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Challenges in Estimating Global CF4 and C2F6 Emissions

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Light Metals 2018 (TMS 2018)

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Abstract

CF4 and C2F6 are very long-lived greenhouse gases (GHG) 50,000 and 10,000 years respectively with a global warming potential (GWP100) of 7390 and 9200. These two perfluorocarbons (PFCs) are almost entirely anthropogenic. Three main sources have been identified: (a) Aluminium Industry (AI), (b) Semiconductor Industry (SCI) and (c) Rare Earth Smelting (RES). Estimating global emissions over time and compiling a bottom-up inventory, are both challenging tasks as there are several limitations related to them. Identifying and addressing those challenges in order to produce an updated and inclusive bottom-up inventory could result in a better understanding of previous CF4 and C2F6 emissions and improved future estimates of these potent greenhouse gasses.

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References

  1. Cicerone, R. J.: Atmospheric Carbon Tetrafluoride—Nearly Inert-Gas, Science, 206, 59–61, 1979.

    Article  CAS  Google Scholar 

  2. Ravishankara, A. R., Solomon, S., Turnipseed, A. A., and Warren, R. F.: Atmospheric lifetimes of long-lived halogenated species, Science, 259, 194–199, 1993.

    Article  CAS  Google Scholar 

  3. Clerbaux, C., Cunnold, D. M., Anderson, J., Engel, A., Fraser, P. J., Mahieu, E., Manning, A., Miller, J., Montzka, S. A., Nas- sar, R., Prinn, R., Reimann, S., Rinsland, C. P., Simmonds, P., Verdonik, D., Weiss, R., Wuebbles, D., and Yokouchi, Y.: Long-Lived Compounds, Chapter 1, in: Scientific Assessment of Ozone Depletion: 2006, Global Ozone Research and Monitoring Project-Report No. 50, 572 pp., World Meteorological Organization, Geneva, Switzerland, 2007.

    Google Scholar 

  4. Forster, P., Ramaswamy, V., Artaxo, P., Berntsen, T., Betts, R., Fa-hey, D. W., Haywood, J., Lean, J., Lowe, D. C., Myhre, G., Nganga, J., Prinn, R., Raga, G., Schulz, M., and Dorland, R. V.: Changes in Atmospheric Constituents and in Radiative Forcing, in: Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the.

    Google Scholar 

  5. Jain, A. K., Briegleb, B. P., Minschwaner, K., and Wuebbles, D. J.: Radiative forcings and global warming potentials of 39 greenhouse gases, J. Geophys. Res., 105, 20773–20790, 2000.

    Article  CAS  Google Scholar 

  6. Hurley, M. D., Wallington, T. J., Buchanan, G. A., Gohar, L. K., Marston, G., and Shine, K. P.: IR spectrum and radiative forcing of CF4 revisited, J. Geophys. Res., 110, D02102, http://doi.org/10.1029/2004JD005201, 2005.

  7. Morris, R. A., Miller, T. M., Viggiano, A. A., Paulson, J. F., Solomon, S., and Reid, G.: Effects of electron and ion reactions on atmospheric lifetimes of fully fluorinated compounds, J. Geophys. Res., 100, 1287–1294, 1995

    Article  CAS  Google Scholar 

  8. Myhre, G., et al. (2013), Anthropogenic and natural radiative forcing, in Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, edited by T. F. Stocker et al., Cambridge Univ. Press, Cambridge, U. K., and New York.

    Google Scholar 

  9. Piccolo, C.; Dudhia, A., 2006: Carbon tetrafluoride from MIPAS measurements, Proceedings of the Conference held 8–12 May, 2006 at ESRIN, Franscati Italy.

    Google Scholar 

  10. Weston E. R.: “Possible greenhouse effects of tetrafluoromethane and carbon dioxide emitted from aluminum production”, Atmospheric Environment Vol. 30, No. 16, pp. 2901–2910, 1996 Copyright © 1996 Elsevier Science Ltd.

    Article  CAS  Google Scholar 

  11. Deeds et al., (2015): Tectonic activity as a significant source of crustal tetrafluoromethane emissions to the atmosphere: Observations in ground waters along the San Andreas Fault, Earth and Planetary Science Letters (Impact Factor: 4.73). 02/2015; 412. http://doi.org/10.1016/j.epsl.2014.12.016.

  12. Harnisch, J., Borchers, R., and Fabian, P.: Estimation of tropospheric trends (1980–1995) for CF4 and C2F6 from stratospheric data, Proc. SPIE, 2506, 384–393, http://doi.org/10.1117/12.221039, 1995.

  13. Harnisch, J., Borchers, R., Fabian, P., and Maiss, M.: Tropospheric trends for CF4 and C2F6 since 1982 de-rived from SF6 dated stratospheric air, Geophys. Res. Lett., 23, 1099–1102, 1996b.

    Google Scholar 

  14. Fabian, P., Borchers, R., Kruger, B. C., and Lal, S.: CF4 and C2F6 in the Atmosphere, J. Geophys. Res., 92, 9831–9835, 1987.

    Google Scholar 

  15. Khalil, M. A. K., Rasmussen, R. A., Culbertson, J. A., Prins, J. M., Grimsrud, E. P., and Shearer, M. J.: Atmospheric perfluorocarbons, Environ. Sci. Technol., 37, 4358–4361, 2003.

    Article  CAS  Google Scholar 

  16. Harnisch, J.: Atmospheric perfluorocarbons: sources and concentrations, in: Non-CO2 greenhouse gases: scientific understanding, control and implementation, edited by: van Ham, J., Baede, A., Meyer, L., and Ybema, R., Kluwer Academic Publishers, Netherlands, 205–210, 2000.

    Chapter  Google Scholar 

  17. Tabereaux A., (Paper presented at Eighth Australasian Aluminium Smelting Technology Conference and Workshops, Yeppoon, Australia, 2004).

    Google Scholar 

  18. Wong D. et al., 2015: PFC Emissions from Detected Versus Non-Detected Anode Effects in the Aluminum Industry, http://doi.org/10.1007/s11837-014-1265-8 2015. The Minerals, Metals & Materials Society.

    Article  CAS  Google Scholar 

  19. Bjerke W., R. Chase, R. Gibson, and J. Marks, Light Metals 2004, ed. A.T. Tabereaux (Warrendale, PA: TMS, 2004), pp. 367–372.

    Google Scholar 

  20. Marks, J., and C. Bayliss (2012), GHG measurement and inventory for aluminum production, in Light Metals 2012, edited by C. E. Suarez, pp. 803–808, John Wiley, Hoboken, N. J.

    Chapter  Google Scholar 

  21. Karuppannan C., (2009): Analyzing of Soderberg Cell Technology Performance and Possibilities, Manufacturing engineering Issue 2, year VIII, 2009 ss. 5–9.

    Google Scholar 

  22. Czerniak et al., (2007): Has the Challenge of PFCs Really BeenSolved? (http://www.semiconductor.net/article/CA6482822.html).

  23. Vogel et al., 2015: Development and Research Trends of the Neodymium Electrolysis—A Literature Review, Proceedings of EMC 2015.

    Google Scholar 

  24. Zepf V., Rare earth elements, 2013.

    Chapter  Google Scholar 

  25. Kingsnorth D., 2015 The global rare earth industry to-day-plagued by illegal production in China. In: 11th International Rare Earth Conference, Metal Events Ltd’s, Singapore.

    Google Scholar 

  26. Marks J. and Bayliss C., Light Metals 2012, ed. C.E. Sua-rez (Hoboken, NJ: Wiley, 2012), pp. 805–808.

    Google Scholar 

  27. Li et al., 2003: FTIR spectometers measure scrubber abatement-efficiencies, http://electroiq.com/sst/print/volume-45/issue-7/features/fab-safety/ftir-spectometer.

  28. Harnisch, J., Frische, M., Borchers, R., Eisenhauer, A., and Jordan, A.: Natural fluorinated organics in fluorite and rocks, Geophys. Res. Lett., 27, 1883–1886, 2000.

    Article  CAS  Google Scholar 

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Correspondence to Eleni Michalopoulou .

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Michalopoulou, E. (2018). Challenges in Estimating Global CF4 and C2F6 Emissions. In: Martin, O. (eds) Light Metals 2018. TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72284-9_196

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