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Generation of Hydroxyl Radicals during Laser Breakdown of Aqueous Solutions in the Presence of Fe and Cu Nanoparticles of Different Sizes

  • BIOCHEMICAL ACTIVATION OF WATER AND AQUEOUS SOLUTIONS BY EXTERNAL IMPACTS
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Abstract—

The influence of iron and copper nanoparticles of different sizes on the physico-chemical processes occurring in colloidal solutions during laser breakdown has been investigated. The water dissociation occurring under the action of breakdown plasma is characterized by generation of hydroxyl radicals. It is found that both the material of nanoparticles and their size affect the processes of hydroxyl radical generation under the action of laser breakdown plasma.

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REFERENCES

  1. L. M. F. Batista, V. K. Meader, K. Romero, K. Kunzler, F. Kabir, A. Bullock, and K. M. Tibbetts, “Kinetic control of [AuCl4]—photochemical reduction and gold nanoparticle size with hydroxyl radical scavengers,” J. Phys. Chem. B.123 (33), 7204–7213 (2019). https://doi.org/10.1021/acs.jpcb.9b04643

    Article  Google Scholar 

  2. E. V. Barmina, A. V. Simakin, and G. A. Shafeev, “Hydrogen emission under laser exposure of colloidal solutions of nanoparticles,” Chem. Phys. Lett. 655, 35–38 (2016). https://doi.org/10.1016/j.cplett.2016.05.020

    Article  ADS  Google Scholar 

  3. D. Amans, W. Cai, and S. Barcikowski, “Status and demand of research to bring laser generation of nanoparticles in liquids to maturity,” Appl. Surf. Sci. 488 (15), 445–454 (2019). https://doi.org/10.1016/j.apsusc.2019.05.117

    Article  ADS  Google Scholar 

  4. A. V. Simakin, M. E. Astashev, I. V. Baimler, O. V.    Uvarov, V. V. Voronov, M. V. Vedunova, M. A. Sevost’yanov, K. N. Belosludtsev, and S. V. Gudkov, “The effect of gold nanoparticle concentration and laser fluence on the laser-induced water decomposition,” J. Phys. Chem. B.123 (8), 1869–1880 (2019). https://doi.org/10.1021/acs.jpcb.8b11087

    Article  Google Scholar 

  5. A. Vogel, K. Nahen, D. Theisen, and J. Noack, “Plasma formation in water by picosecond and nanosecond Nd:YAG laser pulses—part I: Optical breakdown at threshold and superthreshold irradiance,” IEEE J. Sel. Top. Quantum Electron. 2 (4), 847–860 (1996). https://doi.org/10.1109/2944.577307

    Article  ADS  Google Scholar 

  6. P. Wagener, A. Schwenke, B. N. Chichkov, and S. Barcikowski, “Pulsed laser ablation of zinc in tetrahydrofuran: Bypassing the cavitation bubble,” J. Phys. Chem. C.114 (17), 7618–7625 (2010). https://doi.org/10.1021/jp911243a

    Article  Google Scholar 

  7. L.M. Lyamshev, “Optoacoustic sources of sound,” Sov. Phys.-Usp. 24 (12), 977–995 (1981).

    Article  ADS  Google Scholar 

  8. J. Noack and A. Vogel, “Laser-induced plasma formation in water at nanosecond to femtosecond time scales: Calculation of thresholds, absorption coefficients, and energy density,” IEEE J. Quantum Electron. 35 (8), 1156–1167 (1999). https://doi.org/10.1109/3.777215

    Article  ADS  Google Scholar 

  9. A. De Giacomo, R. Gaudiuso, C. Koral, M. Dell’Aglio, and O. De Pascale, “Nanoparticle enhanced laser induced breakdown spectroscopy: Effect of nanoparticles deposited on sample surface on laser ablation and plasma emission,” Spectrochim. Acta, Part B.98, 19–27 (2014). https://doi.org/10.1016/j.sab.2014.05.010

    Article  ADS  Google Scholar 

  10. M.-R. Kalus, R. Lanyumba, N. Lorenzo-Parodi, M. A. Jochmann, K. Kerpen, U. Hagemann, T. C. Schmidt, S. Barcikowski, and B. Gökce, “Determining the role of redox-active materials during laser-induced water decomposition,” Phys. Chem. Chem. Phys. 21 (34), 18636–18651 (2019). https://doi.org/10.1039/C9CP02663K

    Article  Google Scholar 

  11. V. E. Ivanov, A. M. Usacheva, A. V. Chernikov, V. I. Bruskov, and S. V. Gudkov, “Formation of long-lived reactive species of blood serum proteins induced by low-intensity irradiation of helium-neon laser and their involvement in the generation of reactive oxygen species,” J. Photochem. Photobiol., B.176, 36–43 (2017). https://doi.org/10.1016/j.jphotobiol.2017.09.012

    Article  Google Scholar 

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Funding

This study was supported by the Russian Foundation for Basic Research, project no. 19-02-00061-a and (in part) project nos. 18-52-70012-e-Asia-a and 18-32-01044-mol_a, and program no. 5 “Photonic Technologies in Sensing Inhomogeneous Media and Biological Objects” of the Presidium of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Prokhorov General Physics Institute of the Russian Academy of Sciences, 119991, Moscow, Russia

    I. V. Baimler, A. V. Simakin, O. V. Uvarov & S. V. Gudkov

  2. Moscow Institute of Physics and Technology, 141700, Dolgoprudnyi, Moscow oblast, Russia

    I. V. Baimler

  3. Moscow Technological University (MIREA), 119454, Moscow, Russia

    M. Yu. Volkov

Authors
  1. I. V. Baimler
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  2. A. V. Simakin
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  3. O. V. Uvarov
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  4. M. Yu. Volkov
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  5. S. V. Gudkov
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Corresponding author

Correspondence to S. V. Gudkov.

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Translated by Yu. Sin’kov

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Baimler, I.V., Simakin, A.V., Uvarov, O.V. et al. Generation of Hydroxyl Radicals during Laser Breakdown of Aqueous Solutions in the Presence of Fe and Cu Nanoparticles of Different Sizes. Phys. Wave Phen. 28, 107–110 (2020). https://doi.org/10.3103/S1541308X20020028

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  • DOI: https://doi.org/10.3103/S1541308X20020028

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