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Partially Hydrolyzed Guar Gum: Preparation and Properties

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Polymers for Food Applications

Abstract

Guar gum is a galactomannan obtained from the endosperm portion of seed of the plant Cyamopsis tetragonolobus. Guar gum is used as thickener and stabilizer in food industry due to its high viscosity in aqueous solution. The partial hydrolysis of the guar galactomannan leads to production of partially hydrolyzed guar gum (PHGG) which is similar in structure to native guar galactomannan. PHGG can be produced by enzymatic hydrolysis, acid hydrolysis, irradiation, microwave and ultrasonication techniques. Enzymatic hydrolysis of guar gum is preferred for food processing applications. In enzymatic hydrolysis, enzymes such as mannanse, pectinase, cellulase cut the linkages between mannose units in the main chain. Partial hydrolysis of guar gum leads to the reduction in molecular weight of native guar gum. Partially hydrolyzed guar gum shows low viscosity in aqueous solutions. X-ray diffraction analysis of partially hydrolyzed guar gum revealed that it is little crystalline in nature as compared to native guar galactomannan which is amorphous in nature. Partially hydrolyzed guar gum produced from enzymatic hydrolysis can be used mainly for nutritional purpose i.e. for development of fiber enriched processed food products such as cookies, bread, noodles, yoghurt etc. Its specific physicochemical properties make it possible to improve the quality of food products. Partially hydrolyzed guar gum as soluble dietary fibre is beneficial in diabetes, heart disease and digestive problems.

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References

  • Alam NH, Ashraf H, Kamruzzaman M, Ahmed T, Islam S, Olesen MK, Gyr N, Meier R (2015) Efficacy of partially hydrolyzed guar gum (PHGG) supplemented modified oral rehydration solution in the treatment of severely malnourished children with watery diarrhoea: a randomised double-blind controlled trial. J Health Popul Nutr 34(3):1–9

    Google Scholar 

  • Alam NH, Meier R, Sarker SA, Bardhan PK, Schneider H, Gyr N (2005) Partially hydrolysed guar gum supplemented comminuted chicken diet in persistent diarrhoea: a randomized controlled trial. Arch Dis Child 90(2):195–199

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Álvarez K, Famá L, Gutiérrez TJ (2017) Physicochemical, antimicrobial and mechanical properties of thermoplastic materials based on biopolymers with application in the food industry. In: Masuelli M, Renard D (eds) Advances in physicochemical properties of biopolymers: part 1. Bentham Science Publishers, pp 358–400. https://doi.org/10.2174/9781681084534117010015. ISBN: 978-1-68108-454-1. eISBN: 978-1-68108-453-4

  • Ansari SA, Matricardi P, Cencetti C, Di Meo C, Carafa M, Mazzuca C, Palleschi A, Capitani D, Alhaique F, Coviello T (2013) Sonication-based improvement of the physicochemical properties of guar gum as a potential substrate for modified drug delivery systems. Biomed Res Int 2013:985259. https://doi.org/10.1155/2013/985259

    Article  PubMed  PubMed Central  CAS  Google Scholar 

  • Bijkerk CJ, Muris JW, Knottnerus JA, Hoes AW, De Wit NJ (2004) Systematic review: the role of different types of fibre in the treatment of irritable bowel syndrome. Aliment Pharmacol Ther 19(3):245–251

    Article  CAS  PubMed  Google Scholar 

  • Binder HJ, Mehta P (1989) Short-chain fatty acids stimulate active sodium and chloride absorption in vitro in the rat distal colon. Gastroenterology 96(4):989–996

    Article  CAS  PubMed  Google Scholar 

  • Bliss DZ, Guenter PA, Settle RG (1992) Defining and reporting diarrhea in tube-fed patients—what a mess! Am J Clin Nutr 55(3):753–759

    Article  CAS  PubMed  Google Scholar 

  • Brenner DM, Moeller MJ, Chey WD, Schoenfeld PS (2009) The utility of probiotics in the treatment of irritable bowel syndrome: a systematic review. Am J Gastroenterol 104(4):1033–1049

    Article  CAS  PubMed  Google Scholar 

  • Butt MS, Shahzadi N, Sharif MK, Nasir M (2007) Guar gum: a miracle therapy for hypercholesterolemia, hyperglycemia and obesity. Crit Rev Food Sci Nutr 47(4):389–396

    Article  CAS  PubMed  Google Scholar 

  • Carlson J, Gould T, Slavin J (2016) In vitro analysis of partially hydrolyzed guar gum fermentation on identified gut microbiota. Anaerobe 42:60–66

    Article  CAS  PubMed  Google Scholar 

  • Cheng Y, Brown KM, Prud’homme RK (2002) Preparation and characterization of molecular weight fractions of guar galactomannans using acid and enzymatic hydrolysis. Int J Biol Macromol 31(1):29–35

    Article  CAS  PubMed  Google Scholar 

  • Drossman DA, Camilleri M, Mayer EA, Whitehead WE (2002) AGA technical review on irritable bowel syndrome. Gastroenterology 123(6):2108–2131

    Article  PubMed  Google Scholar 

  • Giannini EG, Mansi C, Dulbecco P, Savarino V (2006) Role of partially hydrolyzed guar gum in the treatment of irritable bowel syndrome. Nutrition 22(3):334–342

    Article  CAS  PubMed  Google Scholar 

  • Golay A, Schneider H, Bloise D, Vadas L (1995) The effect of a liquid supplement containing guar gum and fructose on glucose tolerance in non-insulin-dependent diabetic patients. Nutr Metab Cardiovasc Dis 5(2):141–148

    CAS  Google Scholar 

  • Goldin BR, Gorbach SL (1976) The relationship between diet and rat fecal bacterial enzymes implicated in colon cancer. J Natl Cancer Inst 57(2):371–375

    Article  CAS  PubMed  Google Scholar 

  • Greenberg NA, Sellman D (1998) Partially hydrolyzed guar gum as a source of fiber. Cereal Food World 43(9):703–707

    CAS  Google Scholar 

  • Gu Y, Yamashita T, Suzuki I, Juneja LR, Yokawa T (2003) Effect of enzyme hydrolyzed guar gum on the elevation of blood glucose levels after meal. Med Biol 147:19–24

    CAS  Google Scholar 

  • Gupta S, Shah B, Sanyal B, Variyar PS, Sharma A (2009) Role of initial apparent viscosity and moisture content on post irradiation rheological properties of guar gum. Food Hydrocoll 23(7):1785–1791

    Article  CAS  Google Scholar 

  • Hood SK, Zottola EA (1988) Effect of low pH on the ability of Lactobacillus acidophilus to survive and adhere to human intestinal cells. J Food Sci 53(5):1514–1516

    Article  Google Scholar 

  • Ide T, Moriuchi H, Nihimoto K (1991) Hypolipidemic effects of guar gum and its enzyme hydrolysate in rats fed highly saturated fat diets. Ann Nutr Metab 35(1):34–44

    Article  CAS  PubMed  Google Scholar 

  • Jenkins DJ, Wolever TM, Leeds AR, Gassull MA, Haisman P, Dilawari J, Goff DV, Metz GL, Alberti KG (1978) Dietary fiber, fiber analogues and glucose tolerance: importance of viscosity. Br Med J 1(6124):1392–1394

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Jumel K, Harding SE, Mitchell JR (1996) Effect of gamma irradiation on macromolecular integrity of guar gum. Carbohydr Res 282(2):223–236

    Article  CAS  Google Scholar 

  • Kapoor MP, Juneja LR (2009) Partially hydrolyzed guar gum dietary fiber. In: Susan SC, Priscilla S (eds) Fiber ingredients: food applications and health benefits, 1st edn. CRC Press, Boca Raton, pp 79–112

    Google Scholar 

  • Kay RM (1982) Dietary fiber. J Lipid Res 23(2):221–242

    PubMed  CAS  Google Scholar 

  • Kok MS (2010) Rheological study of galactomannan depolymerisation at elevated temperatures: effect of varying pH and addition of antioxidants. Carbohydr Polym 81(3):567–571

    Article  CAS  Google Scholar 

  • Kondo S, Xiao JZ, Takahashi N, Miyaji K, Iwatsuki K, Kokubo S (2004) Suppressive effects of dietary fiber in yogurt on the postprandial serum lipid levels in healthy adult male volunteers. Biosci Biotechnol Biochem 68(5):1135–1138

    Article  CAS  PubMed  Google Scholar 

  • Minekus M, Jelier M, Xiao JZ, Kondo S, Iwatsuki K, Kokubo S, Bos M, Dunnewind B, Havenaar R (2005) Effect of partially hydrolyzed guar gum (PHGG) on the bioaccessibility of fat and cholesterol. Biosci Biotechnol Biochem 69(5):932–938

    Article  CAS  PubMed  Google Scholar 

  • Miyazawa T, Funazukuri T (2006) Noncatalytic hydrolysis of guar gum under hydrothermal conditions. Carbohydr Res 341(7):870–877

    Article  CAS  PubMed  Google Scholar 

  • Mudgil D, Barak S (2013) Composition, properties and health benefits of indigestible carbohydrate polymers as dietary fiber: a review. Int J Biol Macromol 61:1–6

    Article  CAS  PubMed  Google Scholar 

  • Mudgil D, Barak S (2016) Development of functional buttermilk by soluble fibre fortification. Agro FOOD Industry Hi Tech 27(2):44–47

    CAS  Google Scholar 

  • Mudgil D, Barak S, Khatkar BS (2011) Effect of hydrocolloids on the quality characteristics of tomato ketchup. Carpath J Food Sci Technol 3(1):39–43

    Google Scholar 

  • Mudgil D, Barak S, Khatkar BS (2012a) Process optimization of partially hydrolyzed guar gum using response surface methodology. Agro FOOD Industry Hi Tech 23(1):13–15

    CAS  Google Scholar 

  • Mudgil D, Barak S, Khatkar BS (2012b) X-ray diffraction, IR spectroscopy and thermal characterization of partially hydrolyzed guar gum. Int J Biol Macromol 50(4):1035–1039

    Article  CAS  PubMed  Google Scholar 

  • Mudgil D, Barak S, Khatkar BS (2012c) Effect of enzymatic depolymerization on physicochemical and rheological properties of guar gum. Carbohydr Polym 90(1):224–228

    Article  CAS  PubMed  Google Scholar 

  • Mudgil D, Barak S, Khatkar BS (2012d) Soluble fibre and cookie quality. Agro FOOD Industry Hi Tech 23(3):15–17

    CAS  Google Scholar 

  • Mudgil D, Barak S, Khatkar BS (2014a) Guar gum: processing, properties and food applications—a review. J Food Sci Technol 51(3):409–418

    Article  CAS  Google Scholar 

  • Mudgil D, Barak S, Khatkar BS (2014b) Optimization of enzymatic hydrolysis of guar gum using response surface methodology. J Food Sci Technol 51(8):1600–1605

    Article  CAS  PubMed  Google Scholar 

  • Mudgil D, Barak S, Khatkar BS (2016a) Optimization of textural properties of noodles with soluble fiber, dough mixing time and different water levels. J Cereal Sci 69:104–110

    Article  Google Scholar 

  • Mudgil D, Barak S, Khatkar BS (2016b) Optimization of bread firmness, specific loaf volume and sensory acceptability of bread with soluble fiber and different water levels. J Cereal Sci 70:186–191

    Article  CAS  Google Scholar 

  • Mudgil D, Barak S, Khatkar BS (2016c) Development of functional yoghurt via soluble fiber fortification utilizing enzymatically hydrolyzed guar gum. Food Biosci 14:28–33

    Article  CAS  Google Scholar 

  • Mudgil D, Barak S, Khatkar BS (2017a) Cookie texture, spread ratio and sensory acceptability of cookies as a function of soluble dietary fiber, baking time and different water levels. LWT Food Sci Technol 80:537–542

    Article  CAS  Google Scholar 

  • Mudgil D, Barak S, Khatkar BS (2017b) Texture profile analysis of yogurt as influenced by partially hydrolyzed guar gum and process variables. J Food Sci Technol 54(12):3810–3817

    Article  CAS  PubMed  Google Scholar 

  • Mudgil D, Barak S, Khatkar BS (2017c) Development and characterization of soluble fiber enriched noodles via fortification with partially hydrolyzed guar gum. J Food Meas Charact 12(1):156–163. https://doi.org/10.1007/s116940179626y

    Article  Google Scholar 

  • Prajapat AL, Gogate PR (2015) Depolymerization of guar gum solution using different approaches based on ultrasound and microwave irradiations. Chem Eng Process 88:1–9

    Article  CAS  Google Scholar 

  • Prajapat AL, Subhedar PB, Gogate PR (2016) Ultrasound assisted enzymatic depolymerization of aqueous guar gum solution. Ultrason Sonochem 29:84–92

    Article  CAS  PubMed  Google Scholar 

  • Rao TP (2016) Role of guar fiber in appetite control. Physiol Behav 164:277–283

    Article  CAS  PubMed  Google Scholar 

  • Reddy TT, Tammishetti S (2004) Free radical degradation of guar gum. Polym Degrad Stab 86(3):455–459

    Article  CAS  Google Scholar 

  • Robinson G, Ross-Murphy SB, Morris ER (1982) Viscosity-molecular weight relationships, intrinsic chain flexibility, and dynamic solution properties of guar galactomannan. Carbohydr Res 107(1):17–32

    Article  CAS  Google Scholar 

  • Roediger WE, Moore A (1981) Effect of short chain fatty acids on sodium absorption in isolated human colon perfused through vascular bed. Dig Dis Sci 26(2):100–106

    Article  CAS  PubMed  Google Scholar 

  • Salyers AA, West SHE, Vercellotti JR, Wilkins TD (1977) Fermentation of mucins and plant polysaccharides by anaerobic bacteria from the human colon. Appl Environ Microbiol 34(5):529–533

    PubMed  PubMed Central  CAS  Google Scholar 

  • Segal LG, Creely JJ, Martin AE Jr, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29(10):786–794

    Article  CAS  Google Scholar 

  • Shobha MS, Kumar AV, Tharanathan RN, Koka R, Gaonkar AK (2005) Modification of guar galactomannan with the aid of Aspergillus niger pectinase. Carbohydr Polym 62(3):267–273

    Article  CAS  Google Scholar 

  • Shobha MS, Tharanathan RN (2009) Rheological behaviour of pullulanase-treated guar galactomannan on co-gelation with xanthan. Food Hydrocoll 23(3):749–754

    Article  CAS  Google Scholar 

  • Singh V, Tiwari A (2009) Hydrolytic fragmentation of seed gums under microwave irradiation. Int J Biol Macromol 44(2):186–189

    Article  CAS  PubMed  Google Scholar 

  • Singh V, Tiwari A, Kumari P, Tiwari S (2006) Microwave-promoted hydrolysis of plant seed gums on alumina support. Carbohydr Res 341(13):2270–2274

    Article  CAS  PubMed  Google Scholar 

  • Siracusa V, Rocculi P, Romani S, Dalla Rosa M (2008) Biodegradable polymers for food packaging: a review. Trends Food Sci Technol 19(12):634–643

    Article  CAS  Google Scholar 

  • Slavin JA, Greenberg N (2003) Partially hydrolyzed guar gum: clinical nutrition uses. Nutrition 19(6):549–552

    Article  CAS  PubMed  Google Scholar 

  • Takahashi H, Yang SI, Hayashi C, Kim M, Yamanaka J, Yamamoto T (1993) Effect of partially hydrolyzed guar gum on fecal output in human volunteers. Nutr Res 13(6):649–657

    Article  CAS  Google Scholar 

  • Takeno F, Yamada H, Sekiya K, Fujitani B, Ohtsu K (1990) Effect of partially decomposed guar gum on high-cholesterol-fed rats and non-dietary fiber-fed rats. J Jpn Nutr Food Sci 43:421–425

    Article  CAS  Google Scholar 

  • Tayal A, Khan SA (2000) Degradation of a water-soluble polymer: molecular weight changes and chain scission characteristics. Macromolecules 33(26):9488–9493

    Article  CAS  Google Scholar 

  • Tuohy KM, Kolida S, Lustenberger AM, Gibson GR (2001) The prebiotic effects of biscuits containing partially hydrolysed guar gum and fructo-oligosaccharides–a human volunteer study. Br J Nutr 86(3):341–348

    Article  CAS  PubMed  Google Scholar 

  • Wang Q, Ellis PR, Ross-Murphy SB (2000) The stability of guar gum in an aqueous system under acidic conditions. Food Hydrocoll 14(2):129–134

    Article  CAS  Google Scholar 

  • Yamada K, Tokunaga Y, Ikeda A, Ohkura KI, Mamiya S, Kaku S, Sugano M, Tachibana H (1999) Dietary effect of guar gum and its partially hydrolyzed product on the lipid metabolism and immune function of Sprague-Dawley rats. Biosci Biotechnol Biochem 63(12):2163–2167

    Article  CAS  PubMed  Google Scholar 

  • Yamatoya K, Kuwano K, Suzuki J (1997) Effects of hydrolyzed guar gum on cholesterol and glucose in humans. Food Hydrocoll 11(2):239–242

    Article  CAS  Google Scholar 

  • Yamatoya K, Sekiya K, Yamada H, Ichikawa T (1993) Effects of partially hydrolyzed guar gum on postprandial plasma glucose and lipid levels in humans. J Jpn Soc Nutr Food Sci 46:199–203

    Article  CAS  Google Scholar 

  • Yoon SJ, Chu DC, Juneja LR (2008) Chemical and physical properties, safety and application of partially hydrolyzed guar gum as dietary fiber. J Clin Biochem Nutr 42(1):1–7

    Article  CAS  PubMed  Google Scholar 

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Mudgil, D. (2018). Partially Hydrolyzed Guar Gum: Preparation and Properties. In: Gutiérrez, T. (eds) Polymers for Food Applications . Springer, Cham. https://doi.org/10.1007/978-3-319-94625-2_20

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