd Int. IEEE Conf. on Polymers and Adhesives in Microelectronics and Photonics, Polytronic 2003, Montreux, Schweiz, October 21–23, 2003, pp. 123–127.

    Google Scholar 

  60. M. Mündlein, J. Nicolics, and M. Brandl, Packaging concept for a miniaturized wirelessly interrogable temperature logger, Proceedings of the 27th Int. Spring Seminar on Electronics Technology, Sofia, Bulgaria, May 14–16, 2004, pp. 68–73.

    Google Scholar 

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Nicolics, J., Mündlein, M. (2007). Electrically Conductive Adhesives. In: Suhir, E., Lee, Y.C., Wong, C.P. (eds) Micro- and Opto-Electronic Materials and Structures: Physics, Mechanics, Design, Reliability, Packaging. Springer, Boston, MA. https://doi.org/10.1007/0-387-32989-7_41

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  • DOI: https://doi.org/10.1007/0-387-32989-7_41

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