Skip to main content
SpringerLink
Log in

The peculiarities of the kinetics of silver chemical deposition on dielectrics with various technologies of the surface activation

  • Electrical Surface Treatment Methods
  • Published:
Surface Engineering and Applied Electrochemistry Aims and scope Submit manuscript

Abstract

The chemical reduction of single-charged ions of metal (Ar+) under the conditions of a hydrodynamic mode on a rotating cylindrical dielectric (D) specimen is first studied. The partial manifestation of the effect of the hydrodynamical rate limitation (HDRL) of silver deposition has been determined. It has been established that the complete manifestation of the HDRL (V Ag = 0) effect is blocked by the development of the process of the concentration increasing of the electro-active particles in the reactionary zone due to the increase of the amount of collisions of the noncompact silver deposit (growing in the reactor volume) and the oxidation products of the reducer (inverted sugar) with a surface of a compact Ag layer on the D specimen. The results of this research confirm the conceptions concerning the mechanism of the HDRL phenomenondue to the repulsion of electro-active particles of silver from the reactionary layer at high speeds of rotation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Beshentseva, O.A., Kalugin, V.D., and Opaleva, N.S., Peculliarities of Kinetics of Chemical Reduction of Metals from Solutions on Dielectrics under Conditions of a Critical Hydrodynamical Mode, Visnik Kharkivskogo Nats. Univ., Khim., 2005, vyp. 12(35), no. 648, pp. 127–130.

  2. Kalugin, V.D. and Beshentseva, O.A., Analysis of Kinetic and Energetic Factors During Metal Reduction under a Hydrodynamical Mode, Ukrain. Khim. Zh., 2009, vol. 75, no. 1, pp. 33–37.

    Google Scholar 

  3. Shalkauskas, M. and Vashkyalis, A., Khimicheskaya matallizatsiya plastmass (Chemical plastic plating), Leningrad: Khimiya, 1985.

    Google Scholar 

  4. Sergeev, G.B., Nanokhimiya (Nanochemistry), izd. vtoroye, Moscow: Izd-vo MGU, 2007.

    Google Scholar 

  5. Ardamatskii, A.L., Izgotovlenie opticheskikh detalei (Production of Optical Workpieces), ucheb. posobie, Fainberg, S.I. (Ed.), Moscow: Gos. Izd-vo Oboron. Promysh., 1955, pp. 465–477.

    Google Scholar 

  6. Beshentseva, O.A. and Kalugin, V.D., Kinetic Regularities of the Process of Chemical Reduction of Tin on Dielectrics by the Reaction of Disproportioning, Vestnik L’vovskogo Univ., Ser. Khim., L’vov: 2002, no. 42, part 2, pp. 233–236.

  7. Levich, V.G., Fiziko-khimicheskaya gidrodinamika (Physico-Chemical Hydrodynamics), Moscow: Fizmatgiz, 1959.

    Google Scholar 

  8. Dorfman, L.A., Gidrodinamicheskoe soprotivlenie i teplootdacha vrashchayushchikhsya tel (Hydrodynamic Resistance and Heat Transfer of Rotating Solids), Moscow: Fizmatgiz, 1960.

    Google Scholar 

  9. Kuntii, O.I., Elektrokhimiya ta morfologiya dispersnikh metaliv: Monografiya (Electrochemistry and Morphology of Dispersive Metals: Monography), L’viv: Izd. Nats. Univ. “L’vivska politekhnika”, 2008.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kharkov National Road-Autotransport University, ul. Petrovskogo 25, Kharkov, 61022, Ukraine

    O. A. Beshentseva

  2. Scientific-Research Institute of Chemistry, Karazin National University, pl. Svobody 5, Kharkov, 61077, Ukraine

    V. D. Kalugin, N. S. Opaleva & O. V. Sidorenko

Authors
  1. O. A. Beshentseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. D. Kalugin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. S. Opaleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. V. Sidorenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. D. Kalugin.

Additional information

Original Russian Text © O.A. Beshentseva, V.D. Kalugin, N.S. Opaleva, O.V. Sidorenko, 2010, published in Elektronnaya Obrabotka Materialov, 2010, No. 1, pp. 19–23.

About this article

Cite this article

Beshentseva, O.A., Kalugin, V.D., Opaleva, N.S. et al. The peculiarities of the kinetics of silver chemical deposition on dielectrics with various technologies of the surface activation. Surf. Engin. Appl.Electrochem. 46, 16–20 (2010). https://doi.org/10.3103/S1068375510010035

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1068375510010035

Keywords

Search

Navigation