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Depolarized light scattering in a 2.6-lutidine-water solution near the critical point

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Abstract

The spectra of depolarized Rayleigh light scattering, i.e., the Rayleigh line wing (RLW), and Raman scattering in a solution with the lower critical point in the phase separation diagram is experimentally studied. The Rayleigh line wing is studied to 30 cm−1 from the exciting light frequency; the Raman scattering line (RSL) is studied in the near profile region. In the vicinity of the lower critical point, as well as in solutions with the upper critical point, strong narrowing of the RLW and RSL is observed. In this case, the conditions arise for the manifestation of the profile in the Rayleigh line spectrum, which is caused by the interaction of concentration and anisotropy fluctuations. Previously, this spectral line was theoretically predicted by I. A. Chaban in [1].

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Authors and Affiliations

  1. Kuzbass State Technical University, ul. Vesennyaya 28, Kemerovo, 650026, Russia

    G. I. Zaitseva

  2. Kemerovo State Agricultural Institute, ul. Markovtseva 5, Kemerovo, 650056, Russia

    G. I. Kolesnikovb

  3. Lebedev Physical Institute, Russian Academy of Sciences, Leninskii pr. 53, Moscow, 119991, Russia

    S. V. Krivokhizhac & L. L. Chaikovc

Authors
  1. G. I. Zaitseva
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  2. G. I. Kolesnikovb
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  3. S. V. Krivokhizhac
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  4. L. L. Chaikovc
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Corresponding author

Correspondence to G. I. Zaitseva.

Additional information

Original Russian Text © G.I. Zaitsev, G.I. Kolesnikov, S.V. Krivokhizha, L.L. Chaikov, 2012, published in Kratkie Soobshcheniya po Fizike, 2012, Vol. 39, No. 6, pp. 3–12.

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Zaitseva, G.I., Kolesnikovb, G.I., Krivokhizhac, S.V. et al. Depolarized light scattering in a 2.6-lutidine-water solution near the critical point. Bull. Lebedev Phys. Inst. 39, 163–169 (2012). https://doi.org/10.3103/S1068335612060012

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  • DOI: https://doi.org/10.3103/S1068335612060012

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