Abstract
High-temperature corrosion of nickel superalloy VZhM4-VI is studied in environments containing different concentrations of corrosive SO2 (0.01, 1.00, and 10.00%). The corrosion process results in the formation of a mixture of different oxides on the alloy surface. As the SO2 content of the corrosive environment is increased, the metal is affected by progressively more severe corrosion.
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REFERENCES
El-Awadi, G.A., Abdel-Samad, S., and Elshazly, E.S., Hot corrosion behavior of Ni based Inconel 617 and Inconel 738 superalloys, Appl. Surf. Sci., 2016, vol. 378, pp. 224–230.
Chang, J.X., Wang, D., Zhang, G., et al., Interaction of Ta and Cr on type-I hot corrosion resistance of single crystal Ni-base superalloys, Corros. Sci., 2017, vol. 117, pp. 35–42.
Sumner, J., Encinas-Oropesa, A., Simms, N.J., and Nicholls, J.R., Type II hot corrosion: Behavior of CMSX-4 and IN738LC as a function of corrosion environment, Mater. Corros., 2014, vol. 65, pp. 188–196.
Ganesan, P. and Smith, G.D., Oxide scale formation on selected candidate combustor alloys in simulated gas turbine environments, J. Mater. Eng., 1988, vol. 4, no. 9, pp. 337–343.
Abedini, M., Jahangiri, M.R., and Karimi, P., Oxidation and hot corrosion behaviors of service-exposed and heat-treated gas turbine vanes made of IN939 alloy, Oxid. Met., 2018, vol. 90, pp. 469–484.
Gishvarov, A.S. and Davydov, M.N., Sulfide-oxide corrosion of gas turbine blades, Mezhvuzovskii sbornik nauchnykh trudov “Voprosy teorii i rascheta rabochikh protsessov teplovykh dvigatelei” (Interuniversity Collection of Scientific Papers “Issues of Theory and Calculation of Working Processes of Heat Engines”), Ufa: Ufimsk. Gos. Aviats. Tekh. Univ., no. 20, pp. 157–169.
Zurek, Z., Jedlinski, J., Kowalski, K., Kolarik, V., Engel, W., and Musul, J., Sulphidation and oxidation of Ni22Cr10Al1Y alloy in H2/H2S and SO2 atmosphere at high temperatures, J. Mater. Sci., 2000, vol. 35, pp. 685–692.
Min, P.G., Kablov, D.E., Sidorov, V.V., and Vadeev, V.E., The influence of sulfur, phosphorus, and silicon impurities on structure and properties of single crystals of nickel heat-resistant alloys, Inorg. Mater.: Appl. Res., 2019, vol. 10, pp. 220–225. https://doi.org/10.1134/S2075113319010234
Lai, H., Cao, Y., Viklund, P., Karlsson, F., Johansson, L.-G., and Stiller, K.M., High temperature corrosion of Ni-based alloys SCA425+ and IN792, Oxid. Met., 2013, vol. 80, pp. 505–516.
Deodeshmukh, V.P., Evaluating the hot corrosion behavior of high-temperature alloys for gas turbine engine components, JOM, 2015, vol. 67, no. 11, pp. 2068–2614. https://doi.org/10.1007/s11837-015-1635-x
Gregoire, B., Montero, X., Galetz, M.C., Bonnet, G., and Pedraza, F., Correlations between the kinetics and the mechanisms of hot corrosion of pure nickel at 700°C, Corros. Sci., 2019, vol. 155, pp. 134–145.
Birks, N., Meier, G.H., and Pettit, F.S., Introduction to the High-Temperature Oxidation of Metals, Cambridge: Cambridge Univ. Press, 2006.
Skovorodnikov, P.V., Busov, N.S., Poilov, V.Z., and Kazantsev, A.L., Modeling the process of high-temperature corrosion temp-resistant nickel-base alloys in a corrosive-active environment, Proc. All-Russ. Sci.-Pract. Conf. (with Int. Particip.) “Chemistry. Ecology. Urbanism”, Perm’: Perm Nat. Res. Polytekn. Univ., 2020, vol. 4, pp. 156–159. ISBN 978-5-398-02341-1. https://oahp. pstu.ru/wp-content/uploads/2020/05/HimiyaEkologiya Urbanistika_Tom-4_2020.pdf.
Jalowicka, A., Nowak, W.J., Naumenko, D., and Quadakkers, W.J., Effect of SO2 addition on air oxidation behavior of CM247 and CMSX-4 at 1050°C, JOM, 2016, vol. 68, no. 11, pp. 2776–2785. https://doi.org/10.1007/s11837-016-2072-1
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This work was implemented using the research facilities of the Center of Advanced Chemical Technologies and Physicochemical Research, Perm National Research Polytechnic University.
Funding
This work was supported by the Ministry of Science and Higher Education of the Russian Federation within project RFMEFI62120X0038 (no. 075-15-2020-532, dated April 27, 2020).
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Translated by A. Kukharuk
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Poilov, V.Z., Kazantsev, A.L., Skovorodnikov, P.V. et al. High-Temperature Corrosion of a Nickel Alloy. Inorg. Mater. Appl. Res. 13, 39–43 (2022). https://doi.org/10.1134/S2075113322010324
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DOI: https://doi.org/10.1134/S2075113322010324