Abstract
The corrosion resistance of austenitic steel and nickel alloys is studied in the most aggressive media within the chemical shops of coke plants: in the stock solutions of the sulfate department and in sulfuric-acid solutions used for the purification of crude benzene. In the study, the most dangerous ions, activating corrosion in 10X17H13M2T steel, are CNS− ions, which are capable of destroying the passive layers on chromium-nickel-molybdenum steel in the stock solutions of the sulfate department. Research shows that sulfuric-acid solutions used for the purification of crude benzene are very aggressive in relation to high-alloy steel, titanium, zirconium, and copper. Possible structural materials for use in contact with such solutions include the nickel alloys ХН63МБ, ХН65МВНУ, and Hastelloy C-276.
Similar content being viewed by others
References
Kolyandr, L.Ya., Ulavlivanie i pererabotka khimicheskikh produktov koksovaniya (Capture and Processing of Coking Products), Moscow: Metallurgizdat, 1962.
Altsybeeva, A.I. and Levin, O.Z., Ingibitory korrozii: spravochnik (Corrosion Inhibitors: A Handbook), Leningrad: Khimiya, 1968.
Khanin, A.M., Berdnikova, R.D., Melikentsov, B.I., and Sidorenko, I.S., Behavior of weld joints in acidic sulfate solutions, Koks Khim., 1980, no. 7, pp. 55–58.
Nesterenko, S.V. and Dzhelali, V.V., Electrochemical behavior of high-alloy steels in acidic sulfate solutions, Vestn. Khar’kovsk. Politekhn. Inst., 1989, no. 265, pp. 81–83.
Rozenfel’d, I.L. and Maksimchuk, V.P., Passivating properties of anions, Zh. Fiz. Khim., 1961, vol. 35, no. 11, pp. 2561–2567.
Iofa, Z.A. and Fang, L.K., Acceleration of the discharge reaction of hydrogen ions at iron by hydrogen sulfide, Zashch. Met., 1974, vol. 10, no. 1, pp. 17–21.
Iofa, Z.A., Action of hydrogen sulfide on the corrosion of iron and on the adsorption of inhibitors in acidic solutions, Zashch. Met., 1970, vol. 6, no. 4, pp. 491–493.
Nesterenko, S.V. and Khanin, A.M., Corrosion protection of equipment in the sulfate department, Koks Khim., 1988, no. 5, pp. 48–51.
Nesterenko, S.V., Efimenko, I.G., and Balan, L.N., Corrosion resistance of microalloyed weld seams in fluids used in coke-plant chemical shops, Koks Khim., 1992, no. 8, pp. 32–35.
Rubchevskii, V.N., Chernyshov, Yu.A., Zelenskii, V.V., et al., Corrosion resistance of nickel alloys as structural materials used in systems for the sulfuric-acid processing of crude benzene, Uglekhim. Zh., 2013, no. 3, pp. 41–47.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.V. Zelenskiy, S.V. Nesterenko, L.P. Bannikov, 2014, published in Koks i Khimiya, 2014, No. 4, pp. 43–52.
About this article
Cite this article
Zelenskiy, V.V., Nesterenko, S.V. & Bannikov, L.P. Corrosion resistance of nickel steel and nickel alloys in aggressive media. Coke Chem. 57, 167–176 (2014). https://doi.org/10.3103/S1068364X14040097
Received:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1068364X14040097