Abstract
Peculiarities of obtaining of tin oxide and titanium oxide layers and semiconductor structures on their basis are described. The X-ray diffraction data show that the SnO2 and TiO2 layers possess the tetragonal crystal structure (anatase modification for TiO2). The results of analysis of the elemental composition and impedance investigations of the fabricated structures in model chloride-sulfate solutions demonstrate that the oxide/SiO2/Si structures are obtained if Si substrates are used. In the case of InP substrates, the oxide layer at the interface is not detected and the corresponding structure is oxide/InP. The results of investigations of corrosion show that a substantial shift of the corrosion potential to the anode region is observed in the case of deposition of SnO2 and TiO2 oxide layers on Si and InP crystals and fabrication of corresponding semiconductor structures. This demonstrates the possibility of the use of these materials in photoelectrochemical applications.
Similar content being viewed by others
References
Adeeb, N., Kretsu, I., Sherban, D., Sushkevich, V., and Simashkevich, A., Spray Deposited ITO-CdTe Solar Cells, Sol. Energy Mater., 1987, vol. 15, no. 1, pp. 9–19.
Vasu, V., Subrahmanyam, A., Kumar, J., and Pamasamy, P., Spray-Pyrolytic-Grown ITO/InP Junctions: Effects of Tin Doping, Semicond. Sci. Technol. 1993, vol. 8, pp. 437–440.
Do Quoc Hung, Bobeico, E., Gorceac, L, Sherban, D., and Simashkevich, A., Solar Cells Based on SIS structures, Proc. 3rd Int. Workshop on Material Science, Part I, Hanoi, 1999, pp. 56–59.
Gagara, L., Gorcheac, L., Radu, C., Sherban, D., and Simashkevich, A., Photovoltaic Converters of Solar Energy on the Base of SIS Structures, Proc. Int. Conf. “Euro-Sun 96”, Munchen, 1996, vol. 2, pp. 665–669.
Simashkevich, A., Sherban, D., Bruk, L., Bobeico, E., Coval, A., Fedorov, V., and Usatyi Iu, Spray Deposited ITO-n-Si Solar Cells with Enlarged Area, Proc. 20thEuropean PV Solar Energy Conf., Barcelona, 2005, pp. 980–982.
Grätzel, M., Photoelectrochemical Cells, Nature, 2001, vol. 414, pp. 338–344.
Badawy, W.A., Improved n-Si/oxide Junctions for Environmentally Safe Solar Energy Conversion, Sol. Energy Mater. Sol. Cells, 2002, vol. 71, pp. 281–294.
Green, M.A., Silicon Solar Cells: Advanced Principles and Practice, Sydney: Bridge Printery, 1995.
Moss, T., Barrel, G., and Ellis, B., Semiconductor Optoelectronics, New York, Halsted Press, 1973.
Voronkova, E.M., Grechushnikov, B.N., Distler, G.I., and Petrov, I.P., Opticheskie materialy dlya infrakrasnoi tekhniki (Optical Materials for Infrared Technique), Moscow: Nauka, 1965.
Author information
Authors and Affiliations
Additional information
Original Russian Text © O.L. Bersirova, L.I. Bruk, A.I. Dikusar, M.I. Karaman, S.P. Sidel’nikova, A.V. Simashkevich, D.A. Sherban, Yu.S. Yapontseva, 2007, published in Elektronnaya Obrabotka Materialov, 2007, No. 6, pp. 40–49.
About this article
Cite this article
Bersirova, O.L., Bruk, L.I., Dikusar, A.I. et al. Thin films of titanium and tin oxides and semiconductor structures on their basis obtained by pyrolytic pulverization: Preparation, characterization, and corrosion properties. Surf. Engin. Appl.Electrochem. 43, 443–452 (2007). https://doi.org/10.3103/S1068375507060075
Received:
Issue Date:
DOI: https://doi.org/10.3103/S1068375507060075