Abstract
The enthalpy of formation and combustion is calculated for 15 aliphatic amines by various methods. These characteristics depend on the number of carbon atoms and the number of amino groups in the amine molecule. The combustion parameters are calculated when P = 1 atm and V = const, for mixtures of aliphatic amines with air. The adiabatic combustion temperature of mixtures of limiting composition is practically independent of the amine structure. The calculated values of the maximum pressure exceed 1000 kPa.
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Bukharkina, T.V., Verzhichinskaya, S.V., Digurov, N.G., and Tumanyan, B.P., Khimiya prirodnykh energonositelei i uglerodnykh materialov: uchebnoe posobie (Chemistry of Natural Fuels and Carbon Materials: Manual), Moscow: Tekhnika, 2009.
Korol’chenko, A.Ya. and Korol’chenko, D.A., Pozharovzryvoopasnost’ veshchestv i sredstva ikh tusheniya: spravochnik (Fire and Explosion Danger and Extinguishing Means: Handbook), Moscow: Pozhnauka, 2004, 2nd ed.
Stull, D.R., Westrum, E.F., and Sinke, G.C., The Chemical Thermodynamics of Organic Compounds, New York: Wiley, 1969.
Smirnov, V.V., Alekseev, S.G., and Barbin, N.M., Relationship of the indicators of fire danger with chemical structure: XIV. Alkylamines, Pozharovzryvobezopastnost, 2014, no. 9, pp. 27–37.
GOST (State Standard) 12.1.044–89 SSBT: Fire and Explosion Hazard of Substances and Materials. Nomenclature of Indices and Methods of Their Determination, Moscow: Standartinform, 2006.
ChemOffice software, Chem-Bio3D 14.0 User Guide, ver. 2014. http://www.cambridgesoft.com. Accessed October 2, 2016.
Belov, G.V., Thermodynamic analysis of combustion products at high temperature and pressure, Propellants, Explos., Pyrotech., 1998, vol. 23, pp. 86–89.
Akinin, N.I. and Babaitsev, I.V., Tekhnosfernaya bezopastnost’. Osnovy prognozirovaniya vzryvoopastnosti parogazovykh smesei: uchebnoe posobie (Technosphere Safety: Principles of Forecasting of Explosion Danger of Vapor-Gas mixtures: Manual), Dolgoprudnyi: Intellekt, 2016.
Akinin, N.I., Babaitsev, I.V., Kriventsova, V.K., and Shishkova, I.A., Maximum explosive pressure and temperature of vapor-air mixtures, Coke Chem., 2011, vol. 54, no. 8, pp. 302–304.
Akinin, N.I. and Matveev, A.A., Improved classification of explosion and fire safety, Coke Chem., 2014, vol. 57, no. 11, pp. 448–452.
Shalai, E.V., Akinin, N.I., and Raikova, V.M., Calculated evaluation criteria of explosion danger of vaporgas mixture with air, in Obrazovanie i nauka dlya uchebnogo razvitiya (Role of Education and Science), Moscow: Ross. Khim.-Tekhnol. Univ. im. D.I. Mendeleeva, 2014, pp. 79–82.
Akinin, N.I., Melnikov, N.O., and Mikheev, D.I., Explosion of gas-air mixtures in coke production, Coke Chem., 2016, vol. 59, no. 1, pp. 35–39.
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Original Russian Text © N.I. Akinin, V.M. Raikova, K.N. Khvostantseva, 2016, published in Koks i Khimiya, 2016, No. 12, pp. 47–51.
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Akinin, N.I., Raikova, V.M. & Khvostantseva, K.N. Influence of the amine structure on the combustion and explosion of vapor–air mixtures. Coke Chem. 59, 478–482 (2016). https://doi.org/10.3103/S1068364X16120036
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DOI: https://doi.org/10.3103/S1068364X16120036